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991.
Abstract

It has been proposed that, regardless of origin, the recovery of bitumen from oil sands is related to its viscosity. Asphaltene and resin contents are known to affect the viscosity of bitumen. In this article we compare the composition of solvent-extracted bitumens from several Athabasca oil sands with very different recovery profiles. After careful removal of any associated mineral matter by ultra-centrifugation, each bitumen sample was separated into saturate, aromatic, resin, and asphaltene (SARA) fractions by an enhanced SARA technique. The individual components were then characterized by several complementary analytical techniques, including carbon, nitrogen, nitrogen, sulfur, size exclusion chromatography molecular weight (MWn) plus proton and 13C nuclear magnetic resonance spectroscopy. Based on this comparison, we see no correlation between the recovery of bitumen and its composition.  相似文献   
992.
A unification of network coding and tree-packing (routing) theorems   总被引:1,自引:0,他引:1  
Given a network of lossless links with rate constraints, a source node, and a set of destination nodes, the multicast capacity is the maximum rate at which the source can transfer common information to the destinations. The multicast capacity cannot exceed the capacity of any cut separating the source from a destination; the minimum of the cut capacities is called the cut bound. A fundamental theorem in graph theory by Edmonds established that if all nodes other than the source are destinations, the cut bound can be achieved by routing. In general, however, the cut bound cannot be achieved by routing. Ahlswede et al. established that the cut bound can be achieved by performing network coding, which generalizes routing by allowing information to be mixed. This paper presents a unifying theorem that includes Edmonds' theorem and Ahlswede et al.'s theorem as special cases. Specifically, it shows that the multicast capacity can still be achieved even if information mixing is only allowed on edges entering relay nodes. This unifying theorem is established via a graph theoretic hardwiring theorem, together with the network coding theorems for multicasting. The proof of the hardwiring theorem implies a new proof of Edmonds' theorem.  相似文献   
993.
Abstract: This research used PC ARC/INFO, a geographic information system (GIS), to assess the potential seismic vulnerability of essential facilities in Memphis and Shelby County, Tennessee. The GIS is a powerful tool for spatial operations. It offers a link between spatial data in a computerized map form and related nonspatial attribute files. It has the ability to overlay, compare, and analyze several maps in digital form with speed and efficiency. In order to assess the potential vulnerability of essential facilities, evaluation criteria with rational weighting (including soil type, liquefaction potential, slope, foundation, structural conditions, and important elements of bridges such as detour length and average daily traffic) were identified. This research proved that GIS is a reliable and efficient tool for vulnerability assessment of essential facilities in an earthquake-prone area. The GIS is convenient and productive in data management. It is easy to produce special-purpose maps at selected scale and tabular analysis reports in desired format. Results of the study are important for future facility maintenance and improvement and earthquake preparedness /response planning.  相似文献   
994.
从国务院国资委获悉,《关于推进国有资本调整和国有企业重组的指导意见》出台十项措施促进国企改革重组,并明确到2010年中央企业调整重组至80到100户。  相似文献   
995.
    
A new water‐soluble methacrylate/2‐acrylamido‐2‐methylpropane sulfonate copolymer (PMAMP) was synthesized and evaluated as a dispersion agent for cement particles. PMAMP was prepared from methacrylic acid and 2‐acrylamido‐2‐methylpropane sulfonic acid (AMP). The structure of the prepared polymer was verified by its NMR and IR spectra. The dispersing properties of PMAMP were evaluated by a minislump test on cement pastes. The test results indicated that this copolymer could disperse the cement particles and improve the minislump of cement pastes. Compared with a commercial superplasticizer (sulfonated naphthalene formaldehyde condensates), PMAMP performed better in enhancing the fluidity of the cement pastes. The polymer with about 40–50% AMP and a weight‐average molecular weight of about 5 × 104 was most effective in dispersing cement particles and promoting the fluidity of cement pastes. Nevertheless, PMAMP with a higher AMP content or a higher molecular weight appeared to cause less slump loss. This was related to the interaction of this admixture with the cement particles and its adsorption behavior onto the cement particles. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2490–2496, 2006  相似文献   
996.
    
The effect of the molecular structure of an amphoteric copolymer, i.e., poly[acrylamide/(α‐N,N‐dimethyl‐N‐(3‐(β‐carboxylate)acrylamino)propyl)ammonium ethanate)] (PAD) on the interactions with BaTiO3 (BT) particles in water and on the stability of BT suspensions was examined by means of adsorption, ζ potential, sedimentation, and viscosity measurements. The results indicate that the adsorption of PAD onto BT particles follows the Langmuir adsorption isotherm. As the added PAD containing greater ionic group fraction, both the saturated amount of adsorbed polymer and the amount of the polymer required to reach the minimal ζ potential decrease. Whatever the ionic group fraction in PAD, BT suspensions become stable and less viscous when saturated amount of the polymer was adsorbed on particle surface. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007  相似文献   
997.
    
