Stable lead isotopes and lake sediments--a useful combination for the study of atmospheric lead pollution history

Analysis of stable lead isotopes and lead concentrations in lake-sediment deposits, not least in varved (annually-laminated) sediments, is a useful method to study lead pollution history. This paper presents details from a study of 31 lakes in Sweden. Using a strong acid digestion of sediment samples and ICP-MS analyses, we have found that Swedish lake sediments have a high natural (pre-pollution) 206[Pb]207[Pb] ratio (mean 1.52+/-0.18, range 1.28-2.01, n=31 lakes). In contrast, atmospheric lead pollution derived from metal smelting processes, coal burning and from alkyl-lead added to petrol has a lower ratio (< 1.2). Consequently, when pollution lead deposition began approximately 3500 years ago, the lead isotope ratio of the sediments started to decline, and in modern sediments it is typically < 1.2. Using the isotope and concentration values and a mixing model, the relative contribution of pollution and natural lead in sediment samples can be calculated. The pollution lead records of the Swedish lake sediments show a consistent picture of the atmospheric lead pollution history. Some noticeable features are the Roman peak (approx. 0 AD), the large and permanent Medieval increase (approx. 1000 AD), peaks at approximately 1200 and 1530 AD, the rapid increase after World War II, the peak in the 1970s, and the large modern decline.     

Long-term geophysical observations on the inguri dam rock foundation

Bulletin of Engineering Geology and the Environment - It has been found that during construction of the dam, prior to the filling of the reservoir, compaction and loading of the rocks under the...     

Combined nitrification/denitrification in a membrane reactor

An ever stricter legislation regulating wastewater leads to an increasing demand for biological treatment plants which are able to selectively eliminate nitrogen from wastewaters with a high influent concentration, even when operating in partial influent mode. A membrane-tube-module (MSM) reactor (Membran-Schlauch-Modul-Reaktor) was constructed and realized in the IUV at the University of Bremen. The present approach makes use of all the various layers of the whole biofilm, enabling nitrification and denitrification processes to run simultaneously in one and the same biofilm under optimized conditions. The biological degradation capacity of the system was first successfully tested with synthetic wastewater, and subsequently in a real application with effluents from a recycling of animal carcasses plant and from a coke-oven plant. A mathematical model was devised which describes this biofilm system. The resulting equations were solved by means of the simulation software AQUASIM.     

Experience with algal blooms and the removal of phosphorus from sewage

The growth of algae and occurrence of algal “blooms” in a number of different waters are described.They cover the period 1930–1940 when only natural phosphates would be present.The waters were drawn from either protected catchments or from a fully treated domestic supply.Spasmotic blooms in a fully treated domestic supply suggest that the mechanism which “triggers” the start of an algal bloom may be neither nutrient concentration nor the concentration of organic matter.It is considered that the pH, alkalinity, carbon dioxide equilibrium condition is a major factor, not only in promoting, but also in maintaining algal blooms.     

The bacterial population of piggery-waste anaerobic digesters

A survey was made of the anaerobic and facultatively anaerobic bacteria present in piggery waste, digesting piggery waste and domestic anaerobic sludge sludge used to start a piggery waste digester. An influence of the input waste was shown in that streptococci, the predominant facultatively anaerobic bacteria in the piggery waste, were the predominant bacteria in the digesting waste, and they replaced Enterobacter, predominant in the domestic sludge, when a piggery waste digestion had been established from this latter material. Cellulolytic or methanogenic bacteria could not be detected in the piggery waste but populations of these, and other hydrolytic bacteria, became established at different times during the buildup of digestion by gradual addition of piggery waste to water. The bacteria concerned in degradation of the waste constituents were all anaerobes.Production of methane from H₂/CO₂, formate and butyrate could be detected in mixed cultures from dilutions of digester contents, but the only methanogenic bacterium that could be isolated in pure culture was Methanobacterium formicicum, which uses H₂/CO₂ or formate only.     

