纳米碳增强碳/酚醛材料的界面结构分析

研究了纳米碳粉强化后的碳/酚醛(C/Ph)复合材料的界面结构,分析了纳米碳粉对碳/酚醛复合材料的界面结构的影响,结果表明,纳米碳粉能有效改善碳化后的碳/酚醛材料的界面结构,界面裂纹宽度明显下降.     

Preparation and structure of fluorinated/non-fluorinated polyacrylate gradient emulsion blend film

The emulsion blend method, which is environmentally friendly and energy saving, was used to prepare a compositional gradient film of fluorinated/non-fluorinated polyacrylate in this paper. The size and glass-transition temperature (T_g) of the emulsion particles were designed to enhance the driving force of their selective congregation and promote the formation of gradient structure. The structures and surface properties of the obtained films were characterized. The results showed that when the fluorinated components have much smaller particle size and higher T_g than those of fluorine-free polyacrylate components, the gradient structures formed in the direction across the film thickness of the films. The concentration of the fluorinated component increased gradually from film-glass interface to film-air interface in the blend film, making the surface free energies of the two sides of the gradient film distinctively different.     

Rapid growth of angle-confined large-domain graphene bicrystals

In the chemical vapor deposition growth of large-area graphene polycrystalline thin films,the coalescence of randomly oriented graphene domains results in a high density of uncertain grain boundaries (GBs).The structures and properties of various GBs are highly dependent on the misorientation angles between the graphene domains,which can significantly affect the performance of the graphene films and impede their industrial applications.Graphene bicrystals with a specific type of GB can be synthesized via the controllable growth of graphene domains with a predefined lattice orientation.Although the bicrystal has been widely investigated for traditional bulk materials,no successful synthesis strategy has been presented for growing two-dimensional graphene bicrystals.In this study, we demonstrate a simple approach for growing well-aligned large-domain graphene bicrystals with a confined tilt angle of 30° on a facilely recrystallized single-crystal Cu (100) substrate.Control of the density of the GBs with a misorientation angle of 30° was realized via the controllable rapid growth of subcentimeter graphene domains with the assistance of a cooperative catalytic surface-passivation treatment.The large-area production of graphene bicrystals consisting of the sole specific GBs with a tunable density provides a new material platform for fundamental studies and practical applications.     

大直径PPS/PA6共混单丝的结构与性能研究

采用PPS/PA6共混的方法来改进大直径PPS单丝的力学性能.探讨了共混体系的结构对共混单丝力学性能的影响,并与相关聚合物单丝进行了对比分析,同时研究了共混单丝的耐酸碱性能.结果表明:PA6的加入能有效地改善PPS单丝的力学性能,提高了单丝的拉伸强度和勾结强度,增加了PPS单丝的韧性.同时,PPS/PA6共混单丝能保持...     

添加物对Fe_2O_3超微粒的稳定作用

粒子的尺寸直接关系着气敏元件性能的好坏．为了防止Ｆｅ２Ｏ３超微粒在气敏元件烧结过程中长大，我们在纯Ｆｅ２Ｏ３中掺入５ｍｏｌ％碱土金属离子，利用ＸＲＤ和ＴＥＭ系统研究了掺杂物对Ｆｅ２Ｏ３超微粒子的稳定作用，并对由掺杂引起的Ｆｅ２Ｏ３电学性质的变化作了初步探讨．     

多弧离子镀与磁控溅射共沉积TiN/TiCN多层膜的高温抗氧化性能

TiN/TiCN多层膜的高温抗氧化性研究对于扩大其应用领域具有重要作用,但目前鲜见相关报道。采用多弧离子镀与磁控溅射技术以不同调制周期在304不锈钢表面共沉积TiN/TiCN多层膜。采用XRD、XPS、倒置显微镜及高温氧化试验研究了多层膜的高温抗氧化行为。结果表明:TiN/TiCN多层膜表面光滑平整、均匀致密,薄膜主要为具有Ti-(C,N)键的fcc-TiN结构;随着调制周期的减小,TiN/TiCN多层膜生长取向发生转变,且具有(111)晶面生长织构;随着氧化温度的升高,多层膜的显微硬度逐渐降低,氧化增重速率不断增大,且在700℃之后变化速率较快,薄膜的开始氧化温度约为750℃;随着调制周期的减小,多层膜TiN与TiCN界面层数量增多,促使晶粒细化,提高了其致密性,还隔断了缺陷贯穿薄膜的连续性,显著降低了薄膜的孔隙率,致使O原子扩散困难,增强了薄膜的高温抗氧化性能。     

Microstructure developed in the surface layer of Ti-6Al-4V alloy after sliding wear in vacuum

Microstructural changes in the surface layer of Ti-6Al-4V alloy after sliding wear in vacuum have been studied by means of scanning and transmission electron microscopy (SEM and TEM). The wear rates of Ti-6Al-4V alloy in vacuum were measured under different sliding velocities and loads. The experimental results showed that a severely deformed layer with a grain size of 50–100 nm and thickness about 70 μm was formed underneath the worn surface. Under the slower sliding velocities, the substructure of the layer had a high dislocation density, while under higher sliding velocities, twins were found to exist in the substructure. A process by which the deformed layer formed has been proposed and the deformation of materials at the contacting spots of the Ti-6Al-4V sample is discussed.     

会计委派制在实际工作中的应用

实行会计委派制度是强化监督制约机制的有益尝试。由于明确了委派会计人员相对独立的职能地位,有利于充分发挥会计人员的职能作用,保证会计信息的真实和完整;有利于帮助被委派部门和单位依法理财,规范和加强预算资金和国有资产管理;有利于强化内部制约和外部监督机制,堵塞财务管理漏洞,从源头上预防和治理违反财经纪律的行为。     

加氢装置加热炉易爆管部位的分析

重点介绍韩国蔚山炼油厂分馏塔底重沸炉火灾事故、中国石油化工股份有限公司洛阳分公司催化裂化柴油加氢装置反应进料加热炉火灾事故、茂名分公司渣油加氢脱硫装置分馏炉火灾事故、镇海炼油化工股份有限公司加氢裂化装置脱丁烷塔底重沸炉火灾事故的情况,找出加氢装置加热炉的易爆管部位,并通过分析总结,提出了易爆管部位的选材原则、设计改进方案及维护措施.