Electrically conducting thin films obtained by ion implantation in pyrolyzed polyacrylonitrile

Heat treatment of polyacrylonitrile (PAN) leads to products with semiconductor-to-metal range of conductivities. The electrical properties of these materials are further modified by ion implantation. The conductivity, 1×10^–7 (Ω cm)^–1, of heat treated PAN at 435°C (PAN435) increases upon ion implantation with As⁺, Kr⁺, Cl⁺ or F⁺, reaching the maximum value of 8.9×10^–1 (Ω cm)^–1 at a dose of 5×10¹⁶ ion/cm² and an energy of 200 KeV for the case of F⁺ implantation. On the other hand, ion implantation in the more conducting heat-treated PAN at 750 °C (PAN750) leads to a decrease in the electrical conductivity. It is shown that the conductivity modifications are primarily due to structural rearrangements induced by the energetic ions. Specific chemical doping contribution to conductivity is noted for halogen implantation in PAN435. The temperature dependence of conductivity of PAN heat treated at 750°C suggests a two path conduction, namely a three dimensional variable range hopping conduction and a metallic conduction. After ion implantation, the conductivity-temperature dependence is interpreted in terms of a variable range hopping conduction mechanism. Received: 25 August 2000 / Reviewed and accepted: 28 August 2000     

The influence of reusing ‘Formtex’ controlled permeability formwork on strength and durability of concrete

The effects of the reuse of ‘Formtex’ Controlled Permeability Formwork (CPF) liner on strength and durability properties of concrete were investigated at two different water-cement ratios and the results are reported in this paper. Test blocks were cast using the CPF on one side and impermeable formwork (IF) on the opposite side of the mould so that direct comparisons could be made between the two. The strength was assessed using the Limpet pull-off tester and both the air permeability and the water absorption (sorptivity) were measured using the Autoclam Permeability System. Both these instruments measured the ‘covercrete’ properties. In addition, cores cut from the test specimens were subjected to an accelerated carbonation test and a chloride exposure test. The results showed that the ‘Formtex’ CPF increases the surface strength and the durability of concrete compared to the IF. There was an almost complete elimination of blowholes. The permeability of concrete decreased and its resistance to the ingress of both carbon dioxide and chlorides increased when CPF was used. The beneficial effects of the Formtex CPF were most evident in concrete of higher water-cement ratio. With the reuse of the Formtex liner twice, that is a total of three uses, the performance of the CPF to improve the properties of concrete remained almost the same. In this research the CPF liner was cleaned thoroughly between each use, which must be adhered to for site applications for reproducing the beneficial effects observed in the laboratory.     

Selection of Methodology for Neural Network Modeling of Constitutive Hystereses Behavior of Soils

Classic constitutive modeling of geomaterials based on the elasticity and plasticity theories suffers from limitations pertaining to formulation complexity, idealization of behavior, and excessive empirical parameters. This article capitalizes on the modeling capabilities of neural networks as substitutes for the classic approaches. The neural network–based modeling overcomes the difficulties encountered in understanding the underlying microscopic processes governing the material's behavior by redirecting the efforts into learning the cause-effect relations from behavioral examples. Several methodologies are presented and cross-compared for effectiveness in approximating a theoretical hysteresis model resembling stress-strain behavior. The most effective methodology was used in modeling the constitutive behavior of an experimentally tested soil and produced models that simulated the real behavior of the soil with high accuracy. Although these models are empirical, they are retrainable and thus, unlike classic constitutive modeling techniques, can be revised and generalized easily when new data become available.     

An Investigation of Branch and Bound Methods for Solving the Segregated Storage Problem

The segregated storage problem consists of determining a minimum cost distribution of products among compartments such that only one product may be stored in a given compartment. This paper explores the computational aspects of using branch and bound methods to solve this problem. Such methods were first suggested for this problem by White and Francis. A variety of approaches are tested, utilizing heuristic node selection and branching decision rules. Three heuristics are also presented which generate solutions for use as initial upper bounds for improving efficiency of the branch and bound procedure or as solutions for very large problems.     

Recent Advances in Poly (Amide-B-Ethylene) Based Membranes for Carbon Dioxide (CO2) Capture: A Review

Polyamide-b-ethylene (Pebax) is a promising material for membrane-based gas separation application with excellent CO₂ capturing potential. Pebax is a rubbery elastomer which offers good mechanical support with its hard crystalline phase and excellent gas transport through its amorphous polyether phase. This review article includes recent advances in Pebax based membrane synthesis, solvent selection for membrane synthesis, compatible fillers with Pebax matrix and the improved gas separation performance of the prepared membranes. The literature review shows that Pebax based membranes are a good candidate for separation of CO₂ from flue gases and can be used for commercial applications.     

A New Method for Siting Hazardous Units in Chemical Process Facilities Which Minimizes Risk at Least Cost: RIDIMPUS

A new method, RIsk and DIstance Minimization in Process Units Siting (RIDIMPUS), is presented with which hazardous units can be sited in a chemical process facility in a manner that the risk of accidents involving the hazardous units as also the cost of spacing the units is minimized. To achieve this, safety and cost factors were modeled using various governing parameters and then expressions were designed to integrate the safety and the economic concerns to form model equations, inequalities and disjunctions. The resulting nonlinear programming model is solvable by using algorithms and solvers on any common desktop computer, thereby providing an optimal and prompt solution.     

