Aromatic gas oil cracking under realistic FCC conditions in a microriser reactor

A paraffinic hydrowax feed spiked with naphthalene, anthracene, and phenanthrene was cracked in a once-through microriser reactor at 575 °C and with a catalyst-to-oil (CTO) ratio of 4.8 g_cat g_oil⁻¹. The conversion by cracking reactions is limited to the paraffinic fraction of the feed and the alkyl groups associated with the benzene ring in aromatic compounds; the aromatic probes did not crack under the applied conditions, and in fact an additional amount of naphthalene was formed by complex dealkylation and hydrogen transfer reactions. The ‘uncrackabilty’ of aromatics was directly demonstrated by processing an aromatic gas oil, containing 33.3 wt% aromatics. Experiments were performed with residence times between 0.05 and 8.2 s, keeping the temperature (525 °C) and CTO ratio (5.5 g_cat g_oil⁻¹) constant. The data was interpreted with a simplified first-order five-lump kinetic model, where approximately 19 wt% of the feed was found to be uncrackable. HCO (feedstock) conversion took mainly place during the first two seconds and coke was only formed during the first 50 ms of catalyst-oil contact. Gasoline was not overcracked to gas. Approximately 50 wt% of the LCO fraction was formed during this 50 ms and did not change thereafter.     

脱硫污水处理控制系统的设计

根据脱硫废水工艺条件和水质,废水处理系统采用一套可编程控制系统(PLC)进行控制。废水系统PLC控制装置与脱硫系统DCS留有硬接线及通讯接口。在脱硫系统DCS上可以完成废水装置的启停控制及工艺系统的监视。以国华台山电厂湿法烟气脱硫废水处理的实践为例介绍脱硫废水处理的控制系统的设计。     

反相悬浮聚合法制备"核/壳"型高吸水及耐盐性树脂

通过交联剂和复配改性剂的改性作用，用反相悬浮聚合法，制备了“核／壳”结构的聚合物，产物大大提高了吸水性及耐盐性。实验探讨了工艺条件，通过红外光谱分析产物结构及其吸水机理。     

Phtocrosslinking of polyethylene for production of thin wall insulated wire

A photocrosslinking precess for polyethylene and its industrial irradiation apparatus has recently been developed and used successfully in the manufactre of thin wall crosslinked polyethylene-insulated wires. Polyethylene (PE) resin with the desired amounts of additives, such as photoinitiator, multifunctional crosslinker, and antioxidant is mixe homogeneously. The amixture of PE is granulated, and then extruded on a conductor wire. The coated PE layer in the melt is subsequently irradiated in a specially designed UV irradiation apparatus for 5 to 10 s. The studies show that the photocrosslinked PE-insulation high voltage television wires produced by this new technique possess excellent electrical and mchanical properties and much lower operating cost compared with wires produced by the electron beam crosslinking technique.     

玉米芯木聚糖硫酸酯化条件的研究

用碱提法从玉米芯中提取木聚糖,采用氯磺酸吡啶法进行硫酸酯化,通过正交试验确定最佳工艺条件为:吡啶与氯磺酸摩尔比1∶1,温度65℃,时间6h;木聚糖硫酸酯wisX-S通过DEAESepharoseFF层析柱分离得到一个相对分子量为1.3×104的组分,硫酸基取代度为2.24。对此木聚糖硫酸酯进行红外光谱分析,结果显示在波数1259、1228和813cm-1处分别有S=O和C-O-S键的特征吸收峰。     

基于计算机测控技术的转矩流变仪的研制

介绍了基于计算机测控技术的聚合物转矩流变仪的研制，该仪器具有优良的性能指标，强大的数据文件处理能力、测试功能扩展能力，是高分子材料研究和开发的理想工具。     

应用轴功目标法合成低温分离序列

针对以乙烯深冷分离系统为代表的低温精馏过程合成问题。低温精馏系统包括精馏序列以及与之对应的换热网络和制冷系统。依据轴功目标方法,低温分离系统的能耗可以归结到制冷系统的轴功上,且过程的轴功消耗可以不经过换热网络和制冷系统的合成而直接得到。本文以轴功消耗作为优化目标建立数学模型,在模型中不包含换热网络和制冷系统结构的情况下建立精馏序列与对应轴功消耗的关系。这样,在不增加问题复杂程度的前提下实现对系统总能耗的优化。对乙烯冷端分离系统的合成的算例研究表明,通过基于轴功目标的数学模型可以高效的得到具有最低轴功消耗的精馏系统。     

酚醛环氧乙烯酯树脂研究

本文以酚醛环氧树脂F-51与甲基丙烯酸合成出酚醛环氧乙烯酯树脂,并对此树脂的耐热性、耐化学溶剂性能进行了研究.     

图的点可区别边染色算法研究

针对一般图设计了一种新型的点可区别边染色算法。该算法把概率思想和图染色相结合, 根据点可区别边染色的约束规则确立目标函数, 利用交换规则逐步寻优, 当目标函数的值满足要求时染色成功。给出详细算法步骤并进行了测试和分析, 实验结果表明该算法可以求出满足猜想的点可区别边色数。     

用稀疏相似性度量求解压缩传感矩阵

提出一种用稀疏相似性度量求解压缩传感矩阵的方法,并将其应用在图像重建和识别领域中.首先构造一种稀疏相似性度量,然后将其嵌入到传感矩阵的模糊代价函数中,最终传感矩阵的原子更新按照模糊方式进行计算.用该方法优化后的观测矩阵与字典矩阵之间保持了低相干性,并且样本的稀疏信号在相同重构条件下具备了更优的测量数目和质量.在ORL和FERET人脸数据库及91幅自然图像库上的实验结果验证了该算法的有效性.