High-temperature performance and microstructure of composite modified hard asphalt

Composite modified hard asphalt (CMHA) was prepared by four-step high-speed shearing method adding crumb rubber, styrene-butadiene-styrene (SBS) copolymer, and hard asphalt to QHD AH-70 neat asphalt. The high-temperature performance and microstructure of CMHA were evaluated by rotational viscometer, fluorescence microscopy, and infrared spectroscopy, through which the modification mechanism was proposed. The results show that the shearing time had great influence on the high-temperature performance of CMHA. A significant variation in phase morphology of CMHA during preparation was observed. It is found that phase morphology was converted from a continuous asphalt phase with dispersed polymer phase to two twisted continuous phases, then to a continuous asphalt phase with dispersed polymer phase again. Preparation of CMHA was a complex physical and chemical process. A fraction of SBS took part in the chemical reaction and others were dispersed in net structure, which is beneficial for workability and performance of asphalt.     

还原参数对F-T合成Fe-Mn催化剂物相结构的影响

在浆态床反应器中研究了还原气氛和还原压力对微球状FT合成FeMn催化剂织构性质和物相结构变化的影响,结果表明以H2还原后的催化剂比表面积最大,而以合成气或CO还原时,因积炭堵塞孔道,导致催化剂比表面积大幅降低;随还原气氛中CO分压的增大,物相中铁碳化物含量增加,有利于催化剂的还原与碳化;当采用不同还原压力的合成气还原时,催化剂比表面积随还原压力的升高而下降,此外,较高的还原压力使反应器中H2O/H2比增大,导致催化剂中的部分铁碳化物再氧化,因此催化剂中的铁碳化物含量随着还原压力的升高先增加后减少。     

我国浮式生产储油装置的研制与开发

我国自主研制了8艘浮式生产储油装置(FPSO)。依托这8艘FPSO,成功开发了10个海上油田,其中7个为年产油100×104m3以上的油田。在FPSO研制过程中,共申请了12项专利,制定了多项技术标准。FPSO的研制促进了相关学科的发展与人才培养,FPSO已成为海洋石油开发的战略性技术。目前中国海油3 900多万吨油当量的年产量中,75%的产能依靠FPSO支持。在研制FPSO过程中,已掌握了FPSO设计、建造的许多关键技术,并取得了多单元复杂系统总体优化设计技术、大型浮体浅水效应技术**、抗冰设计方法和抗强台风永久性系泊系统设计技术等4项核心技术的重大突破。这些关键技术与核心技术的掌握和突破,以及它们的成功应用,使FPSO在我国海洋石油工业发展进程中起到了关键作用。我国已成为世界上使用FPSO最多的国家之一,也是设计与建造FPSO最多的国家之一。我国的FPSO总体技术已达到当今国际先进水平。     

火成岩油藏特征及其测井响应

系统的阐述了火成岩的生成机制及其构造,结合其石油储存条件,分析得出火成岩油气藏的分布特征,成藏机制。并以塔里木油田和辽河油田对火成岩的勘探为实例,从测井分析角度阐述了火成岩的油气藏的勘探开发成果,尤其是塔里木油田的英买地区及辽河坳陷都在火成岩的部分岩层见到良好的油气显示。这说明与火成岩相关的油气聚集将成为石油勘探开发的一个具有很大潜力的新领域。     

Donor–acceptor copolymers based on benzo[1,2-b:4,5-b′]dithiophene and pyrene-fused phenazine for high-performance polymer solar cells

Two novel donor–acceptor (D–A)-type conjugated polymers of PTTPPz-BDT and PTTPPz-BDTT were successfully synthesized by Stille coupling polymerization, in which 7,8-dialkoxy benzo[1,2-b:4,5-b′]dithiophene (BDT) and 7,8-bithienyl benzo[1,2-b:4,5-b′]dithiophene (BDTT) were used as donor units, thiophene and pyrene-fused phenazine (PPz) were employed as π-bridges and acceptor units, respectively. High carrier mobilities, broad absorption spectra, narrow optical band gaps, and low HOMO energy levels were observed for both polymers. Furthermore, high-efficiency photovoltaic performance with power conversion efficiency (PCE) over 4.25% was exhibited in their polymer solar cells (PSCs) using [6,6]-phenyl-C₇₁-butyric-acid-methyl-ester (PC₇₁BM) as acceptor. The maximum PCE of 4.86% with short-circuit current density of 11.10 mA cm⁻² and fill factor of 62.5% was obtained in the PTTPPz-BDTT based cell. These results indicate that incorporating large planar PPz moiety into D–A-type copolymer is an efficient approach to improve photovoltaic performance for PSCs.     

高保真单昌金属线材的研究进展及其应用前景

单昌连铸技术是一项新型金属型材料造技术,该技术的特点是可以制造无限长的单晶导电金属线材,为高保真通讯电缆的开发提供优质导材材料,本文对该技术的国内外研究进展及其开发应用前景进行了比较全面的评述。     

The excition tunneling in ZnCdSe/ZnSe asymmetric double quantum well

Photoluminescence spectra of asymmetric double-quantum-well structure are studied in this paper. We show the excitation power dependence of exciton tunneling. Due to the different tunneling time of electrons and holes, space-charge effect is observed.     

Parasitic coplanar three-element dielectric resonator antennasubarray

A slot-coupled rectangular dielectric resonator antenna in the parasitic coplanar configuration is investigated experimentally. The measured results for impedance and radiation patterns are presented for the three-element case. It is found that by using suitable choice of the dimensions and offset distance of each dielectric resonator, the impedance bandwidth can be as high as three times that of the single-element structure