Transient behaviour of encapsulated enzyme reactor systems

Mathematical models are developed for the transient behaviour of encapsulated enzyme reactor systems such as the continuous stirred tank reactor (CSTR) and the packed bed tubular reactor. The rate processes taking place in the encapsulated enzyme bed are approximated by using a combined rate control model of enzyme reaction and membrane diffusion. The change in transient substrate concentration is obtained by using the developed rate expression in the material balance over the substrate as a function of time for the CSTR and as a function of time and position for the packed bed tubular reactor. The effects of various parameters such as the enzymic reaction rate constant, Michaelis constant, diffusional resistance of membranes, and Peclet number on the substrate concentration distribution, which varies with respect to operating time, are investigated. This study affords insight into the transient operating characteristics of the encapsulated enzyme reactor system. The results should be useful in understanding the start-up performance of the reactor systems and to control such reactor systems at desired operating conditions.     

High Temperature Oxidation of Steels in Air and CO2–O2 Atmosphere

Three kinds of hot rolled steel slabs, viz. high strength steel, bake hardened steel and low carbon steel, were oxidized isothermally between 1100 and 1250 °C for up to 2 hr in 1 atm of air and an 85%N₂–10%CO₂–5%O₂ gas mixture. The steels were oxidized in a similar fashion in both the atmospheres. The oxidation process followed an initial linear rate law, which then gradually transformed to a nearly parabolic rate law. Thick, porous and nonadherent scales formed rapidly, due to the high oxidation temperature. The scales formed consisted of Fe₂O₃,(Fe₂O₃+Fe₃O₄), (Fe₃O₄+Fe₂O₃ +FeO) and (FeO+Fe₃O₄) from the outer surface. The presence of supersaturated oxygen beneath the scale resulted in grain boundary oxidation and the formation of internal oxide precipitates.     

Intermetallic phase formation in directionally solidified Al−Si−Fe alloy

The present study has been undertaken to better understand the solidification behavior of Al−Si−Fe alloys containing 7wt.% Si and 0.9wt.% Fe, with particular regard to the formation of phase during controlled solidification and influence of growth rates on intermetallic phase selection. The alloys studied were Al-7Si-0.9Fe alloys, which were produced by a modified Bridgman solidification arrangement. These alloys were solidified unidirectionally with different growth rates (1–30mm/min). The solidified microstructure of these alloys consists of the growth of primary aluminum and multiple second phase reactions.     

A novel part-based approach to mean-shift algorithm for visual tracking

Visual tracking is one of the most important problems considered in computer vision. To improve the performance of the visual tracking, a part-based approach will be a good solution. In this paper, a novel method of visual tracking algorithm named part-based mean-shift (PBMS) algorithm is presented. In the proposed PBMS, unlike the standard mean-shift (MS), the target object is divided into multiple parts and the target is tracked by tracking each individual part and combining the results. For the part-based visual tracking, the objective function in the MS is modified such that the target object is represented as a combination of the parts and iterative optimization solution is presented. Further, the proposed PBMS provides a systematic and analytic way to determine the scale of the bounding box for the target from the perspective of the objective function optimization. Simulation is conducted with several benchmark problems and the result shows that the proposed PBMS outperforms the standard MS.

     

A high performance parallel DCT with OpenCL on heterogeneous computing environment

A noteworthy thing in desktop PCs is that they can provide a great opportunity to increase the performance of processing multimedia data by exploiting task- and data-parallelism with multi-core CPU and many-core GPU. This paper presents a high performance parallel implementation of 2D DCT on this heterogeneous computing environment. For this purpose, Intel TBB (threading building blocks) and OpenCL (Open Compute Language) are utilized for task- and data-parallelism, respectively. The simulation result shows that the parallel DCT implementations far the serial ones in processing speed. Especially, OpenCL implementation shows a linear speedup, a typical SIMD characteristic as the increase of 2D data sets.     

Polar-Cartesian Hybrid Transforms: A novel 2D range scan registration algorithm

Registration of range scans is commonly required in many localization and mapping algorithms. In this paper, we introduce a novel approach called Polar-Cartesian Hybrid Transforms for pair-wise registration of range scans. The proposed algorithm iteratively establishes correspondences by searching the points with closest polar angles in the polar coordinate frame. An angular look-up table is constructed based on the properties of the laser range finder to accelerate the searching procedure. In order to speed up the convergence, we compute the difference of polar range of every matched point pair to select the most contributing correspondences. After the correspondences are determined, the transformation is computed in Cartesian coordinate frame using a point-to-line metric. Combining the advantages of the polar and Cartesian coordinate frames, both robustness and efficiency are greatly improved compared with an up-to-date ICP algorithm.     

