The buffering effect of carbon on the structural stability of amorphous silicon films, used as an anode for lithium ion rechargeable batteries, has been studied during long term discharge/charge cycles. To this extent, the electrochemical performance of a prototype material consisting of amorphous Si thin film (∼250 nm) deposited by radio frequency magnetron sputtering on amorphous carbon (∼50 nm) thin films, denoted as a-C/Si, has been investigated. In comparison to pure amorphous Si thin film (a-Si) which shows a rapid fade in capacity after 30 cycles, the a-C/Si exhibits excellent capacity retention displaying ∼0.03% fade in capacity up to 50 cycles and ∼0.2% after 50 cycles when cycled at a rate of 100 μA/cm2 (∼C/2) suggesting that the presence of thin amorphous C layer deposited between the Cu substrate and a-Si acts as a buffer layer facilitating the release of the volume induced stresses exhibited by pure a-Si during the charge/discharge cycles. This structural integrity combined with microstructural stability of the a-C/Si thin film during the alloying/dealloying process with lithium has been confirmed by scanning electron microscopy (SEM) analysis. The buffering capacity of the thin amorphous carbon layer lends credence to its use as the likely compliant matrix to curtail the volume expansion related cracking of silicon validating its choice as the matrix for bulk and thin film battery systems. 相似文献
The objective of this paper is to analyze the temperature distributions and heat affected zone in skin tissue medium when irradiated with either a collimated or a focused laser beam from a short pulse laser source. Experiments are performed on multi-layer tissue phantoms simulating skin tissue with embedded inhomogeneities simulating subsurface tumors and as well as on freshly excised mouse skin tissue samples. Two types of lasers have been used in this study – namely a Q-switched pulsed 1064 nm Nd:YAG short pulse laser having a pulse width of 200 ns and a 1552 nm diode short pulsed laser having a pulse width of 1.3 ps. Experimental measurements of axial and radial temperature distribution in the tissue medium are compared with the numerical modeling results. For numerical modeling, the transient radiative transport equation is first solved using a discrete ordinates method for obtaining the intensity distribution and radiative heat flux inside the tissue medium. Then the temperature distribution is obtained by coupling the bio-heat transfer equation with either hyperbolic non-Fourier or parabolic Fourier heat conduction model. The hyperbolic heat conduction equation is solved using MacCormack’s scheme with error terms correction. It is observed that experimentally measured temperature distribution is in good agreement with that predicted by hyperbolic heat conduction model. The experimental measurements demonstrate that converging laser beam focused directly at the subsurface location can produce desired high temperature at that location compared to that produced by collimated laser beam for the same laser parameters. Finally the ablated tissue removal is characterized using histological studies as a function of laser parameters. 相似文献
A p-version least-squares finite element formulation for non-linear problems is presented and applied to the steady-state, one-dimensional Burgers' equation. The second-order equation is recast as a set of first-order equations which permit the use of C0 elements. The primary and auxiliary variables are approximated using equal-order p-version hierarchical approximation functions. The system of non-linear simultaneous algebraic equations resulting from the least-squares process is solved using Newton's method with a line search. The use of ‘exact’ and ‘reduced’ quadrature rules is investigated and the results are compared. The formulation is found to produce excellent results when the ‘exact’ integration rule is used. The combination of least-squares finite element formulation and p-version works extremely well for Burgers' equation and appears to have great potential in fluid dynamics problems. 相似文献
This paper presents a p-version geometrically non-linear formulation based on the total Lagrangian approach for a nine node three dimensional curved shell element. The element geometry is defined by the coordinates of the nodes located on its middle surface and nodal vectors describing the bottom and top surfaces of the element. The element displacement approximation can be of arbitrary and different polynomial orders in the plane of the element and in the transverse direction. The element approximation functions and the corresponding nodal variables are derived from the Lagrange family of interpolation functions. The resulting approximation functions and the nodal variables are hierarchical and the element displacement approximation ensures C° continuity. The element properties are established using the principle of virtual work and the hierarchical element approximation. In formulating the properties of the element complete three dimensional stresses and strains are considered, hence the element is equally effective for very thin as well as extremely thick shells and plates. Incremental equations of equilibrium are derived and solved using the standard Newton–Raphson method. The total load is divided into increments, and for each increment of load, equilibrium iterations are performed until each component of the residuals is within a preset tolerance. Numerical examples are presented to show the accuracy, efficiency and advantages of the present formulation. The results obtained from the present formulation are compared with those available in the literature. 相似文献
Wireless Personal Communications - The localization is a process of finding out the exact location of sensor nodes. For underwater, it is very difficult task to locate sensor nodes as the... 相似文献
Graphene has been conjugated with Silicene which is a 2D nanosheet of silicon crystal to analyze myriad physico-chemical properties. Upon intercalation of silicene between two graphene nanosheets, there has been a significant shift in the energy of electronic configuration at different isovalues from − 0.12 to + 0.12. Similarly, by analyzing the electronic energy states of silicene–graphene–silicene, a range of isovalues from − 0.08 to + 0.08 were observed. I–V curve exhibited a linear response for graphene–silicene–graphene sandwiched structure and a semiconducting like behavior for silicene–graphene–silicene structure. Band gap measurement in case of graphene–silicene–graphene system is reported to be ~ 0.18 eV, which is a narrow region. While in case of silicene–graphene–silicene, a band gap value of ~ 1.01 eV is calculated that appears to be a pretty broad region. Transmission spectrum also shows intensity in peaks for Gr–Si–Gr case as compared to Si–Gr–Si combinations. Silicon is widely perceived to exhibit outstanding semiconducting behavior and has already been used in devising various electronic devices. In this present work, we try to analyze the outcome of the silicene and graphene at the nanometer scale in various combinations in a bid to understand the potential interaction mechanism between the two nanosheets which would help in the fabrication of the silicene–graphene based optoelectronic devices.
In this article, microwave electromagnetic properties of doped strontium hexaferrites have been investigated in Ku microwave frequency band (12.4–18 GHz), along with their performance as microwave absorbing materials. Vector network analyzer has been used for characterization of cobalt-zirconium substituted strontium hexaferrites Sr(CoZr)xFe(12?2x)O19 (x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0), synthesized using sol-gel method. Real parts of permittivity and permeability have shown very small variations up to 16 GHz. There has been a dip in spectrum of real part of permittivity and a peak in spectrum of real part of permeability at the same frequency in 16–18 GHz range for every composition. Regarding the electromagnetic wave absorption, all the six prepared compositions have potential (≥90% absorption) for usage in suppressing electromagnetic pollution. The composition with x = 1.0 has achieved the highest ?10 dB absorption bandwidth from 15 to 18 GHz frequency. The realization of absorbing materials with maximum absorption is related to the phenomenon of impedance matching and high electromagnetic losses. The correlation of absorption peaks with attenuation constant, wave impedance and complex thickness has also been studied. 相似文献