Modification of poly(vinyl chloride). XXXIII. Novel poly(vinyl chloride) foam crosslinked with 6-dibutylamino-1,3,5-triazine-2,4-dithiol

The formulation for producing the PVC foam crosslinked with a novel crosslinking agent such as 6-dibutylamino-1,3,5-triazine-2,4-dithiol (DB) was studied to determine the processing conditions. DB was almost consumed by radical combination with a coexistent blowing agent such as azobisformamide to give a high-density foam with excessively low crosslinking density. Blowing agents such as p-toluenesulfonylhydrazide (TSH) and 4,4′-oxybis(benzenesulfonylhydrazide) (OBSH) gave a crosslinked foam of low density, while a combination of the two crosslinking agents had moderate crosslinking reaction rate. The formulation recommended in the present study consists of PVC Zeon 101EP or Zeon 121 for paste, 100 parts; DOP, 100 parts; DB, 3–5 parts; OBSH or TSH, 10 parts; MgO, 1–3 parts; and RP101 (mixture of Ba, Ca, and Zn stearate), 2 parts, which gave colorless and insoluble foam of apparent density 0.14 under hot pressing at 180°C. The molded foam could be released without extraction of heat from a hot mold for fusion and expansion.     

Long-term variation in the North Pacific using satellite-derived wind data set/J-OFURO over the last decade and other data sets over a longer record

Time series of gridded data sets of surface winds (from Qscat (J-OFURO)) constructed by satellite microwave sensors covering almost a decade (1999–2009) are used to examine long-term change in surface wind fields over the world’s oceans. Evidence has been provided by most previous studies that wind speeds have a tendency to increase over time in many area, and we verify whether or not this tendency persists. Results reveal that zonal winds tended to be weaker over the study period in the region of the North Pacific where westerly winds prevail. Time series of different types of data sets based on numerical model products and voluntary ship measurements present similar features of weakening westerly winds, even allowing for discrepancies among the data sets. These time series also exhibit a tendency of enhanced westerly winds in periods prior to the start of the twenty-first century, which means that the long-term trend in wind speed has changed from positive in the 1980s/1990s to negative in the 2000s. Examinations of time series for each season reveal that the above feature is found in winter, suggesting that it is related to the strength of the Aleutian Low.     

Polypeptide spheres. VII. Macroreticulation of spherical poly(γ-methyl-L-glutamate) beads

Spherical beads from poly(γ-methyl-L -glutamatate) alone were prepared using various diluents for macroreticulating by the “suspension and evaporation” method. The porosity and the pore size of the beads obtained were remarkably dependent on the chemical structure of a diluent. This is related to the specific miscibility of a diluent with poly(γ-methyl-L -glutamate). For example, decahydronaphthalene made the beads much more macroporous than tetrahydronaphthalene with similar hydrophobisity: the aromaticity of diluent increases the miscibility. However, it was found that long-chain alkyl compounds with a miscible group such as methyl dodecanoate, oleic acid, linoleic acid, and dialkyl-phthalate were not only very effective for macroreticulating, but also induced narrow pore-size distribution. In addition, the diluent influenced physicochemical properties of the beads to cause specific affinity to proteins.     

Anatase Titanium Dioxide Crystallization by a Hydrolysis Reaction of Titanium Alkoxide without Annealing

The crystallization of anatase titanium dioxide (TiO₂) was achieved by a hydrolysis reaction of titanium alkoxide without annealing. The hydrolysis reaction rates of tetraethyl orthotitanate were indicated by a function of the concentration of acetylacetone added. The degree of crystallinity of the product particles was influenced by the amounts of acetylacetone and seed crystals. Anatase TiO₂ was crystallized by restraining the rapid increase in supersaturation of TiO₂ and the consequent nucleation of amorphous TiO₂. The degree of crystallinity of the product particles also changed with the types of seed crystals used, and was strongly influenced by the specific surface areas of the seed crystals.     

Discharge through a Permeable Rubble Mound Weir

The hydrodynamics of a rubble-mound weir are theoretically and experimentally examined. This type of weir is considered to be environmentally friendly, since its permeability allows substances and aquatic life to pass through longitudinally. By performing a one-dimensional analysis on a steady nonuniform flow through the weir, discharge is described as a function of related parameters, such as flow depths on the up- and downstream sides of the weir, porosity, and grain diameter of the rubble mound, weir length, etc. A laboratory experiment is carried out to determine the empirical coefficients included in the analytical model. The theoretical solution of the discharge is compared with the experimental data to verify the analysis. It is confirmed that agreement between theory and experiment is satisfactory for a wide range of flow conditions. The present study makes it possible to apply the rubble mound weir for practical use as a discharge control system.     