Metal Ions versus Protons: Tracking of Charge-Carrier Insertion into a Cathode Oxide in Aqueous Rechargeable Batteries

Protons in aqueous electrolytes can perform as an additional type of charge carrier for insertion/extraction in addition to the primary carrier cations in aqueous rechargeable batteries. Despite many diverse claims regarding the effect of protons, mutually conflicting experimental results and their interpretations without direct evidence have been reported over the last decade. Systematic examinations and analyses are thus imperative to clarify the conditions of proton insertion in aqueous rechargeable batteries. Utilizing V₂O₅ as a model cathode and beaker-type cells with a sufficient amount of ZnSO₄ aqueous electrolytes in this work, it is demonstrated that protons are inserted into the cathode prior to Zn-ions in low-pH conditions (pH ≤ 3.0). In stark contrast, the influence of protons on the discharge voltage and capacity is insignificant, when either the pH becomes higher (pH ≥ 4.0) or the electrolyte volume is considerably low in coin-type cells. Similar behavior of pH-dependent proton insertion is also verified in Na–, Mg–, and Al-ion electrolytes. Providing a resolution to the controversy regarding proton insertion, the present study emphasizes that the influence of protons substantially varies depending on the pH and relative volume of electrolytes in aqueous batteries.     

Neutron diffraction texture study of deformed uranium plates

The texture of two depleted uranium (DU) samples, labelled DUWR and DUWR2, were studied by neutron diffraction. DUWR was prepared by warm rolling of a cast ingot, and DUWR2 was prepared by adding 20% tensile strain to the warm-rolled DUWR. Complete three-dimensional orientation distribution functions were determined using four neutron pole figures for the DUWR, and using six neutron pole figures for the DUWR2 sample, by the WIMV method of the program popLA. The textures of the two samples were essentially identical to each other. They could be described by a twisted helical density tube spiralling continuously along the -axis of the Euler space. The projection of the backbone of the density tube along the -axis cast a linear shadow running parallel to the diagonal of the - plane, which could be defined by a =+90° (and =+270°) relation. The helical tube was confined within narrow -angle limits, from 14° to 30° with the peak orientation at (103) 0 10. The diffraction patterns of the DUWR2 sample were measured from the normal direction to the rolling surface of the sample, up to the scattering angle of 108° using a 0.15 nm neutron beam. The Rietveld profile refinement using the textured diffraction pattern was quite satisfactory when the texture effect to the entire diffraction profile was corrected for by the corresponding pole density from the inverse pole figure.     

Mobile robot localization with gyroscope and constrained Kalman filter

The odometry information used in mobile robot localization can contain a significant number of errors when robot experiences slippage. To offset the presence of these errors, the use of a low-cost gyroscope in conjunction with Kalman filtering methods has been considered by many researchers. However, results from conventional Kalman filtering methods that use a gyroscope with odometry can unfeasible because the parameters are estimated regardless of the physical constraints of the robot. In this paper, a novel constrained Kalman filtering method is proposed that estimates the parameters under the physical constraints using a general constrained optimization technique. The state observability is improved by additional state variables and the accuracy is also improved through the use of a nonapproximated Kalman filter design. Experimental results show that the proposed method effectively offsets the localization error while yielding feasible parameter estimation.     

Improving traversability of quadruped walking robots using body movement in 3D rough terrains

This paper presents a study on improving the traversability of a quadruped walking robot in 3D rough terrains. The key idea is to exploit body movement of the robot. The position and orientation of the robot are systematically adjusted and the possibility of finding a valid foothold for the next swing is maximized, which makes the robot have more chances to overcome the rough terrains. In addition, a foothold search algorithm that provides the valid foothold while maintaining a high traversability of the robot, is investigated and a gait selection algorithm is developed to help the robot avoid deadlock situations. To explain the algorithms, new concepts such as reachable area, stable area, potential search direction, and complementary kinematic margin are introduced, and the effectiveness of the algorithms is validated via simulations and experiments.