Cationic latex interaction with pulp fibers. II. Modification of sheet properties by styrene butadiene latex with quaternized amino groups

Unbeaten kraft fibers covered with experimental cationic latexes were formed into sheets in which direct fiber-fiber bonds are replaced by polymeric bonds. The effect on sheet properties—breaking length, elongation at break, folding endurance, opacity, and light scattering—was evaluated as a function of latex composition. The composition was altered by either the ratios of styrene to butadiene in the polymer or by mixing soft film-forming and hard nonfilming latex. It is shown that, regardless of latex composition and mechanical properties of the polymeric film, all the latexes can modify the sheet properties to a similar extent, providing that the sheets are heated above the polymer's glass transition temperature. An improvement of tensile strength is accompanied by increased elongation. As a probable mechanism of reinforcement, it is suggested that the polymer acts as a filler of the fiber's surface irregularities, thus providing a larger contact area between fibers and an improved stress transfer between them.     

Mechanisms of antioxidant action: The effect of spin traps during the processing and photooxidation of PVC

It is demonstrated by the use of spin traps that during the early stages of thermal processing of PVC considerable concentrations (> 3 × 10^?6 mol g^?1) of free radicals are produced which are primarily responsible for the initial products (hydroperoxides, unsaturation, and hydrogen chloride) previously shown to be formed in the polymer. From a semiquantitative analysis of these products, it is estimated that more than 50% of the radicals are formed from hydroperoxides and the rest by mechanoscission of the polymer chain. The spin traps are effective processing stabilizers in combination with a tin maleate HC1 scavenger. One of them (2-methyl-2-nitroso propane, MNP) has also been shown to be a photoantioxidant.     

Propagation of the Chain Explosive‐Decomposition Reaction in Silver Azide Crystals

The velocity of the chain explosivedecomposition reaction in silver azide whiskes has been measured (1500 m/sec). The measured velocity is identified as the propagation velocity of the diffusion front of holes generated in the course of explosive decomposition.     

Soil removal as a rate process

The rate of soil removal during multiple cycle washing has been studied for three artificially soiled cotton test cloths. Results are considered in relation to a soil removal rate concept proposed some years ago by Vaughn, Vittone, and Smith. It is shown that the rate of removal for these soils, when washed in the Terg-O-Tometer with a built, anionic, synthetic detergent, does not correspond to a simple first order rate process as proposed by Vaughn et al. Rather, it was found that under a variety of washing situations the percentage soil removal increased linearly with the log of cumulative wash time. Further, it was shown that for those experiments involving detergent concentration or level of mechanical action, the slopes of these log time relationships, which reflect the rate of soil removal, vary in the expected manner.     

Influences of zinc oxide and an organic additive on the electrochemical behavior of pure aluminum in an alkaline solution

The corrosion behavior of pure aluminum in inhibited and uninhibited 4 MKOH was investigated by means of hydrogen collection, polarization curve measurement and electrochemical impedance spectroscopy (EIS). The results showed that the corrosion of pure aluminum was greatly inhibited by the addition of ZnO and dimethyl amine epoxy propane (designated as DE). EIS and EDAX analyses revealed that ZnO produces its effect by depositing on the aluminum surface, which increases the overpotential of hydrogen evolution. It was also found that the addition of DE could greatly improve the deposition of zinc layers.     

Structural and mechanical characteristics of aramid fibres for bullet-proof vests

The following conclusions can be drawn from an analysis of the data reported in the present article: SVM and Armos fibres are now the most promising for use in bulletproof materials; increasing the elongation to 5–6% while preserving the strength at the level of 400–450 kgf/mm ² allows increasing the efficiency of use of fibres for bulletproofing; the method proposed here allows rapidly and efficiently conducting comparative tests and initial selection of materials and the pack structure of the energy-absorbing polymer support; new types of bulletproof fabrics must be developed to increase the efficiency of manifestation of the energy-absorbing properties of fibres. Translated from Khimicheskie Volokna, No. 6, pp. 37–40, November–December, 1997.     

Improved bibliographic reference parsing based on repeated patterns

Parsing details like author names and titles out of bibliographic references of scientific publications is an important issue that has received considerable attention recently. However, most existing techniques are tailored to the highly standardized reference styles used in the last two to three decades. They do not perform well with the wide variety of reference styles used in older, historic publications. Thus, they are of limited use when creating comprehensive bibliographies covering both historic and contemporary scientific publications. This paper presents a generic approach to bibliographic reference parsing, named RefParse, which is independent of any specific reference style. Its core feature is an inference mechanism that exploits the regularities inherent in any list of references to deduce its format. In addition, our approach learns names of authors, journals, and publishers to increase the accuracy in scenarios where human users double check parsing results to increase data quality. Our evaluation shows that our approach performs comparably to existing ones with contemporary reference lists and also works well with older ones.     

Sodium bisulfite-initiated polymerization of methyl methacrylate in aqueous medium in the presence of the metal oxides CuO and MnO2

Sodium bisulfite-initiated polymerization of methyl methacrylate (MMA) in water medium was carried out in the absence and in the presence of cupric oxide and manganese dioxide using various initiator concentrations at various temperatures ranging from 30° to 60°C. It seems that the metal oxide–water interface plays an important role, as it has been found that both oxides accelerate the rate of polymerization. Cupric oxide was found to be more effective than manganese dioxide. The cupric oxide was found to have nearly the same catalytic effect as the cuprous oxide, and manganese dioxide was found to be somewhat more effective than titanium dioxide. The initial rate of polymerization increased from 2.3 × 10^?5 mole/(l.sec) to 3.4 × 10^?4 mole/(l.sec) and to 6.6 × 10^?5 mole/(l.sec) when the metal oxide concentration increased from 0 to 3 g/l. in case of cupric oxide and manganese dioxide, respectively. The initial rate of polymerization increased from 3.7 × 10^?4 mole/(l.sec) to 4.2 × 10^?4 mole/(l.sec) and from 7.2 × 10^?5 to 2.2 × 10^?4 mole/(l.sec) when the temperature was raised from 30° to 60°C in the presence of cupric oxide and manganese dioxide, (9 g/l.), respectively. Both the rate of polymerization and the number-average molecular weights were found to increase with increase the monomer concentration; the rate values were higher while the number-average molecular weights were lower in case of cupric oxide than in case of manganese dioxide. For example, the rate of polymerization increased from 2 × 10^?5 mole/(l.sec) to 8.1 × 10^?5 mole/(l.sec) and from 1.9 × 10^?5 mole/(l.sec) to 6.9 × 10^?5 mole/(l.sec); and the number-average molecular weight increased from 0.7 × 10⁵ to 2.2 × 10⁵ and from 1.5 × 10⁵ to 4.9 × 10⁵ in the presence of cupric oxide and manganese dioxide (10 g/l.), respectively, when the monomer concentration was increased from 23.5 g to 94 g/1. water. The apparent energy of activation for the polymerization of methyl methacrylate in water medium between 40° and 50°C was found to be 0.8 and 4.3 kcal/mole when using cupric oxide and manganese dioxide (9 g/l.), respectively.