2,6-二乙酰基吡啶合成方法的改进

优化了2，6—二乙酰基吡啶的合成工艺。以2，6—吡啶二羧酸为原料，经过醇化及克莱森酯缩合反应，合成了2，6—二乙酰基吡啶，2，6—吡啶二羧酸二乙醇和2，6—二乙酰基吡啶的分离收率分别为94．1％和88．9％，2，6—二乙酰基毗啶的质量分数大于99％。     

不饱和酸结构对不饱和聚酯树脂固化行为的影响

通过IR分析了用顺酐和反酸与聚酯合成不饱和聚酯树脂的反应机理,讨论了二种树脂体系固化放热曲线不同的原因。     

基于Morlet小波变换和改进遗传算法的动态识别

如何合理地识别大型复杂结构的动力参数一直是工程领域关心的问题.为此,以Morlet小波变换和采用单亲遗传算子的改进遗传算法为基础,构造一结构动态参数识别模型.并且以C++为平台,通过计算机内部命令调用ANSYS等软件,实现识别模型的程序化.通过模拟算例计算,计算结果与理论值一致.同时,结合一水电站厂房现场振动试验,对该大型结构进行动态参数识别,识别结果与工程经验值基本吻合.     

Global Avalanche Characteristics of Boolean Functions by Concatenation

In order to measure the correlation propeties of two Boolean functions,the global avalanche characteristics of Boolean functions constructed by concatenation are discussed,i.e.,f_1‖f_2and f_1‖f_2‖f_3‖f_4.Firstly,for the function f = f_1‖f_2,the cross-correlation function of f_1,f_2 in the special condition are studied.In this case,f,f_1,f_2 must be in desired form.By computing their sum-of-squares indicators,the crosscorrelation function between f_1,f_2 is obtained.Secondly,for the function g = f_1‖f_2‖f_3‖f_4,by analyzing the relation among their auto-correlation functions,their sum-of-squares indicators are investigated.Based on them,the sum-of-squares indicators of functions obtained by Canteaut et al.are investigated.The results show that the correlation property of g is good when the correlation properties of Boolean functions f_1,f_2,f_3,f_4 are good.     

高温预析出对Al-Zn-Mg-Cu铝合金显微组织、强度和应力腐蚀抗力的影响

通过改变固溶条件 ,对Al Zn Mg Cu高强铝合金采用先高温后低温的两步固溶处理 (高温预析出 )来改善晶内和晶界的析出状态 ,研究了高温预析出对Al Zn Mg Cu铝合金的金相组织、强度和应力腐蚀性能的影响。结果表明 ,4 6 5℃高温预析出在保持较高强度和塑性的同时 ,可以改善合金的抗应力腐蚀性能     

一种提高无线网络语音通话数量的方法

语音通话(Voice over IP)已经成为无线局域网中的一种重要的应用,并且近年来得到了越来越广泛的关注.分析了无线局域网所能支持的语音通话的最大数量,并在网络仿真器NS2上建立了IEEE 802.11语音通话的仿真模型根据仿真分析结果,提出一种自适应传输间隔接入控制方法,提高了IEEE 802.11无线局域网支持语音通话的数量.在自适应传输间隔接入控制方法中,基站(Base Station)通过监测网络冲突概率,自适应的改变网络中语音通话的传输间隔,使网络始终工作在非饱和状态.仿真实验结果表明,提出的白适应传输间隔接入控制方法不仅能够保证IEEE 802.11无线局域网中语音通话的质量,还可以增加网络所能支持语音通话的数量.     

Petri网与数字系统设计

日益复杂的数字系统设计,须由各种专业的设计人员分工完成。他们之间需要一种描述系统的“共同语言”来沟通,这对于提高设计质量、缩短设计周期、减少设计费用具有积极意义。Petri网十分适合担任这一“共同语言”的角色。文章给出了数字电路测试仪器中的硬件设计的部分实例。     

气相色谱仪新旧检定规程的解读

本文主要从规程适用范围、计量器具控制、计量性能要求及检定方法等方面入手,全面的解读了气相色谱仪新旧检定规程的差异,为仪器检定及期间核查提供了参考。     

Energy gap distribution of HgBa2CuO4+δ investigated by scanning tunneling microscopy/spectroscopy

The superconducting energy gap distribution of poly crystalline HgBa₂CuO₄₊ samples of differing oxygen doping levels (T_c = 94 K and T_c = 96 K) is determined by scanning tunneling spectroscopy (STS) using a low temperature scanning tunneling microscope (STM). From histograms of energy gap values the presence of two distinct energy gaps is inferred (₁=8.5±1.6meV and ₂=15.1±1.4meV). We attribute the different gaps to different crystallographic faces, implying a non-BCS electron-electron pairing mechanism.     

Scanning/friction force microscopy study of YBa2Cu3O7−δ single crystals grown in BaZrO3 crucibles

Very pure YBa₂Cu₃O_7– (YBCO) single crystals grown in BaZrO₃ crucibles are studied in the as-grown and the oxidized state by scanning force (SFM), friction force (FFM) and scanning tunneling microscopies (STM). The images show clean terraces with step-heights of one unit cell along YBCO(001), i.e. 1.2 nm. Only close to step edges is material contrast observed by FFM indicating traces af flux. Some crystal surfaces exhibit over-layer features, such as star-like, ribbon-like and checkerboard-like structures, which exhibit friction contrast implying the presence of different materials on the surface. Tunneling spectroscopy at 4.7 K in high vacuum reveals a superconducting energy gap of 2 26 me V.