Artificial Opals as Effect Pigments in Clear‐Coatings

Summary: In this paper, we describe the use of artificial opals from polymer beads as effect pigments in transparent industrial and automotive coatings. For this purpose, we synthesized monodisperse colloids from fluorinated methacrylates by surfactant‐free emulsion polymerization. The fluorinated monomers, in combination with crosslinking, lead to a refractive index contrast, thermal stability, and solvent resistivity necessary for use as effect pigments. After crystallization of the monodisperse polymer beads, crystal flakes with iridescent colors can be obtained. The crystal flakes can act as effect pigments in various transparent industrial and automotive coatings. Due to photonic crystal behavior of effect pigments, color flops up to 100 nm are observed.

Crystal flakes of CS ‐7 as effect pigments in a transparent coating. The diameter of the tube is 5 mm.     

Electrochemistry and spectro-electrochemistry of dithizonatophenylmercury(II)

The reactions between dithizone (H₂Dz, (1)) or potassium dithizonate (K⁺HDz⁻, (2)) and phenylmercury(II) chloride gives PhHg(HDz), (3). Complex (3) is photochromic. In dichloromethane, the blue photo-exited state of (3) exhibits a first order relaxation process to regenerate the orange ground state with rate constant 0.00053 s⁻¹. The half life of this relaxation is ca. 1300 s. Electrochemically, on cyclic voltammetry time scale, the oxidations of (1) and (3) are different. A comparative voltammetric and spectro-electrochemical study of (1) and (3) in CH₂Cl₂ containing 0.1 mol dm⁻³ [N(ⁿBu)₄][B(C₆F₅)₄] revealed that the mercapto group of (1) can be oxidised in two one-electron transfer steps. A disulphide is first produced and then in a second oxidation step, HDz⁺ is formed. In contrast, complex (3) shows only one ligand-based oxidation step. Upon complexation with phenylmercury the free mercaptan group of (1) becomes a stable “metal thioether”, Hg–S–C, which effectively prevents disulphide formation in (3) upon electrochemical oxidation. Both (1) and (3) shows two reduction steps. The electrochemical fingerprint of blue photo-excited (3) is identical to that of the orange ground state as no new functional groups are introduced upon irradiation; only bond rotation occurs. The different electronic spectra for each of the redox states of (3), obtained from spectro-electrochemical measurements, revealed that only the (3)/(3⁻) couple exhibits electrochromic properties.     

Impairment of memory for spatial context in schizophrenia.

A group of 33 patients with schizophrenia were compared with control participants using a spatial memory task in which words were presented on locations of a grid. In the first part of the experiment, recognition of target information (words) was tested. In the second, 2 tasks of spatial location (contextual information) were given involving different sets of words placed in different locations: A location memory task (determining which word was in a particular spatial location) explored an associative form of spatial memory, and a relocation task (determining where a particular word was located) explored an associative and a nonassociative form of spatial memory. Patients were more impaired with regard to the location memory task than to the target recognition and relocation tasks. The impairment was negatively correlated with Stroop task performance. The results suggest that schizophrenia is associated with a spatial context memory deficit, which could be due to defective associations between target and spatial information. This deficit seemed to be related to frontal dysfunction. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Malnutrition in food-surplus areas: experience from nutritional surveillance for decentralized planning in Haiti

In Haiti, a novel approach to nutritional surveillance was developed on the basis of a low-cost, simple-to-repeat set of household surveys in all nine administrative departments using sentinel community sites. This system allows each department to independently conduct follow-up surveys as needed. The results of the first round of surveys conducted in 1995 show lower malnutrition rates in typical food-deficient departments and high levels of malnutrition in several food-surplus areas. Further analyses underscore the importance of variables related to child-care practices and of care-enabling factors such as household food security, health environment, and caregivers' time and education. These findings challenge the traditional thinking among a majority of Haitian policy makers who look at the malnutrition problem solely from the perspective of local food production.     

