Thermoelectric power of single-phase samples of Tl2CaBa2Cu2O y and Ba2CaSr2Cu2O y

Single-phase 2122 samples of thallium and bismuth superconductors were made by the precursor matrix method. The thermopower of these samples was measured in the temperature range 250 K-T _c . The thermopower was positive and decreased linearly with increasing temperature aboveT _c (onset). The exponential enhancement of thermopower seen in the undoped and doped YBCO was not observed in these samples. The linear variation of thermopower can be explained on the basis of either a two-band model or a narrow band model.     

Easy Access to 1‐Amino and 1‐Carbon Substituted Isoquinolines via Cobalt‐Catalyzed C?H/N?O Bond Activation

A green atom‐economical method for the synthesis of highly functionalized 1‐amino and 1‐carbon substituted isoquinolines from the reaction of N′‐hydroxybenzimidamides and aryl ketoximes, respectively, with alkynes via pentamethylcyclopentadienylcobalt(III)‐catalyzed C H/N O bond activation is described. The external oxidant‐free annulation reaction uses the =NOH moiety in N′‐hydroxybenzimidamides or N‐aromatic ketone oximes as the directing group and internal oxidant. This first row transition metal‐catalyzed annulation serves as an efficient alternative for the synthesis of isoquinolines, as water is the only by‐product and expensive noble metals such as rhodium(III), iridium(III), palladium(II), and ruthenium(II) are not required. The reaction proceeds via C H activation, alkyne insertion, reductive elimination, and N O activation.

     

Prediction of tensile strength of friction stir welded aluminium matrix TiCp particulate reinforced composite

The usage of particulate reinforced metal matrix composite (MMC) is steadily increasing due to its properties such as high specific strength, high specific modulus and good wear resistance. Aluminium matrix composite (AMC) plays an important role to meet the above requirements. Effective utilization of AMC is based on not only its production but also on fabrication methods. Among AMCs, those based on particulate reinforcements are particularly attractive, due to their lower production costs. Aluminium matrix titanium carbide reinforced composite (Al–TiC_p) was produced in an inert atmosphere by indigenously developed Modified Stir Casting Process with bottom pouring arrangement (3–7% TiC by weight). Friction stir welding process (FSW) is employed to make weld joints. The welding parameters such as axial force, welding speed, tool rotational speed, percentage TiC addition etc., and profile of the tool were considered for analysis. In this study, an attempt is made to predict ultimate tensile strength (UTS) of the welded joints using a mathematical model. The FSW specimens without any post-weld heat treatment belonging to a different set of parameters tested, exhibited a high joint efficiency (most of them ranging from 90% to 98%) with respect to the ultimate tensile strength of the base material AA6061. It was found from the analysis of the model that the tool pin profile and the welding speed have more significant effect on tensile strength.     

Ultrasonic wave characteristics of a monolayer graphene on silicon substrate

The present work deals with an ultrasonic type of wave propagation characteristics of monolayer graphene on silicon (Si) substrate. An atomistic model of a hybrid lattice involving a hexagonal lattice of graphene and surface atoms of diamond lattice of Si is developed to identify the carbon-silicon bond stiffness. Properties of this hybrid lattice model is then mapped into a nonlocal continuum framework. Equivalent force constant due to Si substrate is obtained by minimizing the total potential energy of the system. For this equilibrium configuration, the nonlocal governing equations are derived to analyze the ultrasonic wave dispersion based on spectral analysis. From the present analysis we show that the silicon substrate affects only the flexural wave mode. The frequency band gap of flexural mode is also significantly affected by this substrate. The results also show that, the silicon substrate adds cushioning effect to the graphene and it makes the graphene more stable. The analysis also show that the frequency bang gap relations of in-plane (longitudinal and lateral) and out-of-plane (flexural) wave modes depends not only on the y-direction wavenumber but also on nonlocal scaling parameter. In the nonlocal analysis, at higher values of the y-directional wavenumber, a decrease in the frequency band gap is observed for all the three fundamental wave modes in the graphene–silicon system. The atoms movement in the graphene due to the wave propagation are also captured for all the tree fundamental wave modes. The results presented in this work are qualitatively different from those obtained based on the local analysis and thus, are important for the development of graphene based nanodevices such as strain sensor, mass and pressure sensors, atomic dust detectors and enhancer of surface image resolution that make use of the ultrasonic wave dispersion properties of graphene.     

