细胞激动素Kinetin合成的改进

介绍了用糠胺与腺嘌呤在催化条件下反应合成细胞激动素kinetin,该法原料易得,反应条件温和,产品收率及纯度都较高。     

气化炉复合炉衬的传热计算

新型 (多喷嘴对置 )水煤浆气化炉拟采用水冷管和耐火浇铸料组成的复合炉衬结构 .炉内的高温高压对复合炉衬的高温侵蚀十分严重 ,是影响其寿命的重要因素 ,因此合理设计气化炉复合炉衬的结构对充分发挥其材质的作用具有十分重要的意义 .建立了气化炉复合炉衬的传热计算的数学模型 ,同时编制了模型求解的计算程序 ,并用某工艺条件对复合炉衬的温度分布进行了计算 .结果表明 ,该方法可有效计算出复合炉衬的温度分布情况 ,为复合炉衬的设计、运行和维护提供理论依据     

Preparation,characterization, and adsorption properties for metal ions of a novel chelating resin containing sulfoxide and diethylene glycol

A novel chelating resin containing sulfoxide and diethylene glycol, poly{4‐vinylbenzyl‐[2‐2‐(hydroxyethyl)ethoxyl]sulfoxide} (PVESO) was synthesized using chloromethylated polystyrene (PS‐Cl) as material. Its structure was characterized by elemental analysis, infrared spectra, and scanning electron microscopy (SEM). The adsorption capacities of the resin for Hg²⁺, Ag⁺, Cu²⁺, Zn²⁺, and Pb²⁺ at various pH values were determined. The maximum adsorption capacities for Hg²⁺ and Ag⁺ were 1.56 and 0.75 mmol g^?1 respectively. The resin had high selectivity for Hg²⁺ and Ag⁺ over the pH range 1.0–7.0. The adsorption capacities for Hg²⁺ and Ag⁺ under competitive condition were also determined by batch experiment method. In addition, the adsorption kinetics of the resin towards Hg²⁺ at different temperatures was also investigated. The results showed that the adsorption rate was governed by film diffusion at 20°C and 25°C, by particle diffusion at 30°C and 35°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 6054–6059, 2006     

Propylene epoxidation in a microreactor with electric heating

Gas phase propylene epoxidation on gold catalysts has attracted wide attention from industry and academia due to its high selectivity. However, it suffers from low propylene conversion and rapid catalyst deactivation. Experiments showed that propylene conversion could be increased by raising H₂, O₂, or C₃H₆ concentration in the feed, but the feed compositions were within the explosion limit. It was also shown that the activity of the used catalyst could be fully recovered, but the regeneration temperature was 280 °C, much higher than that for reaction. Therefore a microchannel reactor was devised to suppress explosion and was constructed with Fecralloy, to raise the temperature rapidly for catalyst regeneration by electric heating. In two minutes the temperature of the reactor could be raised from 50 to 300 °C. Catalysts were coated on the alloy belt by dip coating, and the performance of the reactor was evaluated under different operating conditions. Results showed that in the microreactor the overall reaction rate was controlled mainly by the intrinsic reaction rate, and also influenced by film diffusion to a certain extent. The deactivated catalyst was regenerated in the microchannel reactor and the activity was fully recovered.     

进口刀盘圆环失效原因及改进

首先从材料力学角度分析了抚顺石化公司干法腈纶装置原进口切断刀盘圆环失效的原因 ,认为此种切断刀盘圆环系二维增强结构层压板 ,层间没有纤维增强 ,需要解决由二维增强向三维增强的过渡。给出了改进办法 ,寻求到三维增强的替代材料。同时介绍了机械加工测试及在线实验     

光学镜头调制传递函数的测试

为了定量、客观、全面地评价光学镜头的像质,介绍了光学镜头调制传递函数的测试。先简要叙述了测试的原理,并给出计算公式;然后介绍了测试步骤,其中包括固定、穿轴、测试中心视场和测试轴外视场;最后介绍了测试时的注意事项,包括对测试工装的要求、对测试平面的要求和正、负轴外视场测试值相差较大时的处理办法。     

锅炉水处理系统除氧器的研制

锅炉和循环水处理系统的氧腐蚀是各种腐蚀中最严重的一种。因此，对给水进行除氧处理应该是最有效的防止腐蚀的方法。本文针对新研制出的新型活性铁除氧剂，又研制出与之相配套的除氧设备。该设备具有理想的除氧效果，常温操作，结构简单，弥补了过去一些除氧设备的不足。     

Fabrication and optical characterization of poly(2,5‐di‐n‐butoxyphenylene) nanofibril arrays

Anodic aluminum oxide (AAO) membrane can be used as template for the synthesized nanostructures. In this article, we have prepared the AAO membrane by using electrooxidation of aluminum substrate in phosphoric acid, and fabricated poly(2,5‐di‐n‐butoxyphenylene) (BuO–PPP) nanofibril arrays by oxidative coupling polymerization of 1,4‐di‐n‐butoxybenzene (DBB) within the pores of the AAO template membrane. The detailed molecular structure of the polymer nanofibrils was characterized by using infrared and ¹H nuclear magnetic resonance spectra, and estimated to consist of almost equal fractions of 1,4‐ and 1,3‐ linkages. We have used transmission electron microscopy, scanning electron microscopy, and atom force microscopy to confirm the morphologies and images of the AAO template membrane and the fabricated nanometer scale of BuO–PPP nanofibril arrays. The experimental results demonstrated that the pores of the AAO membrane were regular and uniform, and parallel each other, and the BuO–PPP chains in the narrowest template‐synthesized nanofibrils were oriented parallel to the porous axes of the AAO membrane and perpendicular to the surface of the aluminum substrate. The polymer chain orientation was partially responsible for the enhanced conductivity. The ultraviolet absorption spectrum of the BuO–PPP nanofibril arrays shown that the polymer contains a better extended π‐conjugation system along poly‐(p‐phenylene) backbone, which resulted in longer wavelength shift of the absorption band, the absorption maxima were located at 258 nm (E₁ absorption band) and 332 nm (E₂ absorption band), respectively. Photoluminescence spectrum of the BuO–PPP nanofibril arrays exhibited a blue emission. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 425–430, 2004     

基于大数据背景下的企业生态系统架构研究

随着全球网络技术与移动通信设备的融合发展,“大数据”时代已经引起社会各界的重点关注。苹果、三星、华为、IBM、微软、腾讯等国际知名企业都开始建构出“大数据”时代的企业生态系统。本文将对“大数据”时代的企业生态系统的演化和建构进行深入分析。     

水基Fe3O4磁流体的制备工艺研究

用共沉淀法制备Fe3O4磁流体,总结出用十二烷基磺酸钠与聚乙二醇作为表面活性剂制备水基磁流体的合适条件:(1)反应温度为室温或不高于35℃;(2)表面活性剂十二烷基磺酸钠的最佳用量为0.0030～0.0040 g/80 mL;(3)第一次包裹的最佳pH为9～10;(4)聚乙二醇作为第二次包裹的表面活剂时,体系最佳温度为40℃左右;(5)表面活性剂聚乙二醇的最佳用量为0.0050～0.0060 g/80 mL。通过实验制得了能稳定存在180 d的水基磁流体。并用透射电镜、红外光谱、分光光度计、古埃磁天平等进行了初步表征。