Essential oils of Origanum vulgare L. subsp. glandulosum (Desf.) Ietswaart from Tunisia: chemical composition and antioxidant activity

BACKGROUND: Characterisation of the essential oils from O. glandulosum collected in three locations of Tunisia, chemical composition and the evaluation of their antioxidant activities were carried out. RESULTS: The essential oils from Origanum vulgare L. subsp. glandulosum (Desf.) Ietswaart collected from three localities of north Tunisia—Krib, Bargou and Nefza—were obtained in yields of 2.5, 3.0 and 4.6% (v/w), respectively. The essential oils were analysed by GC and GC/MS and assayed for their total phenolics content, by the Folin–Ciocalteu method, and antioxidant effectiveness, using the 2,2‐diphenyl‐1‐picrylhydrazil (DPPH) radical scavenging assay. The main components of these essential oils, from Nefza, Bargou and Krib, were p‐cymene (36%, 40% and 46%), thymol (32%, 39% and 18%), γ‐terpinene (24%, 12% and 16%) and carvacrol (2%, 2% and 15%), respectively). The ability to scavenge the DPPH radicals, expressed by IC₅₀, ranged from 59 to 80 mg L^?1. The total phenolic content, expressed in gallic acid equivalent (GAE) g kg^?1 dry weight, varied from 9.37 to 17.70 g kg^?1 dw. CONCLUSIONS: A correlation was identified between the total phenolic content of the essential oils and DPPH radical scavenger capacity. The occurrence of a p‐cymene chemotype of O. glandulosum in the northern region of Tunisia is demonstrated. Copyright © 2010 Society of Chemical Industry     

Theoretical study of hydrogen absorption and desorption in Ti1-xZrx Mn1.4 using statistical physics treatment: Microscopic investigation and thermodynamic potential interpretation

Experimental absorption and desorption isotherms of hydrogen in Ti_1-xZr_x Mn_1.4 (x = 0, 0.1, 0.2, 0.3, 0.4) alloys at T = 293 K have been fitted using some theoretical model expressions treated by statistical physics through the grand canonical ensemble. The monolayer model with two types of sites is used to fit and interpret the experimental data. The physicochemical parameters governing the absorption-desorption processes and included into the model expressions could be numerically deduced from the relevant experimental isotherms. Six parameters of the model are fitted, namely the numbers of hydrogen atoms per site n₁ and n₂, the receptor site densities N_1m and N_2m, and the energetic parameters P₁ and P₂. The evolution of these parameters as function of composition x is plotted and explained in correlation with absorption-desorption processes. Finally, the thermo-dynamic potential functions which govern the sorption mechanisms such as internal energy E_int, free enthalpy of Gibbs G_a and entropy S_a were derived from statistical physics calculations based on the model adopted.     

Comparative effects of structural and material parameters variability on Pellet–Cladding Interaction in a PWR fuel rod

In the water pressurised nuclear reactors, the fuel rod cladding is the first barrier against radioactive isotopes release. Its integrity must be demonstrated all along the fuel rod irradiation with increasing strenuous operating conditions. This paper deals with a study made with Electricité de France (EDF) in order to improve the understanding and modelling of the thermomechanical behaviour of fuel rods under these more arduous conditions. The aim of this study is to evaluate the separate influences of structural and material parameters variability on Pellet–Cladding Interaction (PCI). The following parameters have been tested by 3D simulations for a common ramping condition: axial and radial pellet cracks numbers, pellet fragment size, relative fragments displacement, non-symmetrical configuration, pellet–pellet friction and pellet–cladding friction. The second part of the article deals with the development of a model, which gives a better assessment of cladding stress concentration near radial fuel cracks. The implementation in the 1D fuel rod EDF code CYRANO3 and the validation of the model are presented.     

Continuous elliptic and multi-dimensional hyperbolic Darcy-flux finite-volume methods

Elliptic and hyperbolic Darcy-flux approximations are presented. Families of flux-continuous finite-volume methods are investigated for the elliptic full-tensor pressure equation with general discontinuous coefficients. Full pressure continuity across control-volume interfaces is built into the methods leading to an important distinction from the earlier pointwise continuous methods. The families of quasi-positive methods significantly reduce spurious oscillations (induced by earlier schemes) in discrete pressure solutions for strongly anisotropic full-tensor fields. Anisotropy favoring triangulation and non-linear flux splitting are also shown to be effective for computing solutions free of spurious oscillations.Multi-dimensional upwind schemes that reduce cross-wind numerical diffusion induced by the standard upwind scheme are also presented for hyperbolic Darcy-flux approximation.     

