钙钛锆石-钡硼硅酸盐玻璃陶瓷的制备及表征

采用熔融–热处理工艺制备了Si O2–B2O3–Ba O–Na2O–Ca O–Zr O2–Ti O2体系钙钛锆石基钡硼硅酸盐玻璃陶瓷,研究了Ca O、Ti O2、Zr O2(记为CTZ,摩尔比为2:2:1)含量对玻璃陶瓷相结构、显微结构的影响,采用产品一致性测试法(PCT)测试了玻璃陶瓷样品的抗浸出性能。结果表明:样品的玻璃转变温度为615~650℃且随着CTZ含量增加而升高。CTZ含量为35%的样品和CTZ含量为45%的样品分别在900和850℃附近出现了明显的放热峰。当CTZ含量≥30%时,钙钛锆石晶相开始析出;CTZ含量为45%时,样品中出现大量均匀分布的柱状钙钛锆石晶相;CTZ含量达55%时,样品致密性较差,除钙钛锆石晶相外还有榍石和二氧化硅晶相析出。PCT测试表明:CTZ含量为45%的样品具有较好的抗浸出性能,B和Na在42 d后的归一化质量损失约为0.1 g/m2,Si和Ca约为0.01 g/m2,与硼硅酸盐玻璃固化体处于同一数量级。     

多晶体硅太阳电池的PID效应研究

随着多晶硅太阳电池的广泛应用,电池组件的电势诱导衰减(PID)现象越来越引起大家的重视。本文介绍了多晶硅太阳PID现象产生的原因以及目前的解决途径。     

Carbazole Aminoalcohols Induce Antiproliferation and Apoptosis of Human Tumor Cells by Inhibiting Topoisomerase I

Novel carbazole aminoalcohols were designed and synthesized as anticancer agents. Among them, alkylamine‐chain‐substituted compounds showed the most promising antiproliferative activity, with IC₅₀ values in the single‐digit micromolar range against two human tumor cell lines. Topoisomerase I (topo I) is likely to be one of the targets of these compounds. Results of comet assays and molecular docking indicate that the representative compounds may act as topo I poisons, causing single‐strand DNA damage by stabilizing the topo I–DNA cleavage complex. In particular, the most potent compound, 1‐(butylamino)‐3‐(3,6‐dichloro‐9H‐carbazol‐9‐yl)propan‐2‐ol ( 6 ), was shown to be able to induce G₂‐phase cell‐cycle arrest and apoptosis in HeLa cells.     

新甲烷化催化剂出口碳氧化合物偏高的原因

分析新鲜甲烷化催化剂刚投用时,出口碳氧化合物偏高的原因,说明是催化剂未还原彻底造成,提出甲烷化催化剂表征还原度的衡量依据,建议在线对还原不彻底的催化剂进行重新还原.     

固体炸药冲击起爆研究

为了研究固体炸药冲击起爆特性,对JO-9159炸药进行了隔板冲击加载实验,用高速摄影方法记录炸药冲击起爆过程;用解析计算方法分析了有机玻璃隔板的临界厚度值;建立了炸药冲击起爆模型,对起爆过程进行了数值模拟,计算了炸药在冲击作用下的压力历史,分析了JO-9159炸药起爆压力阈值和爆轰成长距离。     

Anisotropic domain switching in Pb(Mg1/3Nb2/3)O3‐0.30PbTiO3 single crystals with rhombohedral structure

Anisotropic domain switching paths in [001]‐, [011]‐, and [111]‐poled Pb(Mg_1/3Nb_2/3)O₃‐0.30PbTiO₃ single crystals were studied by in situ polarized light microscopic driven by an antiparallel electric field. Orientation‐dependent electric field induced polarization and strain behaviors were investigated systematically. For [001]‐oriented crystals, only one‐step 71° switching occurred during the domain switching process, resulting in the appearance of stripe domain walls whose traces on (001) plane were along 45° or 135° with respect to [100] direction. But for [011]‐oriented samples, a two‐step 71° switching was observed during 109° switching and the projections of formed twin domain walls on the (011) plane are along 35.3° or 144.7° with respect to [01] direction. Moreover, a three‐step 71° switching was found during 180° switching in [111]‐oriented samples. It was demonstrated by the produced domain walls whose projections on the (10) plane are along 35.3°, 90° or 160.6° with respect to [11] direction. The energetically motivated mechanism based on multistep polarization switching process was also proposed to explain the anisotropic domain switching paths. Our results provided a visualized observation on the ferroelectric domain switching process and also laid the solid foundations for controlling polarization order parameter in ferroelectric single crystals.     

Temperature effects on unsaturated hydraulic property of bentonite-sand buffer backfilling mixtures

The influence of temperature on the engineered properties of bentonite-sand mixtures (B/S) is of major concern in the design of engineered barriers in underground repositories for high-level radioactive waste disposal. We experimentally studied the influence of temperature on soil unsaturated hydraulic properties related to water holding capacity and permeability of GMZ B/S in China. The vapor equilibrium method and water infiltration apparatus were used to measure the soil water characteristic curve (SWCC) and unsaturated hydraulic conductivity (ku ). The results show that the SWCC under different temperatures from 20 ℃ to 60 ℃ tends to be the same. Temperature influence on unsaturated permeability is more relevant at low suctions, no clear effect is detected below a degree of saturation of 74%, and experimental data show that temperature dependence on unsaturated permeability is small.     

综合嵌入式视觉与网络智能通信的监控系统

基于物联网技术的操作平台,利用DSP,ARM技术的强大数据图像处理能力,结合互联网、移动通信网等网络进行信息的传送与交互,及智能计算技术对信息进行分析处理,提高产品的监控能力。     

Task-wise attention guided part complementary learning for few-shot image classification

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