Alder ene functionalization of polyisobutene oligomer and styrene-butadiene-styrene triblock copolymer

The Alder ene functionalization reaction of double bonds containing macromolecules such as polyisobutene oligomer (PIB) and a styrene-butadiene-styrene triblock copolymer (SBS) samples with maleic anhydride (MAH) or diethyl maleate (DEM) as enophiles is described. The analysis of the products by means of different techniques assesses the addition of the polar molecules to the reactive vinylidene units of the polymer with functional degrees (FD) depending on the type of enophile and polymer reactivity. The role of the reaction conditions and the use as Lewis acids as catalysts are discussed in terms of their influence on the addition reaction extent and on the polymer molecular weight.     

Enzymatic hydrolysis of cotton wastes. Effect of γ-ray pretreatments

Textile cotton wastes were irradiated with γ-rays at different doses and solubilized with 10% NaOH solutions. The regenerated products underwent enzymatic hydrolysis and their degradation pattern was compared with that of the cotton celluloses untreated or treated only with γ-rays. The different samples were characterized by measurements of X-ray diffraction, degree of polymerization, moisture regain and water retention. The structural and morphological modifications induced by the pretreatments were correlated with the variations of kinetic parameters, particularly the V_max/K_m ratio, defined as specificity constant. Only the combination of irradiation with dissolution pretreatments gave a considerable increase of hydrolysis reaction effectiveness.     

Effective molarities in supramolecular catalysis of two-substrate reactions

Reactivity data related to processes in which molecular receptors promote the reaction of two simultaneously complexed reactants have been surveyed and analyzed in terms of effective molarity (EM). Methods and criteria for the calculation of reliable EM's have been highlighted. Extension of a previous extrathermodynamic treatment of intramolecular reactions of bifunctional chains to the intracomplex reactions of the ternary complexes involved in two-substrate catalyzed reactions has provided a sound framework for a comparative analysis of reactivity and catalytic efficiency in structurally diverse and apparently unrelated systems.     

Ranking Approach for the User Story Prioritization Methods

The AHP （analytic hierarchy process） has been applied in many fields and especially to complex engineering problems and applications. AHP is capable of structuring decision problems and finding mathematically determined judgments built on knowledge and experience. This suggests that AHP should prove useful in agile software development, where complex decisions occur routinely. This paper describes a ranking approach to help stakeholders select the best prioritization method for prioritizing the user stories.     

Outlier detection using default reasoning

Default logics are usually used to describe the regular behavior and normal properties of domain elements. In this paper we suggest, conversely, that the framework of default logics can be exploited for detecting outliers. Outliers are observations expressed by sets of literals that feature unexpected semantical characteristics. These sets of literals are selected among those explicitly embodied in the given knowledge base. Hence, essentially we perceive outlier detection as a knowledge discovery technique. This paper defines the notion of outlier in two related formalisms for specifying defaults: Reiter's default logic and extended disjunctive logic programs. For each of the two formalisms, we show that finding outliers is quite complex. Indeed, we prove that several versions of the outlier detection problem lie over the second level of the polynomial hierarchy. We believe that a thorough complexity analysis, as done here, is a useful preliminary step towards developing effective heuristics and exploring tractable subsets of outlier detection problems.     

Scheduling algorithms for fault-tolerance in hard-real-time systems

Many time-critical applications require predictable performance in the presence of failures. This paper considers a distributed system with independent periodic tasks which can checkpoint their state on some reliable medium in order to handle failures. The problem of preemptively scheduling a set of such tasks is discussed where every occurrence of a task has to be completely executed before the next occurrence of the same task can start. Efficient scheduling algorithms are proposed which yield sub-optimal schedules when there is provision for fault-tolerance. The performance of the solutions proposed is evaluated in terms of the number of processors and the cost of the checkpoints needed. Moreover, analytical studies are used to reveal interesting trade-offs associated with the scheduling algorithms.This work has been supported by grants from the Italian Ministero dell'Università e della Ricerca Scientifica e Tecnologica and the Consiglio Nazionale delle Ricerche-Progetto Finalizzato Sistemi Informatici e Calcolo Parallelo.     

Magnetic Properties of Thermal Sprayed Tungsten Carbide–Cobalt Coatings

In the information age, the storage and accessibility of data is of vital importance. There are several possibilities to fulfill this task. Magnetic storage of data is a well‐established method and the range of materials used is continuously extended. In this study, the magnetic remanence of thermally sprayed tungsten carbide–cobalt (WCCo)‐coatings in dependence of their thickness is examined. Two magnetic fields differing in value and geometry are imprinted into the coatings and the resulting remanence field is measured. It is found that there are two effects, which in combination determine the effective value of the magnetic remanence usable for magnetic data storage.