Removal of tiemonium methylsulfate,from aqueous solutions using activated carbon prepared from date stones

The retention of a pharmaceutical compound, tiemonium methylsulfate (TIM), from aqueous solutions by adsorption onto activated carbon prepared from date stones (AC–DS) was investigated. Physical and chemical characteristics of this material were also determined. Results showed that pH 8 was optimal for TIM adsorption. Among the kinetic models considered, the pseudo-second-order model was the most appropriate to describe experimental data. Regarding adsorption isotherms, it was shown that the Sips model accurately describe the sorption of TIM onto AC–DS with a correlation factor R²?>?0.98. The adsorption capacity of AC–DS was found to be 42.2?mg?g^?1 at 10°C and 60.5?mg?g^?1 at 25°C, confirming its efficiency for the removal of this compound from aqueous solutions. The values of ΔG⁰ and ΔH⁰ confirmed that the adsorption of TIM onto AC–DS was spontaneous and endothermic in nature and hence more effective at high temperatures. An irregular increase in the randomness was suggested at the AC–DS solution interface during the adsorption process for positive values of ΔS⁰.     

High level visual scene classification using background knowledge of objects

Multimedia Tools and Applications - This paper introduces a novel and simple approach of high-level scene classification. Knowing that objects are the essence of any given scene, the proposed...     

Advanced interpretation of hydrogen absorption process in LaMgNi3.6M0.4 (M = Ni,Mn, Al,Co, Cu) alloys using statistical physics treatment

To obtain good economic and environmental benefits, LaMgNi_3.6M_0.4 (M = Al, Mn, Ni, Co, Cu) alloys are investigated for the hydrogen storage. The absorption data of hydrogen in the tested alloys are measured experimentally at 373 K. The hydrogen absorption isotherms are analyzed using three models derived from statistical physics formalism. The adequate model permits to discover significant details about the absorption phenomenon via determining the density of the interstitial sites (D_m), the number of hydrogen atoms per site (n) and the energetic parameter ΔE. The results indicate that multi-atomic (n > 1) and multi-linking (n < 1) phenomena are feasible for hydrogen absorption in LaMgNi_3.6M_0.4 (M = Al, Mn, Ni, Cu, Co) metals. The effects of the substitutions of Ni with Mn, Co, Cu and Al on the hydrogen absorption capacity are investigated. The interaction hydrogen/metal is analyzed by the calculation of the absorption energies. The chemical interaction is the responsible for the hydrogen absorption phenomenon. The contribution of this work is to provide advanced investigations of the hydrogen absorption mechanism in LaMgNi_3.6M_0.4 (M = Al, Mn, Ni, Co, Cu) metals, which are promising alloys for the hydrogen storage.     

Spontaneous Outcropping of Self‐Assembled Insulating Nanodots in Solution‐Derived Metallic Ferromagnetic La0.7Sr0.3MnO3 Films

A new mechanism is proposed for the generation of self‐assembled nanodots at the surface of a film based on spontaneous outcropping of the secondary phase of a nanocomposite epitaxial film. Epitaxial self‐assembled Sr–La oxide insulating nanodots are formed through this mechanism at the surface of an epitaxial metallic ferromagnetic La_0.7Sr_0.3MnO₃ (LSMO) film grown on SrTiO₃ from chemical solutions. TEM analysis reveals that, underneath the La–Sr oxide (LSO) nanodots, the film switches from the compressive out‐of‐plane stress component to a tensile one. It is shown that the size and concentration of the nanodots can be tuned by means of growth kinetics and through modification of the La excess in the precursor chemical solution. The driving force for the nanodot formation can be attributed to a cooperative effect involving the minimization of the elastic strain energy and a thermodynamic instability of the LSMO phase against the formation of a Ruddelsden–Popper phase Sr₃Mn₄O₇ embedded in the film, and LSO surface nanodots. The mechanism can be described as a generalization of the classical Stranski–Krastanov growth mode involving phase separation. LSO islands induce an isotropic strain to the LSMO film underneath the island which decreases the magnetoelastic contribution to the magnetic anisotropy.     

Treatment of landfill leachate using Fenton process and coagulation/flocculation

Coagulation/flocculation process, Fenton oxidation and combinations between them were studied, aiming to provide an efficient method for the treatment of partially stabilized leachates. Leachates were collected from a municipal landfill site, samples containing around 3800 mg/L COD, BOD₅/COD ratio about 0.11 and pH around 8. The sequence of stages implemented was: (a) coagulation/flocculation; (b) Fenton oxidation; (c) coagulation/flocculation followed by Fenton oxidation which resulted in a best COD removal (63.62%) and (d) Fenton oxidation followed by coagulation/flocculation.