Preparation of the composite consisting of nano‐sized gold particles and nylon‐11 oligomer

Nylon‐11 oligomer was utilized as a matrix to prepare a composite containing nano‐sized gold particles. Nylon‐11 oligomer was prepared by a thermal degradation of a commercial nylon‐11 in vacuum. Weight‐average molecular weight of the oligomer was in a range from 500 to 800. Nylon‐11 oligomer was formed into a film, and then gold was vapor‐deposited onto the oligomer film. The gold‐colored oligomer film turned a transparent red after a heat treatment at 120°C. Transmission electron microscopy showed an isolated distribution of nano‐sized gold particles in the red film of the oligomer. The gold particles were stable in the oligomer for more than a year, and they were dissolved in CH₂Cl₂ to produce a stable colloidal solution. These results suggest that the gold particles were not only dispersed in the oligomer film, but they were stabilized by the nylon‐11 oligomer to form a composite. IR spectrum of the composite showed that N H groups of the nylon‐11 oligomer were responsible for the interaction between the gold particles and the oligomer. Pulse ¹H‐NMR measurement suggested that an active molecular motion of the nylon‐11 oligomer caused the dispersion of the gold particles. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 74: 1654–1661, 1999     

Temperature rise in a birefringent substrate caused by RF discharge plasma

Temperature rises of a birefringent substrate (LiNbO₃) have been measured in an argon RF discharge plasma. The measurement method is based on monitoring the variation of natural birefringence with temperature by laser interferometry. Using this method, the dependence of substrate temperature rise on applied RF power and gas pressure has been investigated. The evaluation of the temperature curves shows that heat flux from the plasma toward the substrate is independent of time and temperature. The magnitude of the flux differs largely from the applied power, and is approximately 0.4% of the power. By measuring the electron density, electron temperature, and plasma potential with a Langmuir probe, the energy of the ions incident on the substrate is estimated. The ion flux toward the substrate is calculated from the energy of ions and is compared with the measured heat flux. The dependence on the applied power is in approximate agreement between those fluxes. The temperature distribution over the substrate thickness is simulated numerically using the finite difference method. © 1999 Scripta Technica, Electr Eng Jpn, 127(4): 9–17, 1999     

Resolution of a digital servo control system using single‐bit digital signal processing

The application of single‐bit digital signal processing to mechanical control systems has already been proposed by the authors. Multibit A/D converters have been improved to a high level. But it is difficult to improve high‐resolution A/D by the latest semiconductor technologies. A single‐bit digital signal can be generated by a delta‐sigma modulator. Single‐bit digital signal has a small quantized error at low frequency. Then with this single‐bit digital signal processing, high resolution on controlling such a narrow‐bandwidth mechanical system will be realized. In this paper, resolution of analog, multibit, and single‐bit control systems is estimated via simulation. According to the results of simulations, a single‐bit control system has a higher resolution than a multibit system under conditions of equal bit rates. © 1999 Scripta Technica, Electr Eng Jpn, 128(4): 94–101, 1999     

Energy pay-back time and life-cycle CO2 emission of residential PV power system with silicon PV module

The concerns about environmental impacts of photovoltaic (PV) power systems are growing with the increasing expectation of PV technologies. In this paper, three kinds of silicon-based PV modules, namely single-crystalline silicon (c-Si), polycrystalline silicon (poly-Si) and amorphous silicon (a-Si) PV modules, are evaluated from the viewpoint of their life-cycle. For the c-Si PV module it was assumed that off-grade silicon from semiconductor industries is used with existing production technologies. On the other hand, new technologies and the growth of production scale were presumed with respect to the poly-Si and a-Si PV modules. Our results show that c-Si PV modules have a shorter energy pay-back time than their expected lifetime and lower CO₂ emission than the average CO₂ emission calculated from the recent energy mix in Japan, even with present technologies. Furthermore the poly-Si and the a-Si PV modules with the near-future technologies give much reduction in energy pay-back times and CO₂ emissions compared with the present c-Si PV modules. The reduction of glass use and the frameless design of the PV module may be effective means to decrease them more, although the lifetime of the PV module must be taken into account. © 1998 John Wiley & Sons, Ltd.     

