Numerical Technique for Resolving the Dual Phase Lag Heat Conduction in Thin Film Metal

Abstract

In this article, a three-time level finite difference scheme is used to resolve the dual phase lag’s (DPL) heat conduction in a micro scale gold film subjected to spontaneous temperature boundary conditions without knowing the heat flux. Finite difference analog of DPL equation on applying to the intermediate grid points of the computational domain results into a system of linear, algebraic equations which can be solved using Thomas’ algorithm to finally obtain the transient temperature solution distributions in the film. The solution predicted by the DPL model is compared with that obtained by the single-phase Cattaneo–Vernotte’s model. Further, the way in which non-Fourier’s temperature distributions affected by the diffusion due to the increase in Heat Conduction Model numbers agree with the predecessor’s published results. The results by both the models revealed a finite thermal wave speed in the film contrasting the infinite speed of heat propagation as stated by the classical Fourier’s thermal model. Low spatial step and higher order finite difference schemes are recommended for better accurate numerical results of the non-Fourier’s temperature distributions occurring in the very short transient period between the instants of the suddenly applied spatial temperature gradient and the reaching of the steady state conditions.     

Synthesis,characterization, and electrochemical performance of the ternary layered composite (1-x-y) LiNi1/3Co1/3Mn1/3O2·xLi2MnO3·yLiCoO2

Composite ceramic cathodes represented by the formula (1-x-y) LiNi_1/3Co_1/3Mn_1/3O₂·xLi₂MnO₃·yLiCoO₂ were studied. A ternary compositional diagram was built with these ceramic materials as end-members, and selected points were chosen to represent the compositional space. Synthesized ceramic composite materials were investigated as to whether integration of structurally compatible units leads to improved electrochemical performance. Detailed structural (X-ray diffraction – XRD), elemental (X-ray photoelectron spectroscopy-XPS), microstructure (Scanning electron microscopy – SEM), and electrochemical (galvanostatic testing of half-cells) studies were performed and are presented. Within eight samples studied three compositions are found to exhibit first discharge capacity of around 230 mAh/g.     

A Study of Non-Recessed Hybrid Flexible Journal Bearing With Different Restrictors

For bearings operating under heavy loads, the elastic deformation of bearing surface induced by fluid film pressures can no longer be neglected as it is comparable to the order of magnitude of fluid film thickness. In the present work a theoretical study describing comparative performance of non-recessed hybrid journal bearing using different flow control devices has been carried out by considering bearing shell flexibility into the analysis. The relevant governing equations have been solved using finite element method. The comparative performance of non-recessed hybrid journal bearings of two separate configurations have been studied for various values of bearing flexibility parameter (([Cbar]_d)). The results have been presented for hole-entry type journal bearings compensated by capillary, orifice and constant flow valve restrictors and for a slot-entry type journal bearing, for the same set of values of operating and geometric parameters. The computed results indicates that in order to get an improved performance of non-recessed journal bearing, a proper selection of bearing flexibility parameter (([Cbar]_d)) along with type of flow control device (i.e., capillary, orifice, constant flow valve, slot etc.) and type of bearing configuration (symmetric/asymmetric) are essential.     

MALEO: Modular Assembly in Low Earth Orbit: Alternate Strategy for Lunar Base Development

Modular assembly in low Earth orbit (MALEO) is a new strategy for building an initial operational‐capability lunar habitation base, the main purpose of which is to safely initiate and sustain early lunar base buildup operations. In this strategy the lunar base components are brought up to low Earth orbit (LEO) by the Space Transportation System (STS), and assembled there to form the complete lunar base. Specially designed propulsion systems are then used to transport the MALEO lunar base, complete and intact, all the way to the moon. Upon touchdown on the lunar surface, the MALEO lunar habitation base is operational. The strategy is unlike conventional concepts, which have suggested that the components of the lunar base be launched separately from the Earth and landed one at a time on the moon, where they are assembled by robots and astronauts in extravehicular activity (