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71.
Rapid pyrolysis was conducted in a drop tube reactor using seven coals under various operating conditions. In addition to dense char, porous chars (network char and cenospheric char) were formed by the rapid pyrolysis under certain conditions. Porous char was mainly composed of film-like carbon and skeleton carbon. The pyrolyzed coal char particles were characterized in detail. Morphology and bulk density of porous char were quite different from the dense char formed under the same conditions, but elemental composition and BET surface area were similar to each other. CO2 gasification reactivity of porous char was lower than dense char in the later gasification stage, and this was ascribed to the low reactivity of skeleton carbon. 相似文献
72.
73.
Koichi Awazu Xiamin Wang Junji Tominaga Hirohiko Aiba Tetsuro Komatsubara 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》2009,267(6):941-943
It has been reported that elongated Au nanoparticles oriented parallel to one another can be synthesized in SiO2 by ion irradiation. Our aim was to elucidate the mechanism of this elongation. We prepared Au and Ag nanoparticles with a diameter of 20 nm in an SiO2 matrix. It was found that Au nanoparticles showed greater elongated with a higher flux of ion beam and with thicker SiO2 films. In contrast, Ag nanoparticles split into two or more shorter nanorods aligned end to end in the direction parallel to the ion beam. These experimental results are discussed in the framework of a thermal spike model of Au and Ag nanorods embedded in SiO2. The lattice temperature exceeds the melting temperatures of SiO2, Au and Ag for 100 ns after one 110 MeV Br10+ ion has passed through the middle of an Au or Ag nanorod. 相似文献
74.
Effect of treatment of activated carbon fiber cloth electrodes with cold plasma upon performance of electric double-layer capacitors 总被引:4,自引:0,他引:4
Masashi Ishikawa Atsushi Sakamoto Masayuki Monta Yoshiharu Matsuda Koichi Ishida 《Journal of power sources》1996,60(2):233-238
Charge/discharge behavior of electric double-layer capacitors composed of activated carbon fiber cloth (ACFC) electrodes and an organic electrolyte was investigated. The modification of the ACFC electrodes was performed using cold plasma generated in argon-oxygen atmosphere. The effect of the cold plasma treatment of the ACPC electrodes on the capacitor performance was discussed on the basis of the physical and chemical properties of the ACFC surface such as pore radius distribution and surface atom concentration. 相似文献
75.
Saeko Yanaka Shigetaka Nishiguchi Rina Yogo Hiroki Watanabe Jiana Shen Hirokazu Yagi Takayuki Uchihashi Koichi Kato 《International journal of molecular sciences》2022,23(4)
Immunoglobulin G (IgG) adopts a modular multidomain structure that mediates antigen recognition and effector functions, such as complement-dependent cytotoxicity. IgG molecules are self-assembled into a hexameric ring on antigen-containing membranes, recruiting the complement component C1q. In order to provide deeper insights into the initial step of the complement pathway, we report a high-speed atomic force microscopy study for the quantitative visualization of the interaction between mouse IgG and the C1 complex composed of C1q, C1r, and C1s. The results showed that the C1q in the C1 complex is restricted regarding internal motion, and that it has a stronger binding affinity for on-membrane IgG2b assemblages than C1q alone, presumably because of the lower conformational entropy loss upon binding. Furthermore, we visualized a 1:1 stoichiometric interaction between C1/C1q and an IgG2a variant that lacks the entire CH1 domain in the absence of an antigen. In addition to the canonical C1q-binding site on Fc, their interactions are mediated through a secondary site on the CL domain that is cryptic in the presence of the CH1 domain. Our findings offer clues for novel-modality therapeutic antibodies. 相似文献
76.
Koichi Mitsukura Hiromu Sakamoto Haruka Kubo Toyokazu Yoshida Toru Nagasawa 《Journal of Bioscience and Bioengineering》2010,109(6):550-553
To efficiently produce 1,3-adamantanediol (1,3-ad(OH)2) from 1-adamantanol (1-adOH), our stocks of culture strains and soil microorganisms were surveyed for hydroxylation activity towards 1-adOH. Among them, the soil actinomycete SA8 showing the highest hydroxylation activity was identified as Streptomyces sp. based on 16S ribosomal DNA sequence analysis. The reaction products were purified by silica gel column chromatography, and from NMR and MS analyses, they were identified as 1,3-ad(OH)2 and 1,4-ad(OH)2. Streptomyces sp. SA8 produced 5.9 g l? 1 1,3-ad(OH)2from 6.2 g l? 1 1-adOH in culture broth after 120 h at 25 °C. Using resting cells, 2.3 g l? 1 1,3-ad(OH)2 was produced after 96 h of incubation at a 69% conversion rate. In both cases, 1,4-ad(OH)2 was formed as a byproduct at a rate of about 15%. Strain SA8 also hydroxylated 2-adamantanol and 2-methyl-2-adamantanol. 相似文献
77.
Junichiro Otomo Junya Oishi Teruo Mitsumori Hiroshi Iwasaki Koichi Yamada 《International Journal of Hydrogen Energy》2013
Recently, a commercial version of a residential solid oxide fuel cell (SOFC) system with a flat tubular cell has been developed. However, the system cost still remains very high, which is a barrier to its widespread use. In this study, the potential for cost reductions in SOFC stack production was investigated in order to contribute to the viability of the widespread use of such residential SOFC systems in future. A cost analysis of 700 W SOFC stack production based on a process integration modeling was conducted. The present bottom–up approach enabled us to perform a sensitivity analysis with a variety of parameters in terms of cell design, the production process and cell performance. This allowed us to investigate the effects of these factors on the production cost, thereby revealing the quantitative impact of each technological improvement on the cost reduction potential. The present analysis also revealed innovation pathways which could result in technology scenarios where residential SOFC systems could reach a break-even point in comparison with the baseload electricity cost. The analysis of the cost reduction potential presented here provides a useful viewpoint for developing a research strategy for state-of-the-art SOFC technology. 相似文献
78.
Kazumitsu Nawata Masako Ii Aya Ishiguro Koichi Kawabuchi 《Mathematics and computers in simulation》2009
We analyze the length of hospital stays of patients hospitalized for cataract and related diseases (Diagnosis Related Groups (DRG) 2041) in Japan, utilizing the data pertaining to 3436 patients on whom one-eye lens operations are performed. We use the discrete-type proportional hazard model to analyze variables that may affect the length of stay. 相似文献
79.
Ill Yong Kim Ryota Iwatsuki Koichi Kikuta Yumi Morita Toshiki Miyazaki Chikara Ohtsuki 《Materials science & engineering. C, Materials for biological applications》2011,31(7):1472-1476
Osteoconductive materials with self-setting ability have received much attention because their properties allow developing injectable materials for bone defects. Thermosensitive hydrogel with ability of bone-like apatite formation in a body environment is a candidate of injectable bone fillers with osteoconductivity because the apatite formation on materials is an essential to show osteoconduction. The present study focused on the development of a thermosensitive hydrogel through modifications of the sulphonic groups of the polysaccharide, κ-carrageenan, with potassium chloride (KCl) and calcium chloride (CaCl2). We found that the gelation temperature of κ-carrageenan solutions increased with increasing amounts of K+ ions. Apatite formation was observed on the gel after exposure to simulated body fluid for 0.5 day when the gel was prepared with a molar ratio of Ca2+/sulfonic groups = 1.5. These results indicate that a thermosensitive κ-carrageenan hydrogel with apatite-forming ability was obtained through the incorporation of K+ and Ca2+ ions into the solution. 相似文献
80.