Arc erosion characteristics of Cu-W contact at load current range in SF6 gas

Development of SF₆ gas-insulated switches that have a long service life and are highly reliable at medium voltage ratings require arc erosion of contacts in SF₆ gas to be decreased. The effects of SF₆ gas pressure and magnetic field for arc blow-out on erosion were studied experimentally in detail using sintered Cu-W contacts. The test current, SF₆ pressure and magnetic field were 100 to 400 A, 0.1 to 0.6 MPa and 0 to 50 mT, respectively. The results show that the arc erosion rate increased linearly with the SF₆ pressure. The magnetic field effectively reduced anode erosion (i.e., the application of a mere 50 mT lowered the erosion rate to 1/3 to 1/4). These phenomena may be attributed, respectively, to the increase in evaporation rate according to the shrinkage of arcing spot areas caused SF₆ pressure and a decrease of the evaporation rate correlating to high-speed movement of the arcing spot on the anode by the magnetic field. However, the cathode erosion was insensitive to the magnetic field. The influence of both W grain size and composition ratio, Cu:W, on the erosion rate was also studied. The smaller W grain at Cu content of 50 to 70 wt.% was found to be best for suppression of erosion under the present conditions. Further, the increase of N₂ mixture ratio to SF₆ under constant total gas pressure greatly decreased contact erosion. © 1997 Scripta Technica, Inc. Electr Eng Jpn, 118 (1): 41–51, 1997     

A new flexible,reliable, and intelligent electrical energy delivery system

This paper proposes a new concept of an electric power delivery system for future decades. The power delivery network consists of a set of meshed networks spread over every demand-side block (city or town). On the end point of the power line network, quality improvement facilities (referred to as “quality improvement centers”) are installed, and each consumer can select an arbitrary quality of electricity. Thus the system can achieve multi-menu-services and uninterrupted power supply. The system contains small-scale energy storage and dispersed small-scale power generation systems. The main circuit breakers consist of power electronics devices, and communication networks are fully installed so as to control the power electronics devices or power flow according to system situations or the fault situations. The communication network also controls the demand-side management. From the above, the proposed power delivery network is flexible and reliable. The intelligent facilities (computers) are installed in the control centers as well as in the quality improvement centers. They keep the system as the most energy-conservative form. In this paper, the system is named FRIENDS (Flexible, Reliable and Intelligent Electrical eNergy Delivery system). The conclusion of this paper summarizes the major research areas that must be completed to realize the system. © 1997 Scripta Technica, Inc. Electr Eng Jpn, 121(1): 26–34, 1997     

Electric-Field-Induced Crack Growth Behavior in PZT/Al2O3 Composites

Hard lead zirconate titanate (PZT) and PZT/Al₂O₃ composites were prepared and the alternating-electric-field-induced crack growth behavior of a precrack above the coercive field was evaluated via optical and scanning electron microscopy. The crack extension in the 1.0 vol% Al₂O₃ composite was significantly smaller than that in monolithic PZT and the 0.5 vol% Al₂O₃ composite. Secondary-phase Al₂O₃ dispersoids were found both at grain boundaries and within grains in the composites. A large number of dispersoids were observed at the grain boundaries in the 1.0 vol% Al₂O₃ composite. It appears that the Al₂O₃ dispersoids reinforce the grain boundaries of the PZT matrix as well as act as effective pins against microcrack propagation.     

Forming and Sintering of in Situ Alumina Composite with Hydraulic Inorganic Binder

Two types of barium aluminate binders were prepared by heat treatment of barium aluminate precursors, synthesized by using solution processes, at low temperatures ( T < 500°C). One was barium monoaluminate (BaAl₂O₄), and the other was barium aluminate binder (BAH binder) composed of amorphous phase, barium aluminate monohydrate (BaAl₂O₄·H₂O), and BaAl₂O₄. The setting time of the BAH binder was controlled by adjusting the heat-treatment temperature of the BAH binder precursor. The addition of the synthesized BaAl₂O₄ powders to Al₂O₃ powders improved the bending strength of Al₂O₃ matrix green bodies. The synthesized BaAl₂O₄ powders led to the in situ forming of barium hexaaluminate (BaO· x Al₂O₃, x = 6.9: BA6) platelets in the matrix by reacting with Al₂O₃ during sintering. The formed BA6 platelets inhibited the grain growth of the matrix Al₂O₃ grains.     

Analysis of electromagnetic waveguide bends by three-dimensional finite element method with edge elements

An approach based on the finite element method (FEM) with the rectangular-parallelepipd edge element is proposed for the analysis of electromagnetic waveguide bends. Here, to be permissible for analysis of various electromagnetic waveguides, the analytical relations in the uniform waveguide are constructed numerically by using the FEM with the rectangular edge element. To confirm the validity and versatility of this approach, bends of a hollow waveguide, a half-filled dielectric waveguide, and a finline are analyzed. © 1996 John Wiley & Sons, Inc.