Physicochemical state of the nanotopographic surface of commercially pure titanium following anodization-hydrothermal treatment reveals significantly improved hydrophilicity and surface energy profiles

A method of coating commercially pure titanium (cpTi) implants with a highly crystalline, thin hydroxyapatite (HA) layer using discharge anodic oxidation followed by hydrothermal treatment (Spark discharged Anodic oxidation treatment ; SA-treated cpTi) has been reported for use in clinical dentistry. We hypothesized that a thin HA layer with high crystallinity and nanostructured anodic titanium oxide film on such SA-treated cpTi implant surfaces might be a crucial function of their surface-specific potential energy. To test this, we analyzed anodic oxide (AO) cpTi and SA-treated cpTi disks by SEM and AFM. Contact angles and surface free energy of each disk surface was measured using FAMAS software. High-magnification SEM and AFM revealed the nanotopographic structure of the anodic titanium oxide film on SA-treated cpTi; however, this was not observed on the AO cpTi surface. The contact angle and surface free energy measurements were also significantly different between AO cpTi and SA-treated cpTi surfaces (Tukey's, P < 0.05). These data indicated that the change of physicochemical properties of an anodic titanium oxide film with HA crystals on an SA-treated cpTi surface may play a key role in the phenomenon of osteoconduction during the process of osseointegration.     

Local plastic deformation in the vicinity of grain boundaries in Fe–3 mass% Si alloy bicrystals and tricrystal

Nanoindentation was used to study incipient plastic deformation in the vicinity of grain boundaries of different character in Fe–3 mass% Si alloy bicrystals and tricrystal. Pop-in events associated with the grain boundaries were observed in the load–displacement curves. From the pop-in hardness values, the critical stresses required to propagate the yield past the grain boundary were estimated to be in the range of approximately µ/400–µ/130 (where µ is the shear modulus) depending on the grain boundary character: the special boundaries usually had higher critical stresses than the general boundaries. A Hall–Petch (H–P) type relationship was found between the hardness and the distance of the indenter to the grain boundary. The H–P slopes obtained were approximately one order of magnitude lower than the macroscopic value of the H–P slope for the Fe–3 mass% Si alloy, and were generally lower for general grain boundaries than for special boundaries.     

Effect of physical activity on the distensibility of the aortic wall in healthy males

BACKGROUND AND PURPOSE: Diethylenetriamine penta acetic acid (99mTc-DTPA), a substance which indicates glomerular filtration, is distributed equally in blood and tissue after a bolus intravenously injection. Ambulatory Renal Monitor (ARM) is a portable and non invasive device which monitors extracorporeally the clearance of intravenously injected 99mTc-DTPA. We examined correlation between half-time of clearance estimated by ARM and glomerular filtration rare, and clinical usefulness of ARM for a renal function monitoring. MATERIALS AND METHODS: The purposes of this paper are to describe the results obtained through basic analysis experiments and reproducibility in normal control, and its clinical application for 9 renal transplant patients, three drug-induced renal damage, one acute renal failure, one hemolytic uremic syndrome (HUS), two chronic nephritis, one donor of renal transplantation, one ureteral tumor, three renal tumors, two ureteral stones, one bilateral hydronephrosis and two normal controls. The half time of clearance of the tracer measured by an ARM. (ARM-HTC) is compared with the half time of clearance of the tracer measured by repeated blood sampling (Sampling-HTC) as a golden standard, serum creatinine and creatinine clearance. RESULTS: A significant correlation (linear) was detected when ARM-HTC was compared with Sampling-HTC (r = 0.91), 1/serum creatinine (r = 0.85) or creatinine clearance (r = 0.82), although ARM-HTC showed a delay compared with Sampling-HTC. CONCLUSIONS: The reason of this delay may be due to a difference in half-time when the tracer distributed in the blood and tissue. The results indicate that the estimation of 99mTc-DTPA clearance by ARM is valuable for renal function evaluation in wide ranges of renal function and in different origins of renal dysfunction such as in renal transplantation.     

A study on technical feasibility of applying tubular linear induction motor to vertical movement

It is necessary for a linear induction motor (LIM) to have large thrust force in applications for the vertical movement. If it does not have sufficient thrust force, it cannot lift even itself. A ratio (thrust force/weight of motor), therefore, is the most important factor for the design of this motor. In this paper, assuming the LIM has no slot-effect and infinite length, a simple analytical model is introduced for steady-state operation. By comparison with the results of detailed numerical analysis, it is verified to be applicable for basic evaluation of the motor. The design of the motor for vertical movement is carried out and the ratio is maximized. The basic dimensions of a feasible motor are given for such application.     

