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11.
Ahmadi Hossein Arji Goli Shahmoradi Leila Safdari Reza Nilashi Mehrbakhsh Alizadeh Mojtaba 《Universal Access in the Information Society》2019,18(4):837-869
Universal Access in the Information Society - The Internet of Things (IoT) is an ecosystem that integrates physical objects, software and hardware to interact with each other. Aging of population,... 相似文献
12.
Aissaoui Ferhi Leila Sethom Kaouthar Choubani Fethi 《Wireless Personal Communications》2019,109(3):1769-1779
Wireless Personal Communications - With the attractive applications in e-Health, a booming interest is granted to wireless body area network (WBAN). Through WBAN, healthcare professionals can... 相似文献
13.
Leila M. Guimarães Aguiar Rogério Matheus Vargas 《Journal of the American Oil Chemists' Society》1998,75(6):755-756
Glycerolysis of methyl stearate and tristearin has been carried out in the presence of alkylguanidines—strong nonionic bases—as
catalysts. When applied at 10 mol%, 1,5,7-triazabicyclo [4.4.0]dec-5-ene, 1,2,3-tricyclohexylguanidine, and 1,3-dicyclohexyl-2-n-octylguanidine give monoglycerides in more than 90% selectivity, in a maximum of 6 h reaction time. 相似文献
14.
Altering the association properties of insulin by amino acid replacement 总被引:12,自引:0,他引:12
Brems David N.; Alter Leila A.; Beckage Michael J.; Chance Ronald E.; DiMarchi Richard D.; Green L. Kenney; Long Harlan B.; Pekar Allen H.; Shields James E.; Frank Bruce H. 《Protein engineering, design & selection : PEDS》1992,5(6):527-533
The importance of ProB28 and LysB29 on the self-associationof insulin was established by systematically truncating theC terminus of the B chain. The relationship between structureand association was further explored by making numerous aminoacid replacements at B28 and B29 Association was studied bycircular dichroism, size-exclusion chromatography and ultracentrifugation.Our results show that the location of a prolyl residue at B28is critical for high-affinity self-association. Removal of ProB28in a series of C-terminal truncated insulins, or amino acidreplacement of Pro28, greatly reduced association. The largestdisruption to association was achieved by replacing LysB29 withPro and varying the amino acid at B28 Several of the analogswere predominantly monomers in solutions up to 3 mg/ml. Theseamino acid substitutions decreased association by primarilydisrupting the formation of dimers. Such amino acid substitutionsalso substantially reduced the Zn-induced insulin hexamer formation.The formation of monomeric insulins through amino acid replacementswas accompanied by conformational changes that may be the causefor decreased association. It is demonstrated that self-associationof insulin can be drastically altered by substitution of oneor two key amino acids. 相似文献
15.
Lignin‐based chemicals, starch, and urea were used as modifiers for phenol–formaldehyde resol resins. The effects of the addition stage of the modifiers used in the synthesis of the resins and the type of modification reagent on the structures of the resins and their molar masses and reactivities were investigated. The modifications with corn starch and lignin promoted condensation; this was verified by increased molar masses and high ratios of methylene bridges to the sum of free ortho and para aromatic groups with respect to the corresponding reference resin without a modification reagent. The later the modifier was added to the resin condensation mixture, the more methylene bridges were formed with respect to the amounts of free ortho and para aromatic groups. In addition, when urea or wheat starch was added in the later condensation stage, the final condensation also reached high stages. The modifications with lignosulfonate and starch, as well as the early addition of urea, enhanced p–p′ bridge structures. The lowest condensation stage and, therefore, the highest reactivity were found when wheat starch was added with the starting reagents. The curing heat of the wheat‐starch‐modified resins decreased according to the deferred addition point of starch. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 582–588, 2003 相似文献
16.
Omid Velayatipour Leila Nikzad Mohammad Farvizi 《International Journal of Applied Ceramic Technology》2023,20(3):1667-1680
In this study, NiTi–x wt.% B4C (x = 0, 2, and 4) composites were consolidated with spark plasma sintering method, and the effects of boron carbide reinforcement addition on the microstructure and wear behavior of samples were investigated. Identification of the constituent phases of samples by the X-ray diffraction method plus Rietveld analysis revealed that the stability of the martensite phase increased in the composite samples because of mismatch stresses between the NiTi matrix phase and the reinforcing particles, which increases the density of the dislocations and facilitates the diffusion process that subsequently leads to the formation of stable intermetallics. The results of hardness test indicated that the hardness value increased from 3.67 GPa for pure NiTi to 10.99 GPa for NiTi–4 wt.% B4C. Results of wear test revealed that boron carbide reinforced composite specimens had higher wear resistance, whereas wear rate of NiTi sample was 3.6 × 10−3 mm3/N m, and it reached to .21 × 10−3 mm3/N m for NiTi–4 wt.% B4C. Investigation of microstructure by scanning electron microscopy images and EDS analysis revealed that the wear mechanism in NiTi samples was abrasive and the addition of B4C to NiTi changed the wear mechanisms from abrasive to a combination of oxidation, adhesive, and delamination mechanisms. 相似文献
17.
