全文获取类型
收费全文 | 652篇 |
免费 | 5篇 |
国内免费 | 2篇 |
专业分类
电工技术 | 49篇 |
综合类 | 8篇 |
化学工业 | 288篇 |
金属工艺 | 15篇 |
机械仪表 | 10篇 |
建筑科学 | 10篇 |
能源动力 | 33篇 |
轻工业 | 28篇 |
水利工程 | 1篇 |
无线电 | 42篇 |
一般工业技术 | 89篇 |
冶金工业 | 28篇 |
原子能技术 | 30篇 |
自动化技术 | 28篇 |
出版年
2022年 | 3篇 |
2021年 | 8篇 |
2019年 | 3篇 |
2018年 | 6篇 |
2017年 | 4篇 |
2016年 | 5篇 |
2015年 | 7篇 |
2014年 | 8篇 |
2013年 | 15篇 |
2012年 | 18篇 |
2011年 | 26篇 |
2010年 | 14篇 |
2009年 | 25篇 |
2008年 | 26篇 |
2007年 | 24篇 |
2006年 | 23篇 |
2005年 | 13篇 |
2004年 | 15篇 |
2003年 | 23篇 |
2002年 | 24篇 |
2001年 | 12篇 |
2000年 | 10篇 |
1999年 | 19篇 |
1998年 | 15篇 |
1997年 | 13篇 |
1996年 | 17篇 |
1995年 | 21篇 |
1994年 | 14篇 |
1993年 | 17篇 |
1992年 | 13篇 |
1991年 | 10篇 |
1990年 | 9篇 |
1989年 | 12篇 |
1988年 | 5篇 |
1987年 | 14篇 |
1986年 | 15篇 |
1985年 | 16篇 |
1984年 | 16篇 |
1983年 | 16篇 |
1982年 | 12篇 |
1981年 | 18篇 |
1980年 | 13篇 |
1979年 | 21篇 |
1978年 | 14篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1975年 | 7篇 |
1972年 | 2篇 |
1971年 | 2篇 |
1968年 | 2篇 |
排序方式: 共有659条查询结果,搜索用时 31 毫秒
51.
Hideshi Suzuki Masahiro Ogawa Kenji Hironaka Kunio Ito Hisakazu Sunada 《Drug development and industrial pharmacy》2001,27(9):951-958
Nifedipine is a poorly water soluble drug that demonstrates low bioavailability. In a previous study, a coground mixture of nifedipine with sodium deoxycholate (DCNa), a bile salt, immediately produced colloidal particles when dispersed in water. In this study, the effect of the weight fraction of DCNa, grinding time, dissolution media, and storage conditions on colloidal particle formation in solution was investigated. The coground mixture was prepared with a vibration rod mill, and its solid state was characterized using powder X-ray diffraction. A laser diffraction particle size analyzer was used to determine the particle size distribution curve in water. The size of particles formed in solution decreased with an increase in the weight fraction of DCNa and grinding time. A nifedipine-DCNa (1 : 2 w/w) mixture coground for 30 min was used in the experiments. Colloidal particle formation from the coground mixture was also observed in dissolution media of water and a pH 6.8 buffer solution at 37°C. Most precipitates passed through a filter with a pore size of 0.8 μm, but the particle size distribution in water was different from that in the pH 6.8 buffer solution. DCNa exhibited not only micellar solubilization for drug crystals, but also a retarding effect on drug crystal growth in a supersaturated solution. The latter effect could serve to form colloidal particles in solution. When stored under 75% relative humidity at 40°C for 1 month, the amorphous coground mixture crystallized, and the particle size in water markedly increased. Therefore, the weight fraction of DCNa, grinding time, dissolution media, and humidity during storage influence the dissolution characteristics of nifedipine from a coground mixture. 相似文献
52.
Shigeru Okada Toetsu Shishido Takao Mori Kiyokata Iizumi Kunio Kudou Kazuo Nakajima 《Journal of Alloys and Compounds》2008,458(1-2):297-301
LEAlB14 (orthorhombic, Imam) (LE = Li, Mg) crystals were grown using metal salts (Li2CO3, LiF, LiI, MgO, MgF2, MgI2) and crystalline boron from a high-temperature aluminium metal flux. The growth conditions for growing LEAlB14 were established using the starting mixtures of B/LE = 2.0, and Al metal was added to each mixture at a mass ratio of 1:15–20. LEAlB14 crystals from the Al-self flux using metal salts could be obtained from all the different salts. The maximum dimensions of LiAlB14 and MgAlB14 crystals were approximately 18 and 12 mm for the crystals obtained from LiF and MgF2. The unit-cell parameters of as-grown LEAlB14 are as follows: for LiAlB14, obtained from LiF, a = 0.5846 (2) nm, b = 0.8144 (2) nm, c = 1.0355 (3) nm, V = 0.4930 (2) nm3: for MgAlB14, obtained from MgF2, a = 0.5845 (2) nm, b = 0.8114 (2) nm, c = 1.0330 (3) nm, V = 0.4899 (3) nm3. Microhardness, oxidation resistance and magnetic susceptibility of these materials are described in detail. 相似文献
53.