Estimating mean life of an aged power equipment group with operation data sequence

This paper proposes a systematic method of estimating the mean life of an aged power equipment group based on the approach of Dr. W. Li of BCTC, Canada (IEEE Transactions on Power Systems, February 2004). In order to estimate the mean life of aged power equipment systematically and effectively with the operation data sequence, a linear estimation method is developed on the assumption that the stochastic behavior of aged equipment life determines the probability distribution model, such as the normal model or the Weibull model. Introductory and practical examples are illustrated for verification of the proposed approach. © 2009 Wiley Periodicals, Inc. Electr Eng Jpn, 170(4): 18–25, 2010; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20961     

Decomposition of 2-bromophenol in NaOH solution at high temperature

2-Bromophenol was reacted in aqueous sodium hydroxide at 200-250 degrees C. The decomposition rate was remarkably faster at 250 degrees C than at 225 or 200 degrees C, and the percentage debromination reached almost 100% in 1M NaOH at 250 degrees C for 4h. The percentage increased with NaOH concentration over the range 0.1-1M. Aliphatic compounds, such as 2,2-dimethoxypropane and 4-hydroxy-4-methyl-2-pentanone, and aromatic compounds, such as phenol and cresol, were formed as decomposition products. The formation of carboxylic acids, such as formic, acetic, and propionic acids, in the presence of oxygen was also confirmed. Under a nitrogen atmosphere, the oxidation caused by oxygen in solution was suppressed and hydrolysis became the dominant reaction in the decomposition of 2-bromophenol.     

Tracking and readout characteristics of a minute aperture mounted optical head slider flying above a chromium patterned medium

Recent rapid progress in a digital network society necessitates storage devices with higher-density and faster transfer rates. In optical storage, a novel recording principle is eagerly awaited that will drastically improve recording density without being restricted by a wavelength shortening limit or a numerical aperture (NA) limit of the optics utilized. Storage based on the “near-field” principle is thought to be one of the most promising breakthroughs for overcoming various limitations governing traditional optical recording. We have already proposed an integrated optical head slider assembly that relies on the novel near-field principle for its operation; it is mounted on a minute tapered aperture and has a planar focusing lens and a micro silicon mirror. Readout signals corresponding to a 200-nm-long bit have demonstrated a frequency band up to approximately 10 MHz, using a chromium patterned medium. In this study, we have investigated the accuracy of the tracking characteristics of an aperture-mounted head slider by using linearly arranged 1-mm-long line-and-space patterns. Based on the step or inverse step responses that occur when an aperture flies obliquely across the linearly arranged pattern region boundary, we present a simple method of predicting accurate tracking characteristics in detail, and also by using a 350-nm line-and-space pattern signal, we were able to predict both tracking characteristics and tracking sensitivities of arbitrary wide tracks to a track width of 100 nm.     

Readout characteristics of a non-circular aperture mounted on an optical head slider flying above a medium having sub-100-nm-long patterns

The near-field principle combined with thin-film gas-lubricated slider bearing technology is thought to be one of the most promising breakthroughs to overcome the difficult optical diffraction limit (or wavelength shortening limit), which governs traditional optical recording performance. In light of this, we have demonstrated high linear density (150 nm pattern length) and high speed 10 MHz readout signals using the combination of a tapered circular aperture and a planar lens mounted on a quartz slider, flying above a metal patterned medium. In order to further improve both the spatial resolution and signal-to-noise ratio of this device, it is essential to minimize the spacing and laser power throughput of an aperture. Also investigated was the effectiveness of a non-circular aperture, which has approximately triangular configuration in combination with polarized light in simultaneously improving spatial resolution and increasing signal output. In this paper, we confirmed the predicted effectiveness on more practical condition of both high speed and compactness of head construction using a sub-micrometer size non-circular aperture, which was mounted on a 1.5-mm-long miniaturized optical head slider, flying above a ROM medium having sub-100-nm-long chromium patterns. The influence of the electric-field direction of the incident light and aperture to medium spacing on the readout signal are carefully evaluated by flying the aperture at spacing down to less than 50 nm.