A new method for reducing DNL in nuclear ADCs using an interpolation technique

The paper describes a new method for reducing the DNL associated with nuclear ADCs. The method named the “interpolation technique” is utilized to derive the quantisation steps corresponding to the last n bits of the digital code by dividing quantisation steps due to higher significant bits of the DAC, using a chain of resistors. Using comparators, these quantisation steps are compared with the analog voltage to be digitized, which is applied as a voltage shift at both ends of this chain. The output states of the comparators define the n bit code. The errors due to offset voltages and bias currents of the comparators are statistically neutralized by changing the polarity of quantisation steps as well as the polarity of analog voltage corresponding to last n bits) for alternate A/D conversion. The effect of averaging on the channel profile can be minimized. A 12 bit ADC was constructured using this technique which gives DNL of less than ±1% over most of the channels for conversion time of nearly 4.5 μs. Gatti's sliding scale technique can be implemented for further reduction of DNL. The interpolation technique has a promising potential of improving the resolution of existing 12 bit ADCs to 16 bit, without degrading the percentage DNL significantly.     

Evaluation of the antifungal activity of natural xanthones from Garcinia mangostana and their synthetic derivatives

A preparation procedure is described for producing specimen supports of evaporated germanium. The germanium film is used as a replacement for films of carbon and silicon when microanalytical techniques like energy dispersive X-ray microanalysis (XRMA) or electron energy loss spectroscopy (EELS) are focusing on particulates containing these elements. The supports can be produced with high reproducibility within a thickness range of 15 to 30 nm and of a quality suitable also for high resolution transmission electron microscopy.     

Protocols for watermark verification

In current digital watermarking schemes used to deter piracy of multimedia content, the owner typically reveals the watermark in the process of establishing piracy. Once revealed, a watermark can be removed. We eliminate this limitation by using cryptographic protocols to demonstrate the presence of a watermark without revealing it     

Relaxation in poly(alkyl methacrylate)s: Change of intermolecular coupling with molecular structure, tacticity, molecular weight, copolymerization, crosslinking, and nanoconfinement

The voluminous amount of data in the literature on the structural α- and the Johari-Goldstein β-relaxations of the poly(n-alkyl methacrylate)s allows a systematic study of the interrelation between the two important relaxation processes. The data bring out the systematic changes in the interrelation between the structural α- and the Johari-Goldstein β-relaxations with changes in molecular structure, molecular weight, tacticity and size (by nanoconfinement), and modifications by copolymerization, and crosslinking. The results can all be interpreted as primarily due to changes in intermolecular coupling, which have significant effects on the many-molecule dynamics constituting the structural α-relaxation, but not on the precursory Johari-Goldstein β-relaxation. Theoretically, the Coupling Model predicts a relation of intermolecular coupling (or degree of cooperativity of the α-relaxation) to the ratio of the α- and the β-relaxation times, and a correlation of intermolecular coupling to the steepness or “fragility” index. The predicted relation and correlation are compared with experimental data of the poly(alkyl methacrylate)s.     

Detection of stator short circuits in VSI-fed brushless DC motors using wavelet transform

The paper presents methodologies to detect and locate short-circuit faults on the stator winding of VSI-fed PM brushless dc motors. Normal performance characteristics of the motor are obtained through a discrete-time lumped-parameter network model. The model is modified to accommodate short-circuit faults in order to simulate faulty operation. Fault signatures are extracted from the waveforms of electromagnetic torque and phase-voltage summation using wavelet transform. Three independent detection techniques are introduced. Experimental measurements agree acceptably with simulation results, and validate the proposed methods. This work sets forth the fundamentals of an automatic fault detector and locator, which can be used in a fault-tolerant drive.