Kunio Matsui Jun Kikuma Masamichi Tsunashima Tetsuji Ishikawa Shin-ya Matsuno Akihiro Ogawa Masugu Sato 《Cement and Concrete Research》2011,(5):510-519
The hydrothermal formation of tobermorite during the processing of autoclaved aerated concrete was investigated by in situ X-ray diffraction (XRD) analysis. High-energy X-rays from a synchrotron radiation source in combination with a newly developed autoclave cell and a photon-counting pixel array detector were used.To investigate the effects of the silica source, reactive quartz from chert and less-reactive quartz from quartz sand were used as starting materials. The effect of Al addition on tobermorite formation was also studied. In all cases, C-S-H, hydroxylellestadite and katoite were clearly observed as intermediates.Acceleration of tobermorite formation by Al addition was clearly observed. However, Al addition did not affect the dissolution rate of quartz. Two pathways, via C-S-H and katoite, were also observed in the Al-containing system. These results suggest that the structure of initially formed C-S-H is important for the subsequent tobermorite formation reactions. 相似文献
54.
Atsushi Tsutsumi Hidehiko Suzuki Yasushi Saito Kunio Yoshida Ryohei Yamazaki 《Powder Technology》1998,100(2-3):237-241
The granulation of multi-component particles was conducted in a fast fluidized bed with an atomizing binder solution. The effects of gas velocity and binder droplet diameter on granulation rate, granule size distribution and granule composition were studied. The granulation rate and granule yield were determined by the balance between the agglomeration rate of feed particles and the disintegration rate of granules because there was no secondary granulation. With the increase in gas velocity and the reduction in binder droplet size, the agglomeration rate of feed particles decreased but the disintegration rate of granules increased, resulting in a reduced granule yield. Despite the larger fraction of small particles in the granules, the homogenous granulation of multi-component particles was achieved. 相似文献
55.
Kunio Yoshikawa 《中国科学:信息科学(英文版)》2010,(1)
Drying of sewage sludge is an effective way for treatment and utilization of sewage sludge,where reduction of energy consumption is one of the major technical challenges.So we experimentally investigated the possibility of the hydrothermal treatment.We have found that treatment of sewage sludge by saturated steam with the temperature of 190°C and pressure of 20 bar can dramatically improve the dehydration performance of the slurry like product.And the water content can be reduced down to about 55% by a mech... 相似文献
56.
Methanol decomposition to synthesis gas over supported Pd catalysts prepared from synthetic anionic clays 总被引:2,自引:0,他引:2
Ryuji Shiozaki Takashi Hayakawa Yan-yong Liu Tomoko Ishii Mikio Kumagai Satoshi Hamakawa Kunio Suzuki Tatehiko Itoh Tetsuya Shishido Katsuomi Takehira 《Catalysis Letters》1999,58(2-3):131-140
Supported Pd or Rh catalysts were prepared by the solid-phase crystallization method starting from hydrotalcite anionic clay
minerals based on [Mg6Al2(OH)16CO
2
2−
]·4H2O as the precursors. The precursors were prepared by a coprecipitation method from the raw materials containing Pd2+ and various trivalent metal ions which can replace each site of Mg2+ and Al3+ in the hydrotalcite. Rh3+ was also used for preparing the catalyst as comparison. The precursors were then thermally decomposed and reduced to form
supported Pd or Rh catalysts and used for the methanol decomposition to synthesis gas. Among the precursors tested, use of
Mg–Cr hydrotalcite containing Pd2+ resulted in the formation of efficient Pd supported catalysts for the production of synthesis gas by selective decomposition
of methanol at low temperature. Although Pd2+ cannot well replace the Mg2+ site in the hydrotalcite, the Pd supported catalyst (Pd/Mg–Cr) prepared by the solid-phase crystallization method formed
highly dispersed Pd metal particles and showed much higher activity than that prepared by the conventional impregnation method.
