油滴釉制作工艺的研究

在研制氧化气氛烧制油滴黑釉器的基础上 ,探讨了影响油滴釉形成的工艺因素。通过一系列试验 ,进一步验证了油滴釉在结晶过程中主要发生了液液分相 ;釉料的化学组成是油滴晶斑形成的先决条件 ;釉层厚度、烧成制度等是决定釉面效果的重要因素 ;油滴晶斑的呈色不仅与烧成气氛有关 ,还与着色氧化物的引入有关。     

Synthesis and characterization of poly(ϵ‐caprolactone)‐b‐poly(ethylene glycol) block copolymers prepared by a salicylaldimine‐aluminum complex

A series of poly(?‐caprolactone)‐b‐poly(ethylene glycol) (PCL‐b‐PEG) block copolymers with different molecular weights were synthesized with a salicylaldimine‐aluminum complex in the presence of monomethoxy poly(ethylene glycol). The block copolymers were characterized by ¹H NMR, GPC, WAXD, and DSC. The ¹H NMR and GPC results verify the block structure and narrow molecular weight distribution of the block copolymers. WAXD and DSC results show that crystallization behavior of the block copolymers varies with the composition. When the PCL block is extremely short, only the PEG block is crystallizable. With further increase in the length of the PCL block, both blocks can crystallize. The PCL crystallizes prior to the PEG block and has a stronger suppression effect on crystallization of the PEG block, while the PEG block only exerts a relatively weak adverse effect on crystallization of the PCL block. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Catalytic activities and properties of mesoporous sulfated Al2O3–ZrO2

Mesoporous sulfated Al₂O₃–ZrO₂ (MSAZ) catalysts with large surface areas and pore volumes after calcination at high temperature (650 °C) and with higher Al₂O₃ content than 20wt% were successfully prepared from a template of block copolymer (P84). The MSAZ catalysts were characterized by X-ray diffraction (XRD), N₂ adsorption, transmission electron microscopy (TEM), ²⁷Al magic-angle spinning nuclear magnetic resonance (MAS NMR), thermogravimetric analysis (TG–DTG), temperature-programmed desorption of ammonia (NH₃-TPD) and infrared spectra (IR) of adsorbed pyridine. It is shown that the resulting mesostructured sulfated Al₂O₃–ZrO₂ samples have a well-developed textural mesoporosity. The number of acid sites present on MSAZ catalysts is higher than that on conventional sulfated zirconia, and the former catalysts are more active than the latter one for various acid-catalyzed reactions.     

Algorithms for spatial collocation pattern mining in a limited memory environment: a summary of results

Rapid growth of spatial datasets requires methods to find (semi-)automatically spatial knowledge from these sets. Spatial collocation patterns represent subsets of spatial features whose instances are frequently located together in a spatial neighborhood. In recent years, efficient methods for collocation discovery have been developed, however, none of them assume limited size of the operational memory or limited access to memory with short access times. Such restrictions are especially important in the context of the large size of the data structures required for efficient identification of collocation instances. In this work we present and compare three algorithms for collocation pattern mining in a limited memory environment. The first algorithm is based on the well-known joinless method introduced by Shekhar and Yoo. The second and third algorithms are inspired by a tree structure (iCPI-tree) presented by Wang et al. In our experimental evaluation, we have compared the efficiency of the algorithms, both on synthetic and real world datasets.     

溶胶-凝胶法制备多孔陶瓷的研究进展

本文综合论述了溶胶-凝胶法制备多孔陶瓷的工艺研究进展以及影响溶胶-凝胶法制备多孔陶瓷的主要因素，并讨论了今后溶胶-凝胶法制备多孔陶瓷的主要研究问题及其发展前景。     

聚酯瓶的生态性能分析及设计

利用材料的生命周期评估法对聚酯瓶的生态性能和设计要点进行分析。瓶级聚酯的巨大市场 ,优良的物理化学性能 ,简便安全的加工使用特点 ,使聚酯瓶成为一次包装革命。其可持续发展的关键是回收利用。目前回收最多的国家为 3 4% ,60 %以上回收物用于生产纤维。应针对各种回收方法 ,建立稳定的消费 回收 再循环加工的网络。     

木塑复合材料的研究开发进展

近年来，木塑材料以其优越的性能越来越得到广泛的应用，本文对木塑材料在国内外研究现状，木塑材料的种类和加工助剂、加工条件、机械等方面进行了简单的介绍。     

Ionic liquids as electrolytes

Salts having a low melting point are liquid at room temperature, or even below, and form a new class of liquids usually called room temperature ionic liquids (RTIL). Information about RTILs can be found in the literature with such key words as: room temperature molten salt, low-temperature molten salt, ambient-temperature molten salt, liquid organic salt or simply ionic liquid. Their physicochemical properties are the same as high temperature ionic liquids, but the practical aspects of their maintenance or handling are different enough to merit a distinction. The class of ionic liquids, based on tetraalkylammonium cation and chloroaluminate anion, has been extensively studied since late 1970s of the XX century, following the works of Osteryoung. Systematic research on the application of chloroaluminate ionic liquids as solvents was performed in 1980s. However, ionic liquids based on aluminium halides are moisture sensitive. During the last decade an increasing number of new ionic liquids have been prepared and used as solvents. The general aim of this paper was to review the physical and chemical properties of RTILs from the point of view of their possible application as electrolytes in electrochemical processes and devices. The following points are discussed: melting and freezing, conductivity, viscosity, temperature dependence of conductivity, transport and transference numbers, electrochemical stability, possible application in aluminium electroplating, lithium batteries and in electrochemical capacitors.