Highly active methanol decomposition catalyst derived from Pd‐hydrotalcite dispersed on mesoporous silica

Pd‐hydrotalcite (abbreviated as Pd(HT)) was dispersed on HMS (hexagonal mesoporous silica) by synthesizing Pd(HT) in an HMS suspension, and the resultant product (Pd(HT)/HMS) was used as a catalyst precursor for methanol decomposition to synthesis gas. The IR spectra of Pd(HT)/HMS showed all the bands of Pd(HT) and HMS with little shift, which indicated that Pd(HT) was synthesized in the Pd(HT)/HMS. Pd(HT)/HMS did not show the XRD pattern of Pd(HT) when the mass ratio of Pd(HT) to HMS was from 2/1 to 1/2. This indicated that Pd(HT) was formed in very small particles in the Pd(HT)/HMS after dispersion. Two endothermic peaks of Pd(HT) in the DTA curve shifted to lower temperatures in the Pd(HT)/HMS because the small Pd(HT) particles formed in the Pd(HT)/HMS were easily collapsed by heat treatment. Pd(HT)/HMS was thermally decomposed and reduced to form a supported Pd catalyst (abbreviated Pd(Mg(Al)O)/HMS) for methanol decomposition. Pd(Mg(Al)O)/HMS at 3.6 wt% showed a 52.5% conversion which was much higher than those over 3.6 wt% Pd(Mg(Al)O) (34.7%) and 3.6 wt% Pd/HMS (13.7%) for methanol decomposition at 523 K. The conversions of methanol over Pd(Mg(Al)O) and Pd/HMS increased with the increase in Pd loadings from 3.6 to 15 wt% and decreased when the Pd loadings were over 15 wt%. In contrast, the conversion over Pd(Mg(Al)O)/HMS increased with the increase in Pd loading even when the Pd loading was up to 30%. 30 wt% Pd(Mg(Al)O)/HMS showed a 91.7% conversion which was about twice that over 15 wt% Pd(Mg(Al)O) (47.1%) at 523 K. The Pd(Mg(Al)O)/HMS catalyst showed a larger BET surface area and Pd metal surface area than those of Pd(Mg(Al)O). By characterization using XPS analyses, the metal–support interaction between small Pd and small Mg(Al)O became stronger in the Pd(Mg(Al)O)/HMS catalyst. Large surface area, high Pd dispersion and strong metal–support interaction caused the high catalytic activity for methanol decomposition to synthesis gas over the Pd(Mg(Al)O)/HMS catalyst. This revised version was published online in July 2006 with corrections to the Cover Date.     

A 30-ns 256-Mb DRAM with a multidivided array structure

A 256-Mb DRAM with a multidivided array structure has been developed and fabricated with 0.25-μm CMOS technology. It features 30-ns access time, 16-b I/Os, and a 35-mA operating current at a 60-ns cycle time. Three key circuit technologies were used in its design: a partial cell array activation scheme for reducing power-line voltage bounce and operating current, a selective pull-up data-line architecture to increase I/O width and reduce power dissipation, and a time-sharing refresh scheme to maintain the conventional refresh period without reducing operational margin. Memory cell size was 0.72 μm². Use of the trench isolated cell transistor and the HSG cylindrical stacked capacitor cells helped reduce chip size to 333 mm²     

A 75-ch SQUID Biomagnetometer System for Human Cervical Spinal Cord Evoked Field

A 75-ch SQUID biomagnetometer system for the measurement of the cervical spinal cord evoked magnetic field (SCEF) was developed for the purpose of the noninvasive functional diagnosis of the spinal cord. The sensor array has 25 SQUID vector sensors arranged along the cylindrical surface to fit to the shape of the subject's neck. The magnetic fields, not only in the direction radial to the subject's body surface but also in the tangential direction, are observed in the area of 80 mm times 90 mm at one time. The dewar has a unique shape with a cylindrical main body and a protrusion from its side surface. The sensor array is installed in the protruded part. This design is optimized to detect magnetic signals at the back of the neck of the subject sitting in a reclining position. We applied the developed SQUID system to the cervical SCEF measurement of normal subjects who were given electric pulse stimulation to their median nerves at the wrists. The evoked magnetic signals were successfully detected at the cervixes of all subjects. A characteristic pattern of transition of the SCEF distribution was observed as a reproducible result and the signal components propagating along the spinal cord were found in the time varying SCEF distribution. We expect that the investigation of the propagating signal components would help to establish a noninvasive functional diagnosis of the spinal cord.     

Effects of neutral buried p-layer on high-frequency performance ofGaAs MESFETs

Fully ion-implanted n⁺ self-aligned GaAs MESFETs with Au/WSiN refractory metal gates have been fabricated by adopting neutral buried p-layers formed by 50-keV Be-implantation. S-parameter measurements and equivalent circuit fittings are discussed. When the Be dose is increased from 2×10¹² cm^-2 to 4×10¹² cm^-2, the maximum value of the cutoff frequency with a 0.2-μm gate falls off from 108 to 78 GHz. This is because a neutral buried player makes the intrinsic gate-source capacitance increase markedly, while its influence on gate-drain capacitance and gate-source fringing capacitance is negligible. The maximum oscillation frequency recovers, however, due primarily to the drain conductance suppression by the higher-concentration buried p-layer. An equivalent value of over 130 GHz has been obtained for both 0.2-μm-gate GaAs MESFETs