When the precursor was prepared under mild conditions, more fine particles of Pd metal were formed over the catalyst, resulting
in high activity. It is likely that the high activity may be due to the highly dispersed and stable Pd metal particles assisted
by the role of Cr as the co-catalyst.
This revised version was published online in November 2006 with corrections to the Cover Date. 相似文献
57.
The Fushime geothermal field is located in a depression close to the coast line. The system is characterized by very high reservoir temperature (>350°C), and a high salinity production fluid. Geological analysis shows that the main reservoir in this field occurs in a fractured zone developed around a dacite intrusion located in the center of the field. High permeability zones recognized by drilling data are found to be associated with fault zones. One of these zones is clearly associated with a NW–SE trending andesite dike swarm which was encountered in some wells.Alteration in the system can be divided into four zones, in order of increasing temperature, based on calcium–magnesium aluminosilicate mineral assemblages: i.e., the smectite, transition, chlorite and epidote zones. The feed zone is located in the chlorite and epidote zones, which can be further divided into three sub-zones according to their potassium or sodium aluminosilicate mineralogy, from the center of the discharge zone: K-feldspar–quartz, sericite–quartz, and albite–chlorite zones.Chloride concentration of the sea-water is 19,800 mg/l, and Br/Cl mole ratio is 1.55. Based on geochemical information, the reservoir chloride concentration of this field ranges from 11,600 to 22,000 mg/kg. The Clres (Cl in reservoir), Br/Cl ratios and stable isotope data indicate that the Fushime geothermal fluid originated from sea-water and is diluted by ground water during its ascent. Some fluids produced from geothermal wells show low pH (about 4). It is thought that sulfide mineral (PbS, ZnS) precipitation during production produces this acidic fluid. 相似文献
58.
Summary Organoboron copolymers were prepared by polyaddition of diene mixture or diene/diyne mixture, respectively, with thexylborane (1). When a mixture of dienes such as 1,2-diallyloxyethane (2a) and p-diallylbenzene (2b) was polymerized with 1, the peaks in GPC using both UV and RI detectors were shifted to higher molecular weight regions with the increase of the amount of 1. The molecular weight distribution of the copolymer obtained by this method indicated clear difference from that of a mixture of two homopolymers. On the other hand, when the poymerization between 1 and 1,7-octadiene (2c) was carried out in the presence of a trace amount of 1,7-octadiyne (4), the molecular weights of organoboron polymers were found to be increased when the ratio of 4/2c was increased. 相似文献
59.
Yamada J. Miwa T. Koike H. Toyoshima H. Amanuma K. Kobayashi S. Tatsumi T. Maejima Y. Hada H. Mori H. Takahashi S. Takeuchi H. Kunio T. 《Solid-State Circuits, IEEE Journal of》2002,37(8):1073-1079
This paper describes a 128-kb FeRAM macro for smart-card microcontrollers. This macro, which was designed and fabricated using a 0.35-/spl mu/m three-metal CMOS and a Capacitor-on-Metal/Via-stacked-Plug (CMVP) process technology, is ideally suited for recent system LSIs such as smart-card microcontrollers. It has a flexible memory size ranging from 32 to 128 kb, a low consumption current of 0.3 mA, and endurance of more than 10/sup 8/ write/read cycles under a wide range of supply voltages, from 2.7 to 5.5 V. These characteristics, which are required of not only contact-type smart-card microcontrollers but also contactless-type ones, were achieved by using four newly developed circuit technologies: 1) a three-metal CMVP memory cell; 2) a voltage-regulating architecture; 3) a main/sub bitline and wordline structure; and 4) a dynamic-type offset sense amplifier. 相似文献
60.
Kunio Nakajima 《Water research》1986,20(11)
Particulate organic carbon (POC) in waters was determined by chemical oxidation method which has been widely used for the determination of total organic carbon and/or dissolved organic carbon. In this method, a water sample was filtered through a filter paper and the paper was placed in a glass ampoule, followed by the determination of POC with a total carbon analyzer. This paper discussed the problems of carbon contamination dissolving from filter papers. The selection of filter papers, the carbon blank values resulting from the papers and the pretreatment of the papers were studied. It became clear that the glass-fiber filter paper pretreated at 500°C for 8 h was superior to the filter papers treated under other conditions. The POC's in waters were determined by this method, and the results agreed well with those obtained by an ordinary dry combustion method. 相似文献