Technique for measuring metallic salt effects upon the indigenous heterotrophic microflora of a natural water

The effects of several concentrations of the metallic salts Ag₂SO₄, NaAsO₃, BaCl₂2H₂O, CdCl₂2.5 H₂O, CrCl₂6H₂O, CuCl₂, HgCl₂, NaCl, NiCl₂6H₂O, PbCl₂ and ZnCl₂ upon the indigenous heterotrophic microflora of a natural water were studied. Effects of these salts upon the heterotrophic activity of the microbes were assayed using the heterotrophic technique whereas lethal effects upon the heterotrophic bacteria were determined using nutrient agar plate counts. The heterotrophic activity method is based upon the uptake and mineralization of a radioactively labeled metabolite (in these experiments ¹⁴C-glucose) by the indigenous aquatic microbes and data analysis is by Michaelis—Menten enzyme kinetics equations. Concentrations of metallic salts which resulted in bacterial death also caused erratic uptake and mineralization rates of ¹⁴C-glucose whereas sub-lethal concentrations, as determined by nutrient agar plate counts, caused a non-competitive inhibition of maximum heterotrophic activity and markedly increased the turnover time of the glucose substrate.     

Earthquake analysis of isotropic asymmetric multistory buildings

Isotropic multistory buildings are the ones characterized by the property: all load‐resisting planar frames have proportional lateral stiffness matrices. In the present paper it is proved that the modal analysis of an N‐story isotropic asymmetric, torsionally coupled, building (a problem of order 3N) can be separated into two independent sub‐problems: (a) a sub‐problem that corresponds to a single‐story asymmetric, torsionally coupled, building (a problem of order 3); and (b) a sub‐problem that corresponds to an N‐story, torsionally uncoupled, planar frame (a problem of order N). It is also demonstrated that the orientation of peak modal seismic forces of the building is independent of the orientation of seismic excitation, which affects only their size. The separation provides a better insight into the structural behavior of asymmetric multistory buildings under earthquake ground motion. Copyright © 2006 John Wiley & Sons, Ltd.     

Monitoring and kinetic study of ammonia oxidation using dissolved oxygen electrode and NAD(P) H fluorometer

The ammonia oxidation of a mixed culture enriched from a wastewater treatment plant sludge was monitored by a DO probe and a nicotinamide adenine dinucleotide (phosphate) (NAD(P)H) fluorometer. Under fixed aeration, DO reflected ammonia oxidation effectively. According to the DO profiles and the total ammonia concentrations analyzed experimentally, the ammonia oxidation kinetics of the enriched culture was determined. The ammonia oxidation rate was found sensitive to pH, especially at low total ammonia concentrations. At high concentrations of total ammonia, the maximum ammonia oxidation rate occurred at pH 7.6+/-0.1. At low concentrations, the pH sensitivity intensified significantly and the apparent optimal pH shifted higher with decreasing total ammonia concentrations, because NH3 molecules were the true substrate for ammonia oxidation and more NH4+ ions were converted to NH3 molecules at higher pH. The ammonia oxidation kinetics was therefore developed according to the concentration of NH3 molecules, instead of the commonly used total ammonia concentration. The kinetics followed Michaelis-Menten behavior for both DO and NH3 concentration: the maximum rate was 16.7+/-0.7 mg NH3-N/(g TSS-h) and the Michaelis constants for DO and NH3 were (14+/-2)% air saturation and (4.4+/-0.4) x 10(-2) (mg NH3-N/L), respectively. It was also concluded from the study that with or without exogenous organic substances, the NAD(P)H fluorescence of the enriched nitrifying culture was undetectable. The fluorescence did not respond to addition or depletion of substrate (ammonia, glucose, or acetate), change between aerobic and anaerobic conditions, or even KCN addition to kill the culture.     

The Italian national survey of indoor radon exposure

An investigation is being developed by the Camitato Nazionale per la Ricerca e per lo Sviluppo dell'Energia Nucleare e delle Energie Alternative, ENEA, to assess the indoor exposure of the Italian population. The programme, which started in 1982, includes regional and local surveys in all the administrative districts and intensive investigations of factors which influence indoor radon levels. The survey is organized by statistical areas of sampling to obtain representative samples of houses. The definition of the areas takes into account basic parameters e.g. geolithological environments, radon soil gas from underlying soils and rocks, specific activities of local building materials, climatic and seasonal variations, building technology, types of houses and town planning. The collected data may also be used for the compilation of radon risk maps to plan special monitoring and remedial actions if needed. Preliminary results concerning the above items are discussed.