Investigation of electrochromic properties of poly(3,5-bis(4-methoxyphenyl)dithieno[3,2-b;2′,3′-d]thiophene)

Electropolymerization of 3,5-bis(4-methoxyphenyl)dithieno[3,2-b;2′,3′-d]thiophene BMPhDTT, having strong electron-donating methoxy groups, was performed, utilizing potentiodynamic method. The homopolymer was characterized by cyclic voltammetry (CV), Fourier transform infrared (FTIR) and UV–vis spectroscopy. Spectroelectrochemical and electrochromic properties of the homopolymer film were investigated and a PBMPhDTT/PEDOT device was constructed to understand its characteristics in detail. It was revealed that the potential range of 0.0–2.0 V is suitable for operating the device between yellow and blue colors. It indicated a good open circuit memory and stability.     

A review on solar-hydrogen/fuel cell hybrid energy systems for stationary applications

There are several methods for producing hydrogen from solar energy. Currently, the most widely used solar hydrogen production method is to obtain hydrogen by electrolyzing the water at low temperature. In this study, solar hydrogen production methods, and their current status, are assessed. Solar-hydrogen/fuel cell hybrid energy systems for stationary applications, up to the present day are also discussed, and preliminary energy and exergy efficiency analyses are performed for a photovoltaic-hydrogen/fuel cell hybrid energy system in Denizli, Turkey. Three different energy demand paths – from photovoltaic panels to the consumer – are considered. Minimum and maximum overall energy and exergy efficiencies of the system are calculated based on these paths. It is found that the overall energy efficiency values of the system vary between 0.88% and 9.7%, while minimum and maximum overall exergy efficiency values of the system are between 0.77% and 9.3% as a result of selecting various energy paths. More importantly, the hydrogen path appears to be the least efficient one due to the addition of the electrolyzer, the fuel cells and the second inverter for hydrogen production and utilization.     

Compact Thermal Model for the Transient Temperature Prediction of a Water-Cooled Microchip Module in Low Carbon Emission Computing

This article presents a compact computational model for the rapid determination of the junction temperature of a chip cooled with a heat sink, exploring the concept of hot water cooled electronics as a strategy to reduce the carbon footprint of data centers. The model aims at rapid simulations of variations of the chip, as well as the heat sink outlet water temperatures during transient heat loads. The model is validated by experimental tests with a water-cooled manifold microchannel (MMC) heat sink, which is designed to cool the processors of state-of-the-art servers. The chip temperature is determined subject to periodic heat loads as large as 100 W with frequencies in the range from 1 to 10 Hz. The results show that to calculate 1 s of real temperature variation requires less than 20 s of computational time on a Quad-Core AMD Opteron 2350, 2 GHz desktop PC with 4 GB RAM. The thermal response of the heat sink to real-time power traces with durations up to 200 s is modeled for different flow rates. The simulations indicate that application of a flow-control feedback loop could achieve more than 50% reduction in water flow rate, without compromising the maximal chip temperatures.     

A literature survey on energy–growth nexus

This paper provides a survey of the recent progress in the literature of energy consumption–economic growth and electricity consumption–economic growth causality nexus. The survey highlights that most empirical studies focus on either testing the role of energy (electricity) in stimulating economic growth or examining the direction of causality between these two variables. Although the positive role of energy on growth has become a stylized fact, there are some methodological reservations about the results from these empirical studies. A general observation from these studies is that the literature produced conflicting results and there is no consensus neither on the existence nor on the direction of causality between energy consumption (electricity consumption) and economic growth. As a policy implication, to avoid from conflicting and unreliable results, the authors may use the autoregressive distributed lags bounds test, two-regime threshold co-integration models, panel data approach and multivariate models including new variables (such as: real gross fixed capital formation, labor force, carbon dioxide emissions, population, exchange rates, interest rates, etc.). Thus, the authors should focus more on the new approaches and perspectives rather than by employing usual methods based on a set of common variables for different countries and different intervals of time.     