Coordination Cyclopolymerization Behavior of Diethyl Bis(2,3-butadienyl)malonate by Allylnickel Catalyst

Summary The π-allylnickel-catalyzed coordination cyclopolymerization of a bis(allene) possessing a malonate moiety, diethyl bis(2,3-butadienyl)malonate, gave a polymer which is soluble in organic solvents. The polymer was composed of an almost comparable content of the 1,2- and the 2,3-polymerized units. The polymerization was supposed to proceed through the selective formation of a six-membered ring unit in the main chain by means of the cyclopolymerization of the bis(allene). That is, the intramolecular attack of the growing allylnickel species generated from the first allene moiety upon another one was supposed to give the 1,2-polymerized unit having the six-membered ring system while the intermolecular attack of the allylnickel species derived from the second allene provides the 2,3-polymized unit selectively as is the case of the monofunctional allenes. The effect of the polymerization conditions such as the concentration of the monomer on the polymerization behavior is also described.     

An airborne smoke sampling package for field measurements of fires

A unique airborne smoke sample package (ASSP) for determining the smoke yield of large fires has been developed. The uncertainty in the average smoke yield at the 95% confidence interval is about ±7% of the average of three repeat measurements. The ASSP, which weighs less than 4 kg, is light enough to be flown suspended below a tethered helium-filled balloon or attached to a small radio-controlled aircraft. Measurements are made by flying the sampling equipment into a fire's smoke plume. Additional smoke plume measurements that can be made with the ASSP include particle size distribution using a cascade impactor, smoke agglomerate structure using transmission electron microscope (TEM) grids, and polycyclic aromatic hydrocarbons (PAHs) analysis using various sorbent tubes. The application of the ASSP in measuring laboratory and large outdoors petroleum pool fires is discussed. Smoke yield values measured in field burns of Louisiana crude oil range from 0.080 to 0.137, and the primary sphere diameter of the agglomerates is as large as 0.15 µm.     

Modeling the Stress-Strain Relations of Sand in Cyclic Plane Strain Loading

A modeling procedure to simulate stress-strain relations of sand subjected to cyclic loading is proposed. Results from drained plane strain compression, extension, and cyclic loading tests on Toyoura sand are analyzed. The monotonic loading behavior is simulated by the generalized hyperbolic equation to use as the skeleton curves in the simulation of cyclic behavior. To construct hysteretic stress-strain curves based on the skeleton curves, the Masing’s rule is generalized to the proportional rule consisting of the internal and external rules. The drag rule is then introduced to simulate cyclic stress-strain behavior in which the stress amplitude increases at a decreasing rate during cyclic loading with a constant strain amplitude. It is assumed that any plastic shear strain increment taking place in a certain direction drags the whole skeleton curve for loading in the opposite direction towards the direction of the concerned shear strain increment. The measured cyclic stress-strain behavior is well simulated by the proposed method.     

Innervated liver plays an inhibitory role in regulation of food intake

BACKGROUND: With the onset of eating, the associated rise of dopamine in the lateral hypothalamus (LHA-DA) is thought to regulate quantity of food consumed per meal. Early release of LHA-DA induced by eating is facilitated by oronasal stimulation; we propose that the subsequent LHA-DA response induced by nutrients in the portal vein is dampened by the innervated liver. This was tested by measuring LHA-DA in normal rats: during parenteral feeding to bypass oronasal stimulation, while eating during parenteral feeding, and while eating only. METHODS: Rats had either total liver denervation or sham operation, with placement of a jugular vein catheter and LHA-DA microdialysis cannula. After a 3-week recovery period total liver denervated rats were randomized to parenterally fed, food only, and parenteral plus food groups each with sham-operated controls in which LHA-DA was measured. RESULTS: No difference in LHA-DA release in food only groups occurred between total liver denervated or sham-operated rats. A significantly higher rise in LHA-DA was observed in total liver denervated versus sham-operated rats in parenterally fed (129% +/- 4% versus 116% +/- 2%; p < 0.05) and parenteral plus food (151% +/- 4% versus 134% +/- 4%; p < 0.05) groups. CONCLUSIONS: In total liver denervation versus sham operation, an increase in LHA-DA release occurs during parenteral feeding and eating during parenteral feeding, suggesting that innervated liver inhibits LHA-DA release.