Reaction mechanism and microstructure evolution of reaction sintered <Emphasis Type="Italic">h</Emphasis>-BN

Hexagonal boron nitride ceramic (h-BN) based on the nitridation of B powders was obtained by reaction sintering method. The effects of sintering temperature on the mechanical properties and microstructure of the resultant products were investigated and the reaction mechanism was discussed. Results showed that the reaction between B and N₂ occurred vigorously at temperatures ranging from 1 000 °C to 1 300 °C, which resulted in the generation of t-BN. When the temperature exceeded 1 450 °C, transformation from t-BN to h-BN began to occur. As the sintering temperature increased, the spherical particles of t-BN gradually transformed into fine sheet particles of h-BN. These particles subsequently displayed a compact arrangement to achieve a more uniform microstructure, thereby increasing the strength.     

Simple Preparation of Crystal Co3（BTC）2·12H2O and Its Catalytic Activity in CO Oxidation Reaction

Crystalline metal-organic framework cobalt(Ⅱ) benzenetricarboxylate Co3(BTC)2?12H2O(MOF-Co) has been prepared using solvothermal method. The reaction of cobalt(Ⅱ) nitrate and 1,3,5-benzenetricarboxylic(BTC) acid in a mixed solution of N,N-dimethylformamide(DMF)/C2H5OH/H2O(1:1:1, ν/ν) at low temperature for short reaction times produced this crystalline compound. Compared with traditional hydrothermal method, a mixed solution method for the synthesis of crystalline metal complex was found to be highly efficient. After water molecules were removed from this metal complex, its exposed nodes served as active sites. When this MOF-Co was employed in the oxidation of CO, it showed good catalytic properties causing 100% conversion of CO to CO2 at low temperature of 160 ℃.     

微创业:大学生创业实践教育的思考

大学生创业实践是高校创业教育的一个难题。当前国内高校创业教育普遍存在实践教育环节薄弱、效果不显著等问题,本研究同步社会经济发展,尝试以微创业视角思考高校创业实践教育,通过梳理微创业的概念及应用,从契合大学生需求角度分析微创业具有的时代性、低门槛、大众化、创新性等特点。并根据高校实际情况,从完善微创业环境、开设微创业课程、建立微创业实践基地、提供微创业网络平台服务等方面提出推动高校大学生微创业的路径建议。     

超细Al（OH）3的粒度控制研究

采用铝酸钠种子分解法制备超细Al（OH）3.用X射线衍射仪（XRD）表征了样品的晶相组成,用扫描电子显微镜（SEM）观察了样品的形貌,用激光粒度分析仪测定样品的粒度分布.研究了NaOH浓度、NaOH/Al（OH）3摩尔比,分解温度,分解时间、晶种率和搅拌速率等因素对Al（OH）3的粒度的影响.结果表明：NaOH浓度越高,分解温度越低,NaOH/Al（OH）3摩尔比越小,得到的Al（OH）3颗粒的粒度越小.试验条件为：NaOH浓度180 g/L,NaOH/Al（OH）3摩尔比1.15,分解温度40℃,分解时间26 h,晶种率8％,搅拌速率200 rpm时,氢氧化铝颗粒的平均粒度为2.89 μm.     

Electrochemical investigation of La0.4Sr0.6TiO3 synthesized in air for SOFC application

Journal of Applied Electrochemistry - La-doped titanate materials have been widely investigated as alternative Ni-free anodes for solid oxide fuel cells (SOFCs). In this study, La0.4Sr0.6TiO3 (LST)...     

硝硫混酸与Ag、Cu反应的动力学

用失重法探讨了硝硫混酸此例、浸出温度和时间等因素对银的溶解和铜的钝化的影响。结果表明:在一定的[HNO_3]范周内,较高温度时,银的溶解符合一级反应规律;求得银的溶解量与时间、HNO_3起始浓度等的关系式和相应的反应活化能;铜在此条件时是钝化的。本实验再一次证实了银的溶解和铜的钝化机理的正确性,也为银、铜的分离提供了实验依据。     

含Cl^-溶液中SO4^2-对316不锈钢临界点蚀温度的影响

采用外加恒电位下腐蚀电流-温度扫描方法研究了在0．5％Cl^-溶液中，SO4^2-浓度对316不锈钢点腐蚀行为的影响．结果表明，随着SO4^2-浓度的增加，钝化电流增加，开路电位降低．当SO4^2-浓度低于0．42％时，316不锈钢的临界点蚀温度比不存在SO4^2-时的临界点蚀温度低；当SO4^2-浓度大于0．42％时，临界点蚀温度比不存在SO4^2-时的临界点蚀温度高．从离子竞争吸附的角度进行分析，对SO4^2-加速与抑制点蚀两种作用规律的形成原因进行了解释．     

含B2O3渣系的热力学计算模型

根据炉渣结构的共存理论和相图，推导了ＣａＯＢ２Ｏ３和ＦｅＯＦｅ２Ｏ３Ｂ２Ｏ３渣系的热力学计算模型。结果表明：（１）理论计算的ＣａＯＢ２Ｏ３渣系的作用浓度ＮＣａＯ及ＮＢ２Ｏ３与实测的活度ａＣａＯ及ａＢ２Ｏ３一致；（２）理论计算的ＦｅＯＦｅ２Ｏ３Ｂ２Ｏ３渣系的氧化能力ＮＦｅｔＯ与实测的炉渣ＦｅｔＯ的活度值相符合。这说明本文提出的热力学计算模型是合理的。     

栅元有效共振积分的CUDA算法设计与实现

核反应堆中需要实时精确地计算堆芯和增殖材料的有效共振积分或群截面来实现反应堆的安全控制。整个计算过程因为涉及大量的积分运算和庞大的核素截面数据,采用常规的计算方法,计算时耗相当大。基于统一计算设备架构(CUDA)平台,利用图形处理器(GPU)的计算能力,对整个计算过程进行并行化分解,多线程同时运算,大幅度提升计算速度,降低时耗。实验结果表明,在GPU上并行计算所得结果与原始数据没有明显差异,且加速效果显著。