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61.
Jun Rong Li Jun Wang Jia Rui Xu Ming Qiu Zhang Min Zhi Rong Qiang Zheng 《Composites Science and Technology》2006,66(16):3126-3131
The authors of this paper synthesized a series of amphiphilic triblock copolymers of polystyrene-b-poly(ethylene glycol)-b-polystyrene (PS-PEG-PS) having different PEG/PS ratios with nearly identical molecular weights of the entire copolymers. The interfacial interactions in the composites consisting of carbon black and the copolymers can thus be tailored. When these conducting composites are exposed to certain solvent vapors, their electrical resistances greatly increase, showing the gas sensitivity. The present work indicated that this switching behavior is controlled by the structural relaxation of the composites because matrix swelling acts as the main mechanism. The response time has been correlated with absolute temperature by Arrhenius equation, and the estimated activation energy reflects mobility of the fillers involved in the solvent induced expansion of the surrounding polymer. Therefore, by using the gas sensibility of the conductive composites, the structure evolution of the composite materials in solid state and the effect of filler/matrix interfacial interaction on the relaxation property of the matrix polymer has been inspected. It was found that lower activation energy represents stronger interfacial interaction in case good solvent of the matrix was used for the test. 相似文献
62.
高度有序多孔氧化铝模板的制备工艺与生长机制的研究 总被引:4,自引:0,他引:4
采用二次氧化法制备出高度有序的多孔氧化铝模板,结合扫描电镜和原子力显微镜对其结构、形貌进行观察和表征。研究了铝箔预处理和温度等对多孔氧化铝模板孔洞有序性的影响,讨论了有序孔洞的自组织生长机理。 相似文献
63.
Zhi‐Long Ye Min Lu Yan Zheng Ya‐Hong Li Wei‐Min Cai 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(11):1541-1550
BACKGROUND: Food waste generally has a high starch content and is rich in nutritional compounds, including lipids and proteins. It therefore represents a potential renewable resource. In this study, dining‐hall food waste was used as a substrate for lactic acid production, and response surface methodology was employed to optimise the fermentation conditions. RESULTS: Lactic acid biosynthesis was significantly affected by the interaction of protease and temperature. Protease, temperature and CaCO3 had significant linear effects on lactic acid production, while α‐amylase and yeast extract had insignificant effects. The optimal conditions were found to be an α‐amylase activity of 13.86 U g?1 dried food waste, a protease activity of 2.12 U g?1 dried food waste, a temperature of 29.31 °C and a CaCO3 concentration of 62.67 g L?1, which resulted in a maximum lactic acid concentration of 98.51 g L?1 (88.75% yield). An increase in inoculum size would be appropriate for accelerating the depletion of initial soluble carbohydrate to enhance the efficiency of α‐amylase in dining‐hall food waste fermentation. CONCLUSION: A suitable regression model for lactic acid production was developed based on the experimental results. Dining‐hall food waste was found to be a good substrate for lactic acid fermentation with high product yield and without nutrient supplementation. Copyright © 2008 Society of Chemical Industry 相似文献
64.
65.
Tingfang Hu Jinpeng Chen Haiyan Wang Jun Min Wei 《Petroleum Science and Technology》2006,24(12):1477-1484
Etherification reaction of FCC light gasoline over Hβ zeolite was investigated to decrease the light olefins in motor gasoline while enhancing octane. Etherification activity of several molecular sieve catalysts for FCC light gasoline was studied in a fixed-bed reactor. The influence of pore-enlarging agent (PEG) with different molecular weight, binder (γ-Al2O3), and peptizing agent (HNO3) in the shaping process on etherification activity of Hβ zeolite was studied. The impregnating ways of precursor of oxides and the order of extruding and impregnating were also investigated. The results show that the activity of extruded Hβ zeolite before impregnating precursor of oxides is higher than the reverse order. The best shaping condition obtained was PEG-4000 10%, γ-Al2O3 20%, and HNO3 10%. At the optimal reaction condition, the conversion of tert-olefins reached the peak. 62.93%, the yield of TAME, is also high and the technology can be applied to industry as well. 相似文献
66.
Woo Yong Sung Seung Min Lee Wal Jun Kim Jong Girl Ok Ho Young Lee Yong Hyup Kim 《Diamond and Related Materials》2008,17(6):1003-1007
Complementary electroplating combined with electrophoresis enhanced the field emission characteristics of emitters by improving the adhesions between CNT emitters and substrate. The emitting current of the CNT emitters prepared by our combined method increased nine times higher than that of CNT emitters prepared by electrophoresis only, since electroplating improved the adhesion of CNT emitters. During the life-time measurement for 10 h, the emitting current of CNT emitters fabricated by electrophoresis only was drastically decreased to 13% of the initial current, while that prepared by the combination of electrophoresis and successive electroplating decreased to 64% of the initial current. We suggest that our method is a promising approach for the efficient fabrication of reliable CNT emitters. 相似文献
67.
分析了湿法成形薄型陶瓷砖干燥的特点.具体讨论了微波干燥和少空气干燥方式在湿法薄形陶瓷砖干燥上中应用及干燥过程中坯体传动方式的选择。 相似文献
68.
利用流体力学理论 ,结合目前国内外最新的两相流理论和实验研究成果 ,在描述气液两相流水力计算、热力计算和流型判断的数学物理模型基础上 ,研制出适用于海洋、沙漠、丘陵地区原油与伴生气、凝析天然气与凝液输送工艺的一套新的计算模拟软件TFTCS。介绍TFTCS软件的结构、功能、适用范围。用该软件对锦州 2 0 - 2海底湿天然气管道进行模拟计算 ,并与管线生产数据进行对比 ,用国外同类软件PIPEPHASE进行验算。实例计算分析表明 ,该软件功能完善 ,操作方便 ,计算结果可靠 ,能满足油气混输管道的设计计算和生产管理的需要 相似文献
69.
The rate of filtration and the water content of cake are influenced by the existence of a dense skin in a highly compressible
cake. The phenomenon of the dense skin has been rarely studied, and its existence has not been verified experimentally. In
this study, the porosity variation in a very compressible cake is measured by using a new experimental apparatus, and with
this the existence of dense skin has been established experimentally. ‘Unified theory on solid-liquid separation’, a recently
developed theory, is utilized for calculating the porosity variation in a very compressible cake. 相似文献
70.
Tae Geun Kim Kyung Hyun Park Sung-Min Hwang Yong Kim Eun Kyu Kim Suk-Ki Min Si-Jeong Leem Jong-Il Jeon Jung-Ho Park Chang W.S.C. 《Quantum Electronics, IEEE Journal of》1998,34(8):1461-1468
GaAs-AlGaAs V-grooved inner stripe (VIS) quantum-well wire (QWW) lasers grown by metalorganic chemical vapor deposition with different current blocking configurations, n-blocking on p-substrate (VIPS), p-n-p-n blocking on n-substrate (VI(PN)nS) and p-blocking on n-substrate (VINS) have been fabricated and characterized. The VIPS QWW lasers show the most stable characteristics with effective current confinement: one of the lasers shows fundamental transverse mode, lasing up to 5 mW/facet, typical threshold current of 39.9 mA at 818.5 mm, an external differential quantum efficiency of 24%/facet, and characteristic temperature of 92 K. The current tuning rate was almost linear at 0.031 mm/mA, and the temperature tuning rate was measured to be 0.14 nm/°C. Comparison of the light output versus current characteristics of the lasers with different current blocking configurations is presented here 相似文献