Monodisperse microspheres of copolymers of glycidyl methacrylate and its derivatives as materials for biomedical application

Monodisperse microspheres of copolymers of glycidyl methacrylate were prepared by dispersion polymerization in organic media. The microsphere diameter could be adjusted in the range from 0$md$5 μm to 5μm by changing the monomer concentration, the type of dispersion medium and the content of the comonomers. Terpolymers of glycidyl methacrylate, 2-hydroxyethyl methacrylate and tri(ethylene glycol) dimethacrylate were analysed by thermal decomposition gas chromatography and the compositions of the polymers agreed well with those of the monomer mixtures. The epoxide of the polymer microspheres was hydrolysed to α,β-diol with dilute sulphuric acid without side reactions except the slight formation of sulphate. It was confirmed by the ¹³CFT-NMR spectrum that the main structure of the hydrolysate was that of poly(glyceryl methacrylate). In the reaction of the epoxide with ammonia, the predominant production of tertiary amine was presumed by the relationship between the conversion of the epoxide and the nitrogen content of the reaction product. The amination of the epoxide with secondary amines resulted in the quantitative formation of the corresponding tertiary amines.     

Thermohydraulic and mechanical design assessment of tube-panel first wall for Tokamak Fusion Power Reactor

A first wall structural concept cooled by high temperature and pressurized water has been proposed for the Tokamak Fusion Power Reactor (SPTR-P). Among a number of candidate design concepts, a tube-panel structure was selected for the first wall design. Stainless steel serves as the first wall structural material. The first wall is separated from the blanket wall and has a circular cross-section coolant channel since this shape is the most desirable for resisting the mechanical load due to the pressurized cooling water. Feasibility of the thermohydraulic and mechanical design has been established by analyses under steady-state operating conditions. The effect of the heat load during plasma disruptions on the thermomechanical characteristics of the first wall has been clarified. The mechanical strength of the first wall of power reactor is inadequate to withstand the thermal load expected during plasma disruption in an experimental reactor.On leave from Kawasaki Heavy Industries Ltd.     

SIC COATING OF SMALL PARTICLES IN A FLUIDIZED BED REACTOR

Silicon carbide was chemically vapor deposited on the small particles in the fluidized bed reactor. Methyltrichlorosilane and hydrogen were used as reactants and in some cases argon was added as a fluidizing gas. Thirty-one coating runs were carried out where coating temperature, methyltrichlorosilane concentration and fluidizing gas composition were varied systematically. The deposit composition was found to be beta-SiC or mixture of beta-SiC and silicon by X-ray diffractometry. The coating temperature affected the deposit composition. From the results of the coating experiment, the model of the CVD processes was presented, which was based on the mass transfer mechanism. This model explained the experimental results fairly well.     

Effect of blue light from LCD on VDT work: Experiment using blue light reduction function LCD

The aim of this study was to examine the impact of the blue light from the visual display terminal (VDT) on visual search tasks. We assessed the quantity of the blue light from medical imaging diagnoses (medical‐grade) liquid‐crystal display (LCD) and general (personal computer‐grade) LCD for the VDT work, both equipped with the blue light reduction function. Then, we measured the visibility of display by evaluating the correct answer rate and reaction time of visual search tasks. The quantity of the blue light was proportional to the luminance of the display. When the blue light reduction function was used during the VDT work, the blue light at the peak wavelength was reduced by about 56%. Though the luminance of the display reduced, the visibility of the display was not decreased. These findings suggest that the blue light reduction on the LCD could work efficiently in the VDT work, maintaining the visibility of the display.     

The role of “craft language” in learning “Waza”

The role of craft language in the process of teaching (learning) Waza (skill) will be discussed from the perspective of human intelligence.It may be said that the ultimate goal of learning Waza in any Japanese traditional performance is not the perfect reproduction of the teaching (learning) process of Waza. In fact, a special metaphorical language (craft language) is used, which has the effect of encouraging the learner to activate his creative imagination. It is through this activity that the he learns his own habitus (Kata).It is suggested that, in considering the difference of function between natural human intelligence and artificial intelligence, attention should be paid to the imaginative activity of the learner as being an essential factor for mastering Kata.This article is a modified English version of Chapter 5 of my bookWaza kara shiru (Learning from Skill), Tokyo University Press, 1987, pp. 93–105.     

The effect of dispersion of nano-carbon on electrochemical behavior of Fe/nano-carbon composite electrode

In order to estimate the effect of the dispersion of nano-carbon species into a composite electrode, ultrasonic pretreatments under various conditions have been carried out for two kinds of nano-carbons, vapor grown carbon fiber (VGCF) and acetylene black, before preparing a composite electrode with iron powder. The cyclic voltammetry behavior of the resulting Fe/nano-carbon composite electrodes is significantly influenced by the kind of nano-carbon and the pretreatment conditions in spite of as a low content of nano-carbon as 20 wt.%. The largest redox current at initial cycle is obtained for Fe/VGCF composite electrode with the 30 min pretreatment of VGCF in ethanol. The dispersion of nano-carbon verifies the apparent density of the composite, and then affects the feature of three-phase interface among the ion-conducting electrolyte, the redox reaction surface, and the electron conductor.     

