Kinematisch bedingte Auswanderungserscheinungen bei periodisch schwingenden Waagen

Zusammenfassung W?gungen auf Hebelwaagen sind statische Messungen. Der Schwerkraft der zu w?genden Masse wird von der Waage eine konstante Me?kraft entgegengesetzt. Da sich jedoch innerhalb des selbstanzeigenden Bereichs die Me?kraft unter ?nderung des Ausschlags der Hebelkette selbst?ndig einstellt, bilden Waagen schwingungsf?hige Systeme, und zwar im allgemeinen nichtlineare Schwinger mit entsprechenden Eigenschaften. Unter diesen nimmt das Auswandern der Anzeige eine besondere Stellung ein, weil sich dabei die Mittellage der Schwingung gegenüber der statischen Gleichgewichtslage verschiebt. Diese Verschiebung kann von einem W?ger oder einem Me?wertgeber grunds?tzlich nicht erkannt werden und geht voll als Fehler in die W?gung ein.     

Polymer solutions confined in slit-like pores with attractive walls: An off-lattice Monte Carlo study of static properties and chain dynamics

Summary Using a bead spring model of flexible polymer chains, the density profiles and chain configurational properties of polymer solutions confined between parallel plates were studied. A wide range of density , chain length N, and strength of a short-range attractive wall potential was investigated. Both a temperature T in the good solvent regime (T > , being the Theta temperature where a chain in unconfined bulk three-dimensional solution would behave ideally) and a temperature in the bad solvent regime (T < ) were considered. It is shown that phase separation in a polymer-rich and polymer-poor solution in the slit competes with polymer adsorption at the walls. A qualitative connection to the wetting behavior of semi-infinite polymer solutions is drawn. The acceptance rate for monomer motions was studied for various conditions, and profiles of monomer mobility across the slit were recorded. Also, average chain relaxation times were extracted from the time dependence of mean-square displacements. Although with increasing density the chain radii (at T > ) show a crossover from two-dimensional excluded volume behavior (R_g N² with = 3/4) to ideal random walk behavior ( = 1/2), the relaxation times show effective exponents Z_eff ( N^{Z eff}) that clearly deviate from the Rouse prediction in concentrated confined solutions.     

Rundschau

Ohne Zusammenfassung     

Untersuchungen an der Dieselmaschine

Zusammenfassung Der Arbeitsproze? der verlustlosen Luftspeicher-Dieselmaschine wird thermodynamisch untersucht. Durch den unterteilten Verdichtungsraum werden beim Arbeitshub Str?mungen im Zylinder erzeugt, die die Verbrennung beeinflussen. Es wird der zeitliche Verlauf des Zylinderund Speicherdruckes ermittelt. Aus der Untersuchung der Wechselbeziehung zwischen Zylinderund Speicher folgen alle Eigenschaften der Speichermaschine, insbesondere der Einflu? der Maschinenabmessungen, der Drehzahl, der Verbrennung im Zylinder und der Hilfsverbrennung im Speicher. W?hrend des Arbeitshubes sind zwei Wirbel wirksam: der Speicherwirbel und der Saugwirbel des Kolbens. Ihre Lage und St?rke wird abh?ngig von den Bauelementen der Maschine angegeben. Die Ergebnisse werden auf ein Zahlenbeispiel angewendet, wobei auch das Indikatordiagramm der verlustlosen Maschine erhalten wird. Der Einflu? von ?nderungen der verschiedenen Ver?nderlichen auf den Arbeitsproze? wird festgestellt. Aus dem Institut für Verbrennungskraftmaschinen und Technische W?rmelehre der Technischen Hochschule Hannover     

Unitary transformation between Cartesian- and polar-pixellated screens

A unitary transformation between Cartesian and polar pixellations of finite two-dimensional images is obtained from the su(2) model for discrete and finite signals. This transformation analyzes the original image into its finite Cartesian "Laguerre-Kravchuk" modes (involving Wigner little-d functions) and synthesizes it back using a polar mode basis with the same set of mode coefficients. The polar basis is derived from the quantum angular momentum theory, and its modes are given by Clebsch-Gordan coefficients.     