We describe a facile and eco‐friendly solution approach to chemically reduce graphene oxide (GO) to high‐quality graphene using nontoxic inexpensive reductants. The reduction process and mechanism of a group of eco‐friendly reductants were systematically studied. These reductants perform quite differently in terms of reduction rate (l ‐ascorbic acid [l ‐AA] > d ‐fructose > sucrose > glucose > sodium sulfite), density of small sp2 domains (l ‐AA > sodium sulfite > glucose > sucrose > d ‐fructose), degree of reduction (l ‐AA > glucose > d ‐fructose > sodium sulfite > sucrose), and stability of the reduced GO suspension (l ‐AA > d ‐fructose > sucrose > glucose > sodium sulfite). l ‐AA shows the highest reducing ability, achieving the largest extent of reduction after 10 min in the presence of ammonia. Both residual oxygen functionalities and the adsorbed oxidization products of l ‐AA on the graphene surface are responsible for stabilizing the reduced GO suspension over several months. © 2014 American Institute of Chemical Engineers AIChE J, 60: 2757–2764, 2014  相似文献   
998.
    
We present the first investigation of photoisomerization of the azo‐based electroactive polyimide (PI)/amino‐functionalized multiwalled carbon nanotube (MWCNT) composite electrode on the effect of electrochemical sensing for ascorbic acid (AA). First, MWCNTs were grafted with 4‐aminobenzoic acid in a medium of polyphosphoric acid/phosphorous pentoxide to obtain MWCNTs functionalized with 4‐aminobenzoyl groups (AF‐MWCNTs). Subsequently, photoactive and electroactive PI/AF‐MWCNT composites (PEPACCs) were prepared by introducing pendant conjugated oligoaniline (amino‐capped aniline trimer) in the main chain and azobenzene chromophores in the side chain, in the presence of AF‐MWCNTs. Photoactive and electroactive PI (PEPI) and PEPACCs were characterized by 1H NMR spectra, UV?visible absorption spectra, cyclic voltammetry (CV) and transmission electron microscopy. The CV study shows that the PEPACCs have higher electroactivity than PEPI. The redox and reversible photoisomerization (i.e. cis ? trans) behavior of PEPACCs was analyzed by in situ monitoring through systematic studies of CV and UV?visible spectroscopy. The light of the UV lamp was 365 nm. It should be noted that the sensor constructed from a trans‐PEPACC‐modified carbon‐paste electrode (CPE) demonstrated a higher electrocatalytic activity by 2.75‐fold and 1.12‐fold towards the oxidation of AA compared with those constructed using a PEPI‐ and cis‐PEPACC‐modified CPE, respectively. The detection limit of the trans‐PEPACC‐modified electrode was 1.73‐fold and 1.70‐fold lower than that of PEPI‐ and cis‐PEPACC‐modified CPE. Moreover, the differential pulse voltammetry data showed that the trans‐PEPACC‐modified electrode had high electrochemical sensing ability for the determination of AA, dopamine and uric acid. © 2014 Society of Chemical Industry  相似文献   
999.
    
S.C. Kung 《Electrochimica acta》2010,55(27):8074-1606
We report the fabrication of silver nanowires using lithographically patterned nanowire electrodeposition (LPNE). The LPNE synthesis of silver nanowires proceeds by lithographically patterning, and then etching an evaporated nickel film to produce a nickel nanoband 20-80 nm in height. This nanoband, which traces the perimeter of the exposed region, is recessed by ≈500 nm into the photoresist producing a horizontal trench. A silver nanowire, of controlled height and width, is formed within this trench by electrodepositing silver from either of two aqueous solutions at the nickel nanoband. Silver nanowires with controlled widths ranging from 100 to 400 nm were obtained and the height of silver nanowires was independently controllable over the range from 20 to 80 nm. The LPNE process is wafer-scale and continuous silver nanowires millimeters in length are readily obtained. Data for the characterization of these nanowires using AFM, TEM, and XRD is presented.  相似文献   
1000.
    
An amphoteric water‐soluble copolymer, i.e., poly(methacrylate‐coN‐(4‐vinylbenzyl)‐N,N‐dimethylglycinate) (PMV) was synthesized and used as a dispersion agent for barium titanate (BaTiO3) (BT) particles. PMV was prepared from methacrylic acid and N‐(4‐vinylbenzyl)‐N,N‐dimethylglycinate in basic conditions through free radical polymerization. The structure of this copolymer was verified by its IR and 1H‐NMR spectra. The dispersing effects of PMV were examined and evaluated through viscosity and sedimentation measurements. The results indicate that this copolymer could uniformly disperse the particles, make the resulting suspensions less viscous and more stabilized. The dispersing ability of PMV is better than that of a commercial dispersant, ammonium polymethacrylate (PMAAN). Accordingly, the BT compacts with PMV exhibit higher dielectric constant values than those with PMAAN. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010  相似文献   
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