新型膨化硝铵硫磺工业炸药的研究

用膨化硝酸铵、硫磺、木粉和柴油作原材料，通过建立工业炸药配方设计及最优化数学模型，得到新型膨化硝胺硫横工业炸药配方。通过几种工业炸药的理论参数和实际爆炸性能的比较，得出新型膨化硝铵硫磺工业炸药具有低的成本和优良的爆炸性能。     

Manipulating the phase morphology in PPS/PA66 blends using clay

By adding a small amount of clay into poly(p‐phenylene sulfide) (PPS)/polyamide 66 blends, the morphology was found to change gradually from sea–island into cocontinuity and lamellar supramolecular structure, as increasing of clay content. Clay was selectively located in the PA66 phase, and the exfoliated clay layers formed an edge‐contacted network. The change of morphology is not caused by the change of volume ratio and viscosity ratio but can be well explained by the dynamic interplay of phase separation between PPS and PA66 through preferential adsorption of PA66 onto the clay layers and through layer–layer repulsion. This provides a means of manipulating the phase morphology for the immiscible polymer blends. The mechanical and tribological properties of PPS/PA66 blends with different phase morphologies (different clay contents) were studied. Both tensile and impact strength of the blends were found obviously increased by the addition of clay. The antiwear property was greatly improved for the blends with cocontinuous phase form. Our work indicates that the phase‐separating behavior of polymer blends contained interacting clay can be exploited to create a rich diversity of new structures and useful nanocomposites. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

显像管屏玻璃池炉耐火材料侵蚀机理

显像管玻璃池炉耐火材料侵蚀是引发其缺陷的主要原因之一,本文主要论述了彩色显像管屏玻璃池炉耐火材料侵蚀机理,并简要讨论了它们所形成的玻璃缺陷.     

珠江磨刀门河口悬沙浓度变化特征分析

根据2011年枯季和2012年洪季在大、中、小潮期间的多点同步现场观测资料,分析研究了磨刀门河口悬沙浓度变化特征。结果表明:磨刀门口悬沙浓度纵向分布呈近岸高,远岸低的趋势;横向分布具有季节性差异,洪季主槽大于滩地,枯季滩地大于主槽;垂向分布洪季主要以斜线型分布为主,枯季主要以抛物线型分布为主。潮周期平均含沙量大潮普遍大于中、小潮;洪、枯季磨刀门口外落潮含沙量普遍大于涨潮含沙量。洪季含沙量混合较为均匀,落潮时含沙量增大,涨潮时含沙量减小,枯季含沙量分层明显,。受波浪潮汐作用,一个周期内有多次明显的再悬浮过程,涨潮时增大,落潮时减小。     

Reaction Coupling of Ethylbenzene Dehydrogenation with Nitrobenzene Hydrogenation

The chemical equilibrium for the coupling of ethylbenzene dehydrogenation with nitrobenzene hydrogenation, to produce styrene and aniline simultaneously, has been calculated on the basis of the Soave–Redlich–Kwong equation of state. The dehydrogenation of ethylbenzene in the presence of nitrobenzene over the catalysts -Al₂O₃, ZSM-5, activated carbon and platinum supported on activated carbon has been carried out at 400 °C. The effects of Pt loading and the pretreatment of the catalysts have been investigated. It has been revealed that the conversion of ethylbenzene can be greatly improved by the reaction coupling due to the elimination of the hydrogen produced in the reaction by the hydrogenation of nitrobenzene. Platinum supported on the activated carbon has been suggested as a suitable catalyst. The best results with ethylbenzene conversion of 33.8% and styrene selectivity of 99.2% were obtained over Pt(0.02 wt%)/AC at 400 °C. Moreover, such process is also energetically favored since the necessary process heat to drive the ethylbenzene dehydrogenation can be provided by the coupling with the exothermic nitrobenzene hydrogenation reaction.     

SA-3100离心粒度分析条件对粒径真实测定的影响

用SA-3100型离心粒度分析仪测试粉体的粒度时,对同一样品的分析,往往会有不同的结果.通过对沉降介质和分散剂、最大粒径值的设定、以及测量模式的选择等影响因素作比较试验,寻求准确使用该仪器进行粒度分析的方法.     

汽轮发电机高速集电环国产电刷导线过热的原因及改进措施

分析了集电环电刷在运行中产生的导线过热变色，烧损的原因，介绍了集电环开螺旋槽和采用开口气孔率大的多孔电刷，克服导线过热烧损的方法。     

高含水率杨木单板室温胶合的脲醛树脂胶研究

在实验室条件下 ,以传统脲醛树脂胶的生产工艺为基础 ,加用氨基取代羧酸类化合物。新配方制得脲醛树脂胶 ,用DSC分析了树脂固化反应热过程 ,对含水率在 12 % -2 0 %杨木单板进行了室温胶合研究     

膜分离技术在丙烯尾气回收中的应用

分析了聚丙烯生产过程中压缩 /冷凝法丙烯尾气回收的不足 ,介绍了压缩 /冷凝 /有机蒸汽膜法在丙烯尾气回收中的应用     

光亮碱性化学镀镍工艺研究

通过均匀设计法 ,优选了芳香基磺酸盐、芳香醛、炔醇以及含铅、含碘添加剂 ,从而开发了一种光亮碱性化学镀镍新工艺。所得镀层光亮 ,色泽均匀。讨论了主盐、还原剂、温度及pH值对镀速的影响 ,检测了镀液、镀层的性能