Interplay Between Wetting and Phase Behavior in Binary Polymer Films and Wedges: Monte Carlo Simulations and Mean Field Calculations

Confining a binary mixture, one can profoundly alter its miscibility behavior. The qualitative features of miscibility in confined geometry are ratheruniversal and shared by polymer mixtures as well as small molecules, but the unmixing transition in the bulk and the wetting transition are typically well separated in polymer blends. The interplay between wetting and miscibility of a symmetric polymer mixture via large-scale Monte Carlo simulations in the framework of the bond fluctuation model and via numerical self–consistent field calculations is studied. The film surfaces interact with the monomers via short ranged potentials, and the wetting transition of the semi–infinite system is of first order. It can be accurately located in the simulations by measuring the surface and interface tensions and using Young’s equation. If both surfaces in a film attract the same component, capillary condensation occurs and the critical point is close to the critical point of the bulk. If surfaces attract different components, an interface localization/delocalization occurs which gives rise to phase diagrams with two critical points in the vicinity of the pre-wetting critical point of the semi–infinite system. The crossover between these two types of phase diagrams as a function of the surface field asymmetry is studied. The dependence of the phase diagram on the film thickness Δ for antisymmetric surface fields is investigated. Upon decreasing the film thickness, the two critical points approach the symmetry axis of the phase diagram, and below a certain thickness Δ_tri, there remains only a single critical point at the symmetric composition. This corresponds to a second-order interface localization/delocalization transition even though the wetting transition is of first order. At a specific film thickness, Δ_tri, tricritical behavior is found. The behavior of antisymmetric films is compared with the phase behavior in an antisymmetric double wedge. While the former is the analog of the wetting transition of a planar surface, the latter is related to the filling behavior of a single wedge. Evidence for a second-order interface localization/delocalization transition in an antisymmetric double wedge is presented, and its unconventional critical behavior is related to the predictions of Parry et al. (Phys. Rev. Lett. 83:5535 (1999)) for wedge filling. The critical behavior differs from the Ising universality class and is characterized by strong anisotropic fluctuations.Invited paper presented at the Fifteenth Symposium on Thermophysical Properties, June 022–27, 2003, Boulder, Colorado, U.S.A.     

Uncertainty in Quantitative Electron Probe Microanalysis

Quantitative electron probe analysis is based on models based on the physics or x-ray generation, empirically adjusted to the analyses of specimens of known composition. Their accuracy can be estimated by applying them to a set of specimens of presumably well-known composition.     

Reduction of COD in wastewater from an organized tannery industrial region by Electro-Fenton process

Advanced oxidation processes (AOPs) have led the way in the treatment of aqueous waste and are rapidly becoming the chosen technology for many applications. In this paper, COD reduction potential of leather tanning industry wastewaters by Electro-Fenton (EF) oxidation, as one of the AOPs, was experimentally evaluated. The wastewater sample was taken from an outlet of an equalization basin in a common treatment plant of an organized tannery industrial region in Istanbul, Turkey. Treatment of the wastewater was carried out by an electrochemical batch reactor equipped with two iron electrodes, which were connected parallel to each other. The oxidation process was studied for optimization of H(2)O(2) and the electricity consumptions were observed at different contact times under different pH conditions (3.0, 5.0 and 7.2). In each case, electricity consumption for decreased COD mass was estimated. In this process, COD was reduced by 60-70% within 10 min. By taking into consideration the local sewerage discharge limit, applicability of EF process for the tannery wastewaters was evaluated.     

Top-down proteomics on a chromatographic time scale using linear ion trap fourier transform hybrid mass spectrometers

Proteomics has grown significantly with the aid of new technologies that consistently are becoming more streamlined. While processing of proteins from a whole cell lysate is typically done in a bottom-up fashion utilizing MS/MS of peptides from enzymatically digested proteins, top-down proteomics is becoming a viable alternative that until recently has been limited largely to offline analysis by tandem mass spectrometry. Here we describe a method for high-resolution tandem mass spectrometery of intact proteins on a chromatographic time scale. In a single liquid chromatography-tandem mass spectrometry (LC-MS/MS) run, we have identified 22 yeast proteins with molecular weights from 14 to 35 kDa. Using anion exchange chromatography to fractionate a whole cell lysate before online LC-MS/MS, we have detected 231 metabolically labeled (14N/15N) protein pairs from Saccharomyces cerevisiae. Thirty-nine additional proteins were identified and characterized from LC-MS/MS of selected anion exchange fractions. Automated localization of multiple acetylations on Histone H4 was also accomplished on an LC time scale from a complex protein mixture. To our knowledge, this is the first demonstration of top-down proteomics (i.e., many identifications) on linear ion trap Fourier transform (LTQ FT) systems using high-resolution MS/MS data obtained on a chromatographic time scale.