Dynamic and Partial FPGA Exploitation

Today's field programmable gate array (FPGA) architectures, like Xilinx's Virtex-II series, enable partial and dynamic run-time self-reconfiguration. This feature allows the substitution of parts of a hardware design implemented on this reconfigurable hardware, and therefore, a system can be adapted to the actual demands of applications running on the chip. Exploiting this possibility enables the development of adaptive hardware for a huge variety of applications. A novel method for communication interfaces using look up table (LUT)-based communication primitives enables an exact separation of reconfigurable parts and a fast and intelligent bus-system. A new adaptive software/hardware reconfigurable system is presented in this paper, using a real application in the automotive domain implemented on a Xilinx Virtex-II 3000 FPGA to present results     

Supramolecular Chemistry of Carbon-Based Dots Offers Widespread Opportunities

Carbon dots are an emerging class of nanomaterials that has recently attracted considerable attention for applications that span from biomedicine to energy. These photoluminescent carbon nanoparticles are defined by characteristic sizes of <10 nm, a carbon-based core and various functional groups at their surface. Although the surface groups are widely used to establish non-covalent bonds (through electrostatic interactions, coordinative bonds, and hydrogen bonds) with various other (bio)molecules and polymers, the carbonaceous core could also establish non-covalent bonds (π π stacking or hydrophobic interactions) with π-extended or apolar compounds. The surface functional groups, in addition, can be modified by various post-synthetic chemical procedures to fine-tune the supramolecular interactions. Our contribution categorizes and analyzes the interactions that are commonly used to engineer carbon dots-based materials and discusses how they have allowed preparation of functional assemblies and architectures used for sensing, (bio)imaging, therapeutic applications, catalysis, and devices. Using non-covalent interactions as a bottom-up approach to prepare carbon dots-based assemblies and composites can exploit the unique features of supramolecular chemistry, which include adaptability, tunability, and stimuli-responsiveness due to the dynamic nature of the non-covalent interactions. It is expected that focusing on the various supramolecular possibilities will influence the future development of this class of nanomaterials.     

Assessment of Methods Used in 1D Models for Computing Bed-Load Transport in a Large River: The Danube River in Slovakia

Comprehensive measurements of bed-load sediment transport through a section of the Danube River, located approximately 70?km downstream from Bratislava, Slovakia, are used to assess the accuracy of bed-load formulas implemented in 1D modeling. Depending on water discharge and water level, significant variations in the distribution of bed load across the section were observed. It appeared that, whatever the water discharge, the bed shear stress τ is always close to the estimated critical bed shear stress for the initiation of sediment transport τcr. The discussion focuses on the methods used in 1D models for estimating bed-load transport. Though usually done, the evaluation of bed-load transport using the mean cross-sectional bed shear stress yields unsatisfactory results. It is necessary to use an additional model to distribute the bed shear stress across the section and calculate bed load locally. Bed-load predictors also need to be accurate for τ close to τcr. From that point of view, bed-load formulas based on an exponential decrease of bed-load transport close to τcr appear to be more appropriate than models based on excess bed shear stress. A discussion on the bed-load formula capability to reproduce grain sorting is also provided.     

Green tea catechins of food supplements facilitate pepsin digestion of major food allergens,but hampers their digestion if oxidized by phenol oxidase

The in vitro gastric digestion of several food allergens (beta-lactoglobulin (BLG), alpha-lactalbumin (LA) and peanut allergens (PE)) in the presence of a catechin-enriched polyphenol extract of green tea (GTC), oxidized polyphenols and phenol oxidase processed food allergens and GTC was investigated. Pepsin-resistant proteins, such as BLG, major peanut allergens, Ara h 1 and Ara h 2, degrade faster in the presence of catechin-enriched green tea polyphenols. Phenol oxidase polymerized GTC affected adversely protein digestion of BLG and LA, but not digestion of PE proteins. Protecting effect of polyphenols correlated well with the ability of proteins to form insoluble complexes with oxidized catechins. Cross-linking of proteins and polyphenols further extended the half-lives of BLG and LA in the in vitro digestion by pepsin. Catechin-enriched green tea polyphenols of food supplements facilitate pepsin digestion of major food allergens, but hamper their digestion if oxidized and polymerized by phenol oxidase.     

Continuous Photo-Electro-Catalytic Synthesis of Bio-Based Adipic Acid with Reaction Kinetics Modeling

Photo-electro-catalytic oxidation reactions of 1,6-hexanediol were carried out in a coil-type continuous-flow microreactor with an immobilized TiO₂ catalyst material. Bio-based adipic acid was formed as the only intermediate product before the total mineralization process. The production was stable, enabling green, selective and continuous resource conversion, but with low, non-optimized yields. In addition, the catalyzed chemical kinetics was modeled, based on mechanisms as well as approximated rate-determining steps. The Butler-Volmer relation was used for activation. The electro-catalytic oxidative pathway was demonstrated to dominate over photo-catalysis, also on account of the band gap characteristics of the titania nanotube electrode.