Mono- and bi-functional arenethiols as surfactants for gold nanoparticles: synthesis and characterization

Stable gold nanoparticles stabilized by different mono and bi-functional arenethiols, namely, benzylthiol and 1,4-benzenedimethanethiol, have been prepared by using a modified Brust's two-phase synthesis. The size, shape, and crystalline structure of the gold nanoparticles have been determined by high-resolution electron microscopy and full-pattern X-ray powder diffraction analyses. Nanocrystals diameters have been tuned in the range 2 ÷ 9 nm by a proper variation of Au/S molar ratio. The chemical composition of gold nanoparticles and their interaction with thiols have been investigated by X-ray photoelectron spectroscopy. In particular, the formation of networks has been observed with interconnected gold nanoparticles containing 1,4-benzenedimethanethiol as ligand.     

Hybrid Hydrogen Home Storage for Decentralized Energy Autonomy

As the share of distributed renewable power generation increases, high electricity prices and low feed-in tariff rates encourage the generation of electricity for personal use. In the building sector, this has led to growing interest in energy self-sufficient buildings that feature battery and hydrogen storage capacities. In this study, we compare potential technology pathways for residential energy storage in terms of their economic performance by means of a temporal optimization model of the fully self-sufficient energy system of a single-family building, taking into account its residential occupancy patterns and thermal equipment. We show for the first time how heat integration with reversible solid oxide cells (rSOCs) and liquid organic hydrogen carriers (LOHCs) in high-efficiency, single-family buildings could, by 2030, enable the self-sufficient supply of electricity and heat at a yearly premium of 52% against electricity supplied by the grid. Compared to lithium-ion battery systems, the total annualized cost of a self-sufficient energy supply can be reduced by 80% through the thermal integration of LOHC reactors and rSOC systems.