Leila M. Saleh Medina Antonela Cánneva Fabricio N. Molinari Norma D'Accorso R. Martín Negri 《Polymer Engineering and Science》2023,63(2):366-378
The objective of this work is to prepare absorbent materials based on polydimethylsiloxane (PDMS) for the absorption of organic solvents by a relative simple method, with large absorption capacities and reusability. Different particles (ZnO, MgSO4, ZnCl2, and NaHCO3) were first incorporated in PDMS and then removed by immersion in HCl (c) or water. The absorbent materials were characterized by TGA, mercury porosimetry, stress–strain curves, SEM, EDS, XPS, FTIR, and water contact angle. The materials can absorb polar organic chlorinated solvents (carbon tetrachloride, dichloroethene, dichloromethane, and chloroform) more than four times its own weight. Other solvents were also tested showing 2–3 times its own weight. Additionally, these materials show demulsification properties and absorption of oleophilic compounds. The reusability of the material makes them good candidates for remediation of polluted water. 相似文献
18.
Leila Pakzad Farhad Ein-MozaffariSimant R. Upreti Ali Lohi 《Chemical Engineering Research and Design》2013
The design of the coaxial mixers depends on many interrelated parameters including the geometry and dimensions of the mixing vessel, the location and type of the impellers, speed ratio, impeller diameter, rotation mode, and fluid rheology. No study has been reported in the literature regarding the mixing performance of the coaxial mixers in the agitation of yield-pseudoplastic fluids. Thus, the main objective of this study was to evaluate the performance of a Scaba–anchor coaxial mixer (a novel configuration) in the mixing of xanthan gum solutions (yield-pseudoplastic fluids). The Herschel–Bulkley model was used to describe the rheological behavior of the xanthan gum solutions. To develop new correlations for the generalized Reynolds and power numbers of the coaxial mixers employed in the agitation of this class of non-Newtonian fluids, we utilized numerous experimental and computational fluid dynamics (CFD) data. The new correlations were tested successfully at different operating conditions (e.g. speed ratio, fluid rheology, and operation mode). 相似文献
19.
José L. S. Lopes Maria J. Gómara Isabel Haro Georgina Tonarelli Leila M. Beltramini 《International journal of molecular sciences》2013,14(6):12313-12328
Plantaricin149a (Pln149a) is a cationic antimicrobial peptide, which was suggested to cause membrane destabilization via the carpet mechanism. The mode of action proposed to this antimicrobial peptide describes the induction of an amphipathic α-helix from Ala7 to Lys20, while the N-terminus residues remain in a coil conformation after binding. To better investigate this assumption, the purpose of this study was to determine the contributions of the Tyr1 in Pln149a in the binding to model membranes to promote its destabilization. The Tyr to Ser substitution increased the dissociation constant (KD) of the antimicrobial peptide from the liposomes (approximately three-fold higher), and decreased the enthalpy of binding to anionic vesicles from −17.2 kcal/mol to −10.2 kcal/mol. The peptide adsorption/incorporation into the negatively charged lipid vesicles was less effective with the Tyr1 substitution and peptide Pln149a perturbed the liposome integrity more than the analog, Pln149S. Taken together, the peptide-lipid interactions that govern the Pln149a antimicrobial activity are found not only in the amphipathic helix, but also in the N-terminus residues, which take part in enthalpic contributions due to the allocation at a lipid-aqueous interface. 相似文献
20.
Mehrdad Irannejad Toney Fernandez Purushottam Joshi Zhanxiang Zhao Joris Lousteau Billy Richards Gin Jose Animesh Jha 《International Journal of Applied Glass Science》2013,4(3):202-213
Following on from Part I of this review article that focuses on the suitability of Er3+-doped tellurium oxide glass for optical amplification in fiber, this Part II article describes how the fiber gain data were then employed to engineer amplification in waveguides, which can be integrated with semiconductor pump sources. The gain characteristics and bandwidth of a phosphate modified tellurite waveguide formed on a GaAs substrate are discussed. The limiting structural compatibility of Er3+-doped tellurite glass with polydimethylsiloxane polymer for active–passive integration is overcome by adopting a nanoscale super-lattice approach for waveguide engineering. 相似文献