Effect of lysine incorporation,annealing and heat moisture treatment alone and in combination on the physico-chemical,retrogradation, rheological properties and in vitro digestibility of kithul (Caryota urens L.) starch

Physico-chemical, retrogradation, rheological properties and in vitro digestibility of lysine incorporated kithul starch modified by annealing, heat moisture treatment and its combinations were studied. LS-AHMT (annealed-heat moisture treated lysine incorporated kithul starch) exhibited lowest amylose leaching. LS-AHMT showed significantly (P ≤ 0.05) higher relative crystallinity. LS-ANS (annealed lysine incorporated kithul starch), LS-HMT (heat moisture treated lysine incorporated kithul starch) and LS-AHMT formed more weak gel by the effect of annealing, heat moisture treatment and its combination. LS-AHMT showed lowest pasting viscosities, G′ and G″ values among the modified kithul starch, which indicates its lower retrogradation properties. In vitro digestibility of kithul starch decreased after modifications and LS-ANS, LS-HMT and LS-AHMT showed significantly higher resistant starch content. The current study showed that annealing, heat moisture treatment and its combination on NS-LS (lysine incorporated kithul starch) effectively modified kithul starch properties.     

Multilayer Partially Homomorphic Encryption Text Steganography (MLPHE-TS): A Zero Steganography Approach

Wireless Personal Communications - This paper presents a Multilayer Partially Homomorphic Encryption Text Steganography, an invisible approach for covert communication. Existing text-based schemes...     

Solar cells sensitised by push–pull azo dyes: dependence of photovoltaic performance on electronic structure,geometry and conformation of the sensitizer

Novel Azo dyes possessing varying conjugation lengths and different extents of electron cloud delocalisation were synthesised and characterised and explored as sensitizers for dye-sensitised solar cells (DSSC). The envisaged azo dyes comprising of electron withdrawing and electron-donating moieties which are linked through conjugation bridges of varying lengths facilitated the prevalence of push–pull mechanism in the molecules. Optimisation of the geometry were performed for the synthesised compounds using B3LYP/ 6-31?+?G (d,p) level of density functional theory and their computed optical absorption and band gaps were validated with experimental results. The dyes exhibited molar extinction coefficients in the range of 3.2?×?10⁴ to 4.2?×?10⁴?mol^?1?Lcm^?1. The highest occupied molecular orbital (HOMO) was located between ?5.53 and ?5.03?eV for the various sensitizers synthesised and their lowest unoccupied molecular orbital (LUMO) was located between ?2.86 and ?3.08?eV. HOMO–LUMO gaps were in the range of 2.02–2.67?eV. Fill factor of the cells varied from 28% to 32% and the power conversion efficiencies ranged from 0.4% to 2.7%. This is the first time reporting of a systematic investigation, correlating the influence of nature and position of substituent, extending of conjugation and geometry of sensitizers on the photo physical properties of the sensitizers and the photovoltaic performance of corresponding DSSC.

Highlights

• The article focuses on push–pull azo dyes and were explored as promising candidate sensitizers for low cost dye-sensitised solar cells (DSSC).

• The effect of chemical structure, extend of conjugation and geometry of the sensitizer on the photo physical properties of the sensitizers and the photovoltaic performance of DSSC were analysed.

     

Structural Characteristics and Electrical Conductivity of Spark Plasma Sintered Ytterbia Co‐doped Scandia Stabilized Zirconia

The effect of replacing Sc₂O₃ with Yb₂O₃ on the structural and electrical properties of xYb₂O₃–(12–x)Sc₂O₃–88ZrO₂ has been investigated. Spark plasma sintering technique is employed to fabricate dense bulk samples from the nano‐sized powders. X‐ray diffraction and transmission electron microscopy performed on pellets indicate the existence of cubic and rhombohedral phases in 12ScSZ, and a single cubic phase in all the co‐doped compositions. However, Raman spectroscopic studies suggest the presence of a metastable tetragonal t″‐phase along with rhombohedral phases in 12ScSZ, whereas a single cubic phase in all the co‐doped compositions. Significant enhancement in the conductivity of grain and grain boundary is observed on replacing Sc₂O₃ with Yb₂O₃. In the intermediate temperature range, 1Yb11ScSZ exhibits the highest, while 12ScSZ shows the lowest conductivity values, which is attributed to corresponding phases present in that range. Through co‐doping with >1 mol% Yb₂O₃ leads to conductivity decrease, but the value remains higher than that of 12ScSZ. A sharp conductivity change is observed in 12ScSZ and 1Yb11ScSZ samples, which is attributed to partial phase transition as well to the formation of cation‐vacancy complexes. In this work, the beneficial effect of Yb₂O₃ co‐doping in 12ScSZ on the phase and conductivity has been highlighted.