旋风分离器结构改进的研究

根据旋风分离器的工作原理及应用特点 ,分析了影响旋风分离器分离效率的因素及结构存在的问题 ,并提出了改进措施 ,即内管外壁增设螺旋翼片 ,扩散形锥体改为悬挂挡板。通过实验观察 ,改进结构的旋风分离器分离效率比常规旋风分离器高。实践证明 ,对于密度差异较小的非均相物系的分离 ,只要对旋风分离器作适当改进 ,仍能取得令人满意的效果 ,这大大拓宽了旋风分离器的应用领域     

Top-Seeded Melt-Growth of YBa2Cus3Ox Crystals for Neutron Diffraction Studies

We have grown cubic centimeter-size crystals of YBa₂Cu₃O _x suitable for neutron studies, by a top-seeded melt-growth technique. Growth conditions were optimized with an eye toward maximizing phase purity. It was found that the addition of 2% Y₂BaCuO₅ and 0.5% Pt (by mass) were required to prevent melt loss and to obtain the highest crystallinity. A neutron diffraction study on a mosaic of six such crystals found that the final Y₂BaCuO₅ concentration was 5%, while other impurity phases comprised less than 1% by volume. The oxygen content was set to x = 6.5, the crystals were detwinned, and then carefully annealed to give the well-ordered ortho-II phase. The neutron study determined that 70% of the mosaic's volume was in the majority orthorhomic domain. The neutron (006) and (110) rocking curve widths were ～1° per crystal and ～2.2° for the mosaic, and the oxygen chain correlation lengths were >100 Å in the a- and b-directions and ～50 Å in the c-direction.     

纳米β-NiOOH的固相合成及其性能

首次利用固相氧化法制备了 β NiOOH纳米粉体样品 ,经X射线衍射和透射电镜测试结果表明所得样品 β NiOOH粒子呈球形 ,粒径大小在 2 0～ 40nm之间。热重与差热分析结果表明当温度超过 10 0℃ ,样品开始不可逆地分解为NiO。运用恒流充放电、循环伏安以及Tafel极化等电化学测试对样品的电化学性能进行了初步研究。结果表明 :β NiOOH的交换电流密度高于 β Ni(OH) 2 的交换电流密度约一个数量级 ,具有较好的电极可逆性、较高的质量比容量以及优良的容量保持率 ,适于作为Zn/NiOOH类型镍电池的正极活性材料     

两段式热脱焦油煤气炉在环形加热炉上的开发应用

介绍了两段式煤气发生炉热脱焦油煤气在无缝钢管环形加热炉上的开发与应用 ,以及两段式煤气发生炉热脱焦油煤气站的设计和采用热脱焦油煤气代替重油所产生的经济效益     

Determination of molecular weight distributions of tert-octylphenol ethoxylate surfactant polymers by laser desorption Fourier transform ion cyclotron resonance mass spectrometry and high-performance liquid chromatography

Triton polymers are commercial surfactants whose molecular weight distributions are conventionally determined by means of high-performance liquid chromatography (HPLC). However, in the case of the important octylphenol ethoxylates [p-C8H17-C6H4-O-(CH2CH2O)n-H], HPLC cannot resolve individual oligomers of high molecular weight Triton surfactants (e.g., greater than 2000 u or so; u = unified atomic mass unit). In this paper, we show that laser desorption Fourier transform ion cyclotron resonance mass spectrometry (LD/FT/ICR/MS) provides a simple and accurate measure of such Triton surfactant molecular weight distributions up to at least 3500 u, based on a single-shot laser pulse measurement of a few seconds duration. Comparison of LD/FT/ICR/MS and HPLC molecular weight distributions of low molecular weight surfactants shows that laser desorption/ionization produces minimal fragmentation and thus offers an accurate measure of the relative abundances of the neutral oligomers, without the need for prior chromatographic separation of the components. Moreover, for all Triton polymer molecular weight distributions (700-3000 u), LD/FT/ICR/MS provides much more highly resolved profiles of oligomer relative abundances. Finally, LD/FT/ICR/MS reveals the presence of poly(ethylene oxide) side products of the polymerization process, which are not observed by HPLC with conventional ultraviolet absorption detection.     

锂离子电池有机电解液成膜添加剂的研究现状

文章综述了锂离子电池有机电解液成膜添加剂的作用原理，具体介绍了CO2、SO2、VC化合物、卤化物、有机铜盐以及马来酐等添加剂的研究现状。     

上海外环隧道水下最终接头的施工技术

沉管隧道采用水下最终接头,可以大大缩短工期和减少成本,但施工难度较大,而且有一定风险。文章以上海外环隧道工程为例,对沉管隧道水下最终接头的施工工艺中管段轴线精度控制、安装保护罩、间隙间的安全排水和混凝土施工等四大难点进行探讨,并介绍了水密性施工和管内结构施工的具体工艺和步骤。指出其成果对今后类似工程具有较大的参考价值。     

Identify unrepairability to speed-up spare allocation for repairing memories

In this paper, we discuss some strategies for identifying unrepairable memories, and from that to introduce a novel theorem that can make more precise identification. A new algorithm for searching repair solutions is also proposed, which characterizes the rows, and columns of defective memory cells with revised effective coefficients. We have simulated it on many generated example maps, and compared it with the previous algorithms to verify its efficiency. It's combined with those arranged strategies of judging unrepairability to generate a complete flow. The complete algorithm has also been run on many examples with various memory sizes, defect numbers, and distribution types. The simulation results further show that identifying unrepairability in advance can help the reconfiguration procedure run much faster than searching solutions directly.     

Structural study of cubic pyrochlores based on quantum mechanical simulation

In the ideal A₂B₂O₆O′ pyrochlore structure, the x-value of O atom position is a variable parameter. In Bi_1.5ZnNb_1.5−xTa_xO₇ (BZNT) cubic pyrochlores, the x-values alter with the different compositions of Nb/Ta. In this work, a series of initial models for BZNT were established by analyzing X-ray diffraction data. Then three structure modifying methods, including Rietveld refinement, Rietveld refinement with energy and geometry optimization based on quantum mechanics, were employed to obtain the precise models using Materials Studio. Moreover, the reflectivities of BZNT were computed by quantum mechanical simulation based on the refined models. Comparing the simulation results from different modifying models with the experimental results, it is found that Rietveld refinement with energy optimization is the most accurate method for BZNT pyrochlores. According to the simulation results, the different reflectivities correspond well with various x-values of O atom positions in BZNT pyrochlores.     

绿色再生混凝土利用途径与评定思路

就再生混凝土骨料进行深入系统的研究 ,建立了一套与现行评价天然骨料标准相一致的评定方法 ,具有工程实际意义 ,为将来实际应用作好了基础理论研究