A comparative study of the gas sensing behavior of nanostructured nickel ferrite synthesized by hydrothermal and reverse micelle techniques

A comparative study of gas sensing behavior of nanocrystalline nickel ferrite synthesized by micro-emulsion and hydrothermal method to liquefied petroleum gas (LPG) is presented. Nanocrystalline nickel ferrite synthesized by hydrothermal method indicated higher electrical conductivity and gas sensitivity at low operating temperature compared to nanocrystalline nickel ferrite synthesized by reverse micelle technique. This difference in the gas sensing behavior can be attributed to the presence of more oxygen vacancies (i.e. non-stoichiometry) in the hydrothermally synthesized nickel ferrite. Incorporation of palladium had a catalytic effect and the operating temperature was significantly reduced in both the samples. The higher operating temperature of the reverse micelle nickel ferrite material makes the sensor response speed faster (∼10 s) compared to the hydrothermally synthesized material (∼1 min).     

Autoscan: a scan design without external scan inputs or outputs

We propose a design-for-testability technique for synchronous sequential circuits called autoscan. Autoscan uses scan chains similar to conventional scan. However, it gives up the external scan inputs and outputs in order to eliminate the test data volume associated with them. Scan operations under autoscan improve the circuit testability by allowing the circuit state to be modified through shifting. Due to the removal of the scan inputs and outputs, synthesis of scan chains under autoscan does not have to satisfy all the constraints imposed on conventional scan chains. We describe a synthesis procedure for autoscan chains, and demonstrate that autoscan allows us to detect almost all the faults that are detectable using conventional scan. We use random sequences in order to show that sequential test generation is not necessary under autoscan. We also describe a test generation procedure, and discuss the effect of autoscan on fault diagnosis.     

Maximum likelihood estimation of constellation vectors for blindseparation of co-channel BPSK signals and its performance analysis

In this paper, we present a method for blind separation of co-channel BPSK signals arriving at an antenna array. This method consists of two parts: the maximum likelihood constellation estimation and assignment. We show that at high SNR, the maximum likelihood constellation estimation is well approximated by the smallest distance clustering algorithm, which we proposed earlier on heuristic grounds. We observe that both these methods for estimating the constellation vectors perform very well at high SNR and nearly attain Cramer-Rao bounds. Using this fact and noting that the assignment algorithm causes negligible error at high SNR, we derive upper bounds on the probability of bit error for the above method at high SNR. These upper bounds fall very rapidly with increasing SNR, showing that our constellation estimation-assignment approach is very efficient. Simulation results are given to demonstrate the usefulness of the bounds     

LP-BM5 virus causes changes in lactic dehydrogenase and oxygen radical production in splenocytes of C57BL/6J mice

The LP-BM5 murine leukemia virus causes acquired immunodeficiency syndrome in C57BL/6J mice (MAIDS), similar to that of AIDS in humans. The objective of this study was to determine the effect of LP-BM5 viral infection on cellular activation and membrane integrity of splenocytes. Oxidative burst in splenocytes in response to exposure to PMA (20 microg/ml) was significantly higher (p<.02) in infected than in control mice at two weeks post-infection using luminol-enhanced chemiluminescence. By 13 weeks post-infection superoxide anion production in infected mice was significantly lower when compared to controls coinciding with decreased proliferative response to mitogens. The extent of cell membrane damage as indicated by lactic dehydrogenase (LDH) activity in serum was significantly higher in infected than in control mice (p<.001). The results from this study suggests that LP-BM5 virus causes an initial stimulation of cellular activity followed by a decreased cell activation characterized by decreased proliferation of splenocytes and decreased oxygen radical production. Decreased cell membrane integrity indicated by increased LDH activity may partly be responsible for these changes.     

Fundamental Limitations of Continuous-Time Delta–Sigma Modulators Due to Clock Jitter

We examine noise due to clock jitter in single-loop low-pass continuous-time delta-sigma (Delta Sigma) modulators (CT-DSMs) employing nonreturn to zero (NRZ) feedback digital-to-analog converters (DACs). Using the discrete-time version of the Bode sensitivity integral, we derive a lower bound on jitter noise and its relationship to the noise transfer function (NTF) of the modulator. We show that NTFs with optimized zeros result in lower jitter noise than those with all zeros at the origin. We give intuition to a recent observation (arrived through numerical optimization) that NTFs with peaking in their passbands have lower jitter noise than maximally flat NTFs. We propose a design procedure that minimizes the sum of the quantization and jitter noise. The arguments regarding Delta Sigma analog-to-digital converters are extended to Delta Sigma DACs and measurement results are presented.     

Surface characterization of sprayed CuGa x In1−x Se2 layers

Small-area polycrystalline CuGa _x In_1–x Se₂-based solar cells produced in the laboratory have been reported with efficiencies up to 18.8%. This success at achieving high-efficiency devices has stimulated a parallel research effort to produce large-area modules based on the use of CuGa _x In_1–x Se₂ with reduced cost of production. One method that has potential to achieve these objectives is chemical spray pyrolysis. Preliminary studies have resulted in devices with efficiencies of 4–5%. Further improvements toward implementing higher-efficiency devices are expected to result from a better understanding of the physical and chemical properties of the chalcopyrite layers produced. In this work we have investigated, for the first time, the properties of these layers using X-ray photoelectron spectroscopy (XPS) to identify the secondary phases and residual impurities present. The layers studied were for In/Ga mole ratios of x=0, 0.2, 0.4, 0.6, 0.8, and 1.0 in CuGa _x In_1–x Se₂. The layers were also profiled by sputter etching away the surface of the layers and repeating the XPS measurements. The effects of annealing the layers in air, vacuum, and selenium vapor were also investigated.     

Analysis of slots in nonradiating dielectric waveguide using the modal expansion method

A modal expansion method is used with the reciprocity and Poynting theorems to derive the admittance of inclined slots cut in the metal wall of a nonradiating dielectric (NRD) waveguide. Theoretical values of normalised conductance and susceptance are compared with previously reported experimental results and are found to be in good agreement.<>     

Comparative study of crystallization processes in Sb2Te3 films using laser and thermal annealing techniques

Adherent and pin-hole free amorphous Sb₂Te₃ thin films have been obtained by vacuum evaporation at substrate temperatures ≤25 °C. The films have been crystallized by thermal and laser annealing, and the crystallization processes monitored as a function of annealing temperature and laser scan speed. A comparative study of topography reveals disk-shaped crystallized areas in thermal crystallization and dendrite growth in the laser induced process. The crystallized films in both cases contain a single Sb₂Te₃ phase. Activation energy of 2 eV for crystallization, determined using differential scanning calorimetery indicates good room temperature stability of the amorphous states.     

Graph‐Theory Approach to Eigenvalue Problem of Large Space Structures

The dynamic analysis and control system design of large space structures involve the solution of the large‐dimensional generalized matrix eigenvalue problem. The computational effort involved is proportional to the third power of the dimension of the matrices involved. To minimize the computational time a graph‐theory approach to reduce a matrix to lower‐ordered submatrices is proposed. The matrix‐reduction algorithm uses the Boolean matrices corresponding to the original numerical matrices and, thus, the computational effort to reduce the original matrix is nominal. The computational savings directly depend upon the number of submatrices into which the original matrix is reduced. A free‐free square plate is considered as an example to illustrate the technique. In this example a matrix of 16th order is reduced to three scalars corresponding to three rigid‐body modes, and three matrices of order three and one matrix of order four.