CdTe/CdS thin film solar cells grown in substrate configuration

The ability to grow efficient CdTe/CdS solar cells in substrate configuration would not only allow for the use of non‐transparent and flexible substrates but also enable a better control of junction formation. Yet, the problems of barrier formation at the back contact as well as the formation of a p–n junction with reduced recombination losses have to be solved. In this work, CdTe/CdS solar cells in substrate configuration were developed, and the results on different combinations of back contact materials are presented. The Cu content in the electrical back contact was found to be a crucial parameter for the optimal CdCl₂‐treatment procedure. For Cu‐free cells, two activation treatments were applied, whereas Cu‐containing cells were only treated once after the CdTe deposition. A recrystallization behavior of the CdTe layer upon its activation similar to superstrate configuration was found; however, no CdTe–CdS intermixing could be observed when the layers were treated consecutively. Remarkably high V_OC and fill factor of 768 mV and 68.6%, respectively, were achieved using a combination of MoO₃, Te, and Cu as back contact buffer layer resulting in 11.3% conversion efficiency. With a Cu‐free MoO₃/Te buffer material, a V_OC of 733 mV, a fill factor of 62.3%, and an efficiency of 10.0% were obtained. Copyright © 2012 John Wiley & Sons, Ltd.     

Design of Engineered Elastomeric Substrate for Stretchable Active Devices and Sensors

In the field of flexible electronics, emerging applications require biocompatible and unobtrusive devices, which can withstand different modes of mechanical deformation and achieve low complexity in the fabrication process. Here, the fabrication of a mesa‐shaped elastomeric substrate, supporting thin‐film transistors (TFTs) and logic circuits (inverters), is reported. High‐relief structures are designed to minimize the strain experienced by the electronics, which are fabricated directly on the pillars' surface. In this design configuration, devices based on amorphous indium‐gallium‐zinc‐oxide can withstand different modes of deformation. Bending, stretching, and twisting experiments up to 6 mm radius, 20% uniaxial strain, and 180° global twisting, respectively, are performed to show stable electrical performance of the TFTs. Similarly, a fully integrated digital inverter is tested while stretched up to 20% elongation. As a proof of the versatility of mesa‐shaped geometry, a biocompatible and stretchable sensor for temperature mapping is also realized. Using pectin, which is a temperature‐sensitive material present in plant cells, the response of the sensor shows current modulation from 13 to 28 °C and functionality up to 15% strain. These results demonstrate the performance of highly flexible electronics for a broad variety of applications, including smart skin and health monitoring.     

An adaptive hybrid MOOC model: Disrupting the MOOC concept in higher education

In the 18th century, the educational model underwent a disruptive change driven by the transition from an agricultural to an industrial society. In the 21st century, the change from the industrial society to a knowledge society has been consolidated, but it has not involved a disruption in the learning context. Some elements, many based on technologies, can be considered disruptive, but they have not had sufficient effect to produce a change in the model that has predominated for 300 years. In 2008, teachers began to offer training outside the walls of the university, with a totally disruptive and chaotic model compared to the traditional one; this was supported by open, informal, cooperative, connectivist, autonomous and self-guided training. Massive open online courses (MOOCs) began with cMOOCs, and most universities join the initiative, but they abandoned this disruption, ultimately offering the same courses they always had with free access for anyone, resulting in the second generation of MOOCs (xMOOCs). These MOOCs responded to a new social demand, but their characteristics and context make a formative disruption – which has not yet emerged – necessary. This paper analyses the elements of the two generations of MOOCs in order to propose a new model that does not require sophisticated technological solutions and recovers the initial disruptive sense of MOOCs, so called ahMOOC. It also presents a case study that integrates the social advantages of cMOOCs, the organisational benefits of xMOOCs and the personalisation of the learning, which is essential due to the heterogeneity of the participants. The results and the participant viewpoints emerging from the case study confirm the feasibility of the model, the improvement of the results of current MOOCs and the need – demanded by the participants – to consider diversity, all of which should be accomplished in a disruptive way.     