CO2 emissions,energy consumption and economic growth in Turkey

This paper examines the long run and causal relationship issues between economic growth, carbon emissions, energy consumption and employment ratio in Turkey by using autoregressive distributed lag bounds testing approach of cointegration. Empirical results for Turkey over the period 1968–2005 suggest an evidence of a long-run relationship between the variables at 5% significance level in Turkey. The estimated income elasticity of carbon emissions per capita is ?0.606 and the income elasticity of energy consumption per capita is 1.375. Results for the existence and direction of Granger causality show that neither carbon emissions per capita nor energy consumption per capita cause real GDP per capita, but employment ratio causes real GDP per capita in the short run. In addition, EKC hypothesis at causal framework by using a linear logarithmic model is not valid in Turkish case. The overall results indicates that energy conservation policies, such as rationing energy consumption and controlling carbon dioxide emissions, are likely to have no adverse effect on the real output growth of Turkey.     

Respiratory motion of the heart from free breathing coronary angiograms

Respiratory motion compensation for cardiac imaging requires knowledge of the heart's motion and deformation during breathing. This paper presents a method for measuring the natural tidal respiratory motion of the heart from free breathing coronary angiograms. A three-dimensional (3-D) deformation field describing the cardiac and respiratory motion of the coronary arteries is recovered from a biplane acquisition. A cardiac respiratory parametric model is formulated and used to decompose the deformation field into cardiac and respiratory components. Angiograms from ten patients were analyzed. A 3-D translation motion model was sufficient for describing the motion of the heart in only two patients. For all patients, the heart translated caudally (mean, 4.9+/-1.9 mm; range, 2.4 to 8.0 mm) and underwent a cranio-dorsal rotation (mean, 1.5 degrees+/-0.9 degrees; range, 0.2 degrees to 3.5 degrees) during inspiration. In eight patients, the heart also translated anteriorly (mean, 1.3+/-1.8 mm; range, -0.4 to 5.1 mm) and rotated in a caudo-dextral direction (mean, 1.2 degrees+/-1.3 degrees; range, -1.9 degrees to 3.2 degrees).     

Nanostructured artificial nacre

Finding a synthetic pathway to artificial analogs of nacre and bones represents a fundamental milestone in the development of composite materials. The ordered brick-and-mortar arrangement of organic and inorganic layers is believed to be the most essential strength- and toughness-determining structural feature of nacre. It has also been found that the ionic crosslinking of tightly folded macromolecules is equally important. Here, we demonstrate that both structural features can be reproduced by sequential deposition of polyelectrolytes and clays. This simple process results in a nanoscale version of nacre with alternating organic and inorganic layers. The macromolecular folding effect reveals itself in the unique saw-tooth pattern of differential stretching curves attributed to the gradual breakage of ionic crosslinks in polyelectrolyte chains. The tensile strength of the prepared multilayers approached that of nacre, whereas their ultimate Young modulus was similar to that of lamellar bones. Structural and functional resemblance makes clay- polyelectrolyte multilayers a close replica of natural biocomposites. Their nanoscale nature enables elucidation of molecular processes occurring under stress.     

Dynamic stability of cracked multi-bay frame structures

The effects of crack depth and crack location on the in-plane static and dynamic stability of cracked multi-bay frame structures subjected to periodic loading have been investigated numerically by using the finite element method. For the rectangular cross-section beam, a crack element is developed by using the principles of fracture mechanics. In addition, the effect of the number of spans and static and dynamic load parameters on static and dynamic stability analysis are also investigated. For buckling and dynamic stability analyses, the results obtained by using the present model are presented in three-dimensional graphical forms and tables.     

Modeling and simulation of 5-axis milling processes

5-axis milling is widely used in machining of complex surfaces. Part quality and productivity are extremely important due to the high cost of machine tools and parts involved. Process models can be used for the selection of proper process parameters. Although extensive research has been conducted on milling process modeling, very few are on 5-axis milling. This paper presents models for 5-axis milling process geometry, cutting force and stability. The application of the models in selection of important parameters is also demonstrated. A practical method, developed for the extraction of cutting geometry, is used in simulation of a complete 5-axis cycle.