Evaluation of gas-particle partition of dioxins in flue gas I: evaluation of gasification behavior of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans in fly ash by thermal treatment

The gasification behavior of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) in fly ash by thermal treatment has been investigated to estimate gas-particle partition in flue gas. The results obtained in thermal experiments under various conditions showed that gasification of PCDD/Fs depends on air flow rate and treatment weight of fly ash as well as treatment temperature. On the other hand, the results obtained in the thermal experiments using dioxin-free fly ash revealed that during thermal treatment, the de novo synthesis, gasification, and decomposition of PCDFs proceeded at different rates. This difference in the reaction rates indicates that thermal treatment time is also a factor in determining the gas-particle partition of PCDD/Fs in fly ash. Therefore, reasonable thermal treatment conditions were established and applied to three ash samples. For all samples, PCDD/Fs started to gasify at 350 degrees C treatment, whereas 53-98% of PCDD/F homologs gasified at 400 degrees C treatment, implying that gaseous PCDD/Fs are dominant in flue gas at temperatures in the range 350-400 degrees C regardless of particle concentration.     

Protective Effects of Voluntary Exercise on Hepatic Fat Accumulation Induced by Dietary Restriction in Zucker Fatty Rats

Weight control based on dietary restriction (DR) alone can cause lipid metabolic failure and progression to fatty liver. This study aimed to investigate the effect of exercise on preventing DR-induced hepatic fat accumulation in Zucker fatty (ZF) rats by focusing on the relationship between adipose tissue lipolysis and hepatic fat uptake. Six-week-old male ZF rats were randomly assigned to obese, DR, or DR with exercise (DR + Ex) groups. The DR and DR + Ex groups were fed a restricted diet, with the latter also undergoing voluntary exercise. After 6 weeks, hepatic fat accumulation was observed in the DR group, whereas intrahepatic fat was markedly reduced in the DR + Ex group. Compared with the obese (Ob) group, the DR group exhibited 2.09-fold expression of hepatic fatty acid translocase (FAT)/CD36 proteins (p < 0.01) and 0.14-fold expression of hepatic fatty acid-binding protein (FABP)1 (p < 0.01). There were no significant differences between the DR + Ex group and the Ob group. FAT/CD36 and hepatic triglyceride (TG) expression levels were strongly positively correlated (r = 0.81, p < 0.001), whereas there was a strong negative correlation between FABP1 and hepatic TG expression levels (r = −0.65, p < 0.001). Our results suggest that hepatic fat accumulation induced by DR in ZF rats might be prevented through exercise-induced modifications in FAT/CD36 and FABP1 expression.     

Cobalt‐containing smectite‐like mesoporous material as a new type of catalyst for hydrodesulfurization of thiophene

Cobalt‐containing mesoporous smectite‐like material (SM(Co)) was prepared by a hydrothermal method and used as a catalyst for hydrodesulfurization (HDS) of thiophene. It is active by itself and produces mainly butenes and a small amount of n-butane. When platinum is added to this material, the HDS activity is enhanced by 50%, while the product distribution does not change so much. The platinum‐loaded sample should have two types of active sites, one originally present in the smectite‐like material and the other with platinum, the latter being different in nature from a sample of platinum supported on silica gel. Thus, the SM(Co) and Pt/SM(Co) samples are new types of HDS catalysts. This revised version was published online in July 2006 with corrections to the Cover Date.     

Effect of chromatic components on facial skin whiteness

Although the color measurement of facial skin becomes more common in dermatology and cosmetics, little is known about the relationship between subjective color perception and colorimetric values in facial skin. In this study, the possible relationships among perceived whiteness and the metric lightness, chroma and hue angle of Japanese females' facial skin color were investigated. First, the perceived brightness of the facial skin of Japanese females was evaluated visually and compared with metric lightness, chroma and hue angle, and the effect of hue and chroma on the perceived brightness was discussed. Second, a psychophysical experiment on the whiteness of the facial images and synthesized skin color plate images was conducted for examining the effect of hue and chroma on the perceived whiteness more precisely and independently. The results of two experiments showed that in regard to the facial skin color of the Japanese female, metric lightness disagrees with perceived whiteness or brightness in a narrow lightness range. The reddish facial skin color appeared brighter or whiter than that of a yellowish one in high lightness regions, and the low‐chroma facial skin color appeared brighter or whiter than a high‐chroma one. However, in the color plate images, a change in perceived whiteness by hue could not be confirmed, and the change in perceived whiteness by chroma was weaker than that from facial images. These results indicated that a higher‐level process of face recognition affected whiteness perception, and the criterion of facial skin whiteness was determined by facial skin color distribution. © 2011 Wiley Periodicals, Inc. Col Res Appl, 2011;