Osteoconductive Performance of Carbon Nanotube Scaffolds Homogeneously Mineralized by Flow‐Through Electrodeposition

The treatment of bone lesions, including fractures, tumor resection and osteoporosis, is a common clinical practice where bone healing and repair are pursued. It is widely accepted that calcium phosphate‐based materials improve integration of biomaterials with surrounding bone tissue and further serve as a template for proper function of bone‐forming cells. Within this context, mineralization on preformed substrates appears as an interesting and successful alternative for mineral surface functionalization. However, mineralization of “true” 3D scaffolds –in which the magnitude of the third dimension is within the same scale as the other two– is by no means a trivial issue because of the difficulty to obtain a homogeneous mineral layer deposited on the entire internal surface of the scaffold. Herein, a “flow‐through” electrodeposition process is applied for mineralization of 3D scaffolds composed of multiwall carbon nanotubes and chitosan. It is demonstrated that, irrespective of the experimental conditions used for electrodeposition (e.g., time, temperature and voltages), the continuous feed of salts provided by the use of a flow‐through configuration is the main issue if one desires to coat the entire internal structure of 3D scaffolds with a homogeneous mineral layer. Finally, mineralized scaffolds not only showed a remarkable biocompatibility when tested with human osteoblast cells, but also enhanced osteoblast terminal differentiation (as early as 7 days in calcifying media).     

Contact effects in organic thin-film transistor sensors

Contact effects in organic thin-film transistors (OTFTs) sensors are here investigated specifically respect to the gate field-induced sensitivity enhancement of more than three orders of magnitude seen in a DHα6T OTFT sensor exposed to 1-butanol vapors. This study shows that such a sensitivity enhancement effect is largely ascribable to changes occurring to the transistor channel resistance. Effects, such as the changes in contact resistance, are seen to influence the low gate voltage regime where the sensitivity is much lower.     

Network and single user performance evaluation of a mobile data system over flat fading transmission channels

In this paper the contrasting effects of transmission impairments and capture on both the network and single user performance of a slotted Aloha system are investigated in a mobile radio environment, accounting for frequency non-selective random propagation phenomena, and employing the packet error probability in order to define packet losses and capture. With this study we demonstrate that it is possible to generalize in a real propagation context a method previously proposed in literature for evaluating the network behavior in terms of steady-state throughput, backlog and stability in conventional transmission conditions, i.e., when all the transmission channels were error-free and the collisions caused the loss of all the packets involved. Moreover, we indicate under which specific constraints on the terminal mobility we can apply this method to analytically predict the single user performance, which we show being an important design parameter. Through the numerical results reported we quantitatively point out that in the absence of coding capture increases system stability and moderately improves the overall system throughput and backlog. We also outline the trade-off between an increased capture gain obtained by means of coding and the corresponding system cost in terms of complexity and bandwidth occupancy. Furthermore, we demonstrate the unfairness which affects the single user performance and the consequent need for countermeasures in order not to discriminate among users differently located within the network; yet, this last solution is detrimental as regards the positive capture effects.This work was supported by M.U.R.S.T. and C.N.R. (Italy).     

Sputtered ZnO seed layer enhances photovoltaic behavior in hybrid ZnO/P3HT solar cells

We investigated the characteristics of inverted solar cells comprising bulk-heterojunction active layers of ZnO nanowire arrays and poly(3-hexylthiophene), P3HT. By utilizing a sputtered ZnO seed layer, we are able to grow vertically oriented ZnO nanowire arrays homoepitaxially. Unlike the ZnO nanowires that are grown on sol–gel derived seed layers, our nanowires are more uniform in their dimensions and spatial distribution. This sputtered seed layer also acts as the hole-blocking layer when these nanowire arrays are incorporated in solar cells; hybrid solar cells comprising these nanowires and P3HT exhibit power conversion efficiencies of 1.6%. To date, this is the highest efficiency observed for ZnO nanowire arrays:P3HT hybrid solar cells.     

Experimentation with a water tank including a PCM module

Storage of heat is seen as a major issue for the development of solar energy for house heating and cooling under all climates. Most of the storage systems available on the market use water as the storage medium. The idea studied here was to add a phase change material (PCM) module at the top of a hot-water storage tank with stratification. An experimental solar pilot plant was constructed to test the PCM behaviour in real conditions. The PCM module geometry adopted was to use several cylinders. A granular PCM–graphite compound was chosen as the PCM for the experiments presented here.     

Antioxidant and antibacterial activities of a starch film with bioextracts microencapsulated from cactus fruits (Opuntia oligacantha)

Food Science and Biotechnology - The use of unconventional sources is very relevant in the food area. In the present study the development of active films with the addition of bioextract (BE) or...