工艺参数对合成ZnO／Ag纳米复合抗菌剂产率的影响

通过正交实验，研究了反应温度、反应时间、反应物配比对ZnO／Ag纳米复合抗菌剂合成产率的影响规律。获得了高产率合成ZnO／Ag纳米复合抗菌剂的优选工艺条件：反应温度为10～25℃，ZnSO4与NH4HCO3的摩尔比为1：2-2．5，ZnSO4与NH4HCO3的反应时间为2．5～3h，AgNO3与NH4HCO3的摩尔比为1：1．5～2，反应时间为0．5h，ZnO／Ag的产率超过98％。XRD、TEM和SAED结果表明：ZnO／Ag纳米复合抗菌剂为具有纤锌矿结构的ZnO和立方结构的Ag组成。粒径为15～25nm，分散性较好。     

带斜裂纹模拟圆筒容器静压爆破和疲劳试验

本文提出了斜裂纹鼓胀效应修正系数公式.用该公式计算了带斜裂纹圆筒爆破载荷和开裂载荷,结果与实测大致相符,其平均误差在8%左右,可用于工程计算.本文还研究了斜裂纹疲劳扩展规律.采用直线法和投影法计算了疲劳扩展后的斜裂纹尖端应力强度因子。按照Paris 裂纹扩展方程整理了数据,然后获得了该钢种扩展速率方程,并论及了斜裂纹的扩展角问题.     

Effect of NiAl Microcrystalline Coating on the High-Temperature Oxidation Behavior of NiAl–28Cr–5Mo–1Hf

The effect of an NiAl microcrystalline coating prepared by magnetron sputtering on the high-temperature oxidation behavior of NiAl–28Cr–5Mo–1Hf was investigated in static air at 1000–1150°C. The additions of Cr, Mo, and Hf changed the single -phase structure into a multiphase structure [-NiAl, -Cr(Mo), and Heusler phase]. The NiAl–28Cr–5Mo–1Hf alloy formed a nonprotective mixed scale of Al₂O₃+Cr₂O₃+HfO₂ and exhibited relatively large weight gains. The large weight gains were attributed to extensive internal oxidation. The sputtered NiAl microcrystalline coating remarkably improved the oxidation resistance of NiAl–28Cr–5Mo–1Hf due to the formation of a compact and adherent Al₂O₃ scale at all test temperatures. It was found that the --Al₂O₃ transformation caused the anomalous behavior of the oxidation–kinetics curves of the NiAl microcrystalline coating in the temperature range 1000–1150°C. A change in the morphology of scales occurred with the transformation.     

防锈油膜在5% Na2SO4溶液中的半导体导电行为

采用电位—电容法及Mott-Schottky分析技术研究了自腐蚀电位条件下防锈油膜在5% Na2SO4溶液中失效过程的导电机制转变行为.防锈油膜在5% Na2SO4溶液中的失效过程存在半导体导电特征，随着浸泡时间的延长，防锈油膜从浸泡初期的p型半导体转变为n型半导体，转变过程中，防锈油膜中出现两个空间电荷过渡层.随着浸泡时间的延长，防锈油膜中的空间电荷层厚度皆逐渐减小，载流子密度则逐渐增加，并且计算了不同转变时期防锈油膜中的电子给体（ND）和电子受体（NA）密度大小.     

脉冲关断时间对电刷镀Ni/CNTs复合镀层组织及性能的影响*

采用脉冲电刷镀的方法,制备了镍/碳纳米管（Ni/CNTs）复合镀层.运用扫描电子显微镜（SEM）、X射线能谱分析仪（EDS）、透射电子显微镜（TEM）、球盘式磨损试验机、显微硬度计等分析与测试方法,研究了脉冲关断时间对Ni/CNT复合镀层的表面形貌、孔隙率、CNTs含量、显微硬度和耐磨性等的影响.结果表明：在直流电源下,由于导电性和准一维性碳纳米管的共沉积,复合镀层表面粗糙,孔隙率高.采用脉冲电源后,当脉冲关断时间增加至1 900μs时,复合镀层的表面平整度增加、孔隙率减小为1%、硬度增加为605 HV、磨损重量减小1/3.     

Influence of thermal exposure on the microstructures and mechanical properties of a superalloy

The effects of long-term aging on microstructures and their influence on tensile and stress-rupture behavior of a corrosion resistant nickel-base superalloy are investigated. Samples are aged isothermally at 1073, 1123, or 1173 K for different times of up to 10,000 h and mechanical tests are performed on samples in both standard heat treatment (SHT) and aged conditions. Scanning electron microscopy (SEM) studies reveal that the coarsening kinetics of γ′ follows a linear law at different temperatures with the calculated activation energy, i.e., 255 kJ/mol, for γ′ growth according to Lifshitz-Slyozof-Wagner (LSW) theory. After long-term aging for more than 1 khours, σ phase appears in the alloy. The kinetics of σ formation can be described by the Johnson-Avrime-Mehl equation. Tensile experiments at room temperature and 1173 K and endurance experiments at 1173 K/274 MPa are performed to test the effect of σ phases on these properties and no remarkable harmful effect is found. γ′ coarsening can be used to explain the reduction of yield stress, which is tested by the Labusch-Schwarz hardening theory. Although the presence of the σ phase clearly does affect the fracture process, the σ phase does not embrittle the alloy.     

四辊轧机轧辊弹性变形解析模块的开发

采用影响函数方法开发了四辊轧机轧辊弹性变形解析模块，完善了辊间压扁和工作辊压扁影响函数计算模型，克服了轧辊压扁影响函数计算过程浮点数被零除的缺陷，提出了平滑指数和收敛指标取值的处理方法，有效地解决了四辊轧机辊系弹性变形计算精度及收敛问题。该模块适应于普通四辊轧机、PC轧机和CVC轧机轧辊弹性变形计算，为热轧带钢板形控制提供了解析工具。     

安哥拉南部社会住房项目设计优化探讨

安哥拉南部社会住房项目具有平面空间及纵向海拔跨度大,气候、地形、地貌以及地质状况存在巨大差异且复杂多变的特点。施工图阶段如何合理的利用现状地形、当地材料及施工技术水平进行设计方案优化,达到降低工程造价、削弱施工难度、缩短工期、推进项目的顺利实施是该项目中的重要问题。通过对该项目设计优化的分析和研究,探讨出适合海外EPC项目的设计优化原则和方法,并总结了安哥拉南部社会住房项目设计优化经验,可为其他海外EPC项目的设计工作提供重要的借鉴。