Harris Hawks Optimizer with Graph Convolutional Network Based Weed Detection in Precision Agriculture

Precision agriculture includes the optimum and adequate use of resources depending on several variables that govern crop yield. Precision agriculture offers a novel solution utilizing a systematic technique for current agricultural problems like balancing production and environmental concerns. Weed control has become one of the significant problems in the agricultural sector. In traditional weed control, the entire field is treated uniformly by spraying the soil, a single herbicide dose, weed, and crops in the same way. For more precise farming, robots could accomplish targeted weed treatment if they could specifically find the location of the dispensable plant and identify the weed type. This may lessen by large margin utilization of agrochemicals on agricultural fields and favour sustainable agriculture. This study presents a Harris Hawks Optimizer with Graph Convolutional Network based Weed Detection (HHOGCN-WD) technique for Precision Agriculture. The HHOGCN-WD technique mainly focuses on identifying and classifying weeds for precision agriculture. For image pre-processing, the HHOGCN-WD model utilizes a bilateral normal filter (BNF) for noise removal. In addition, coupled convolutional neural network (CCNet) model is utilized to derive a set of feature vectors. To detect and classify weed, the GCN model is utilized with the HHO algorithm as a hyperparameter optimizer to improve the detection performance. The experimental results of the HHOGCN-WD technique are investigated under the benchmark dataset. The results indicate the promising performance of the presented HHOGCN-WD model over other recent approaches, with increased accuracy of 99.13%.     

Saccharomyces spores are born prepolarized to outgrow away from spore–spore connections and penetrate the ascus wall

How nonspore haploid Saccharomyces cells choose sites of budding and polarize towards pheromone signals in order to mate has been a subject of intense study. Unlike nonspore haploids, sibling spores produced via meiosis and sporulation by a diploid cell are physically interconnected and encased in a sac derived from the old cell wall of the diploid, called the ascus. Nonspore haploids bud adjacent to previous sites of budding, relying on stable cortical landmarks laid down during prior divisions, but because spore membranes are made de novo, it was assumed that, as is known for fission yeast, Saccharomyces spores break symmetry and polarize at random locations. Here, we show that this assumption is incorrect: Saccharomyces cerevisiae spores are born prepolarized to outgrow, prior to budding or mating, away from interspore bridges. Consequently, when spores bud within an intact ascus, their buds locally penetrate the ascus wall, and when they mate, the resulting zygotes adopt a unique morphology reflective of repolarization towards pheromone. Long‐lived cortical foci containing the septin Cdc10 mark polarity sites, but the canonical bud site selection programme is dispensable for spore polarity, thus the origin and molecular composition of these landmarks remain unknown. These findings demand further investigation of previously overlooked mechanisms of polarity establishment and local cell wall digestion and highlight how a key step in the Saccharomyces life cycle has been historically neglected.     

Development of two multiplex polymerase chain reactions for the detection of enterotoxigenic strains of Staphylococcus aureus isolated from foods

Two multiplex polymerase chain reactions were developed for the detection of enterotoxigenic strains of Staphylococcus aureus: one multiplex reaction for the simultaneous detection of enterotoxigenic strains type A (entA), type B (entB), and type E (entE) and another for the simultaneous detection of enterotoxigenic strains type C (entC) and type D (entD). Both reactions were standardized with the use of the reference enterotoxigenic strains of S. aureus: FRI 722, producer of staphylococcal enterotoxin (SE) type A (SEA); FRI 1007, producer of SEB; FRI 137, producer of SEC1; FRI 472, producer of SED; and FRI 326, producer of SEE. Optimized methods were used to determine the presence of enterotoxigenic types for 51 S. aureus strains isolated from meat (sausage, ham, and chorizo) and dairy (powdered milk and cheese) products by the Baird-Parker technique. The enterotoxigenic capacities of the strains were determined by the indirect enzyme-linked immunosorbent assay (ELISA) with the use of reference staphylococcal toxins and antitoxins. Fifty of the 51 strains isolated were enterotoxigenic and produced one to four enterotoxin types, with the most frequently produced types being SEA and SED. Levels of correlation between the presence of genes that code for the production of SE (as determined by polymerase chain reaction) and the expression of these genes (as determined by the indirect ELISA) were 100% for SEA and SEE, 86% for SEC, 89% for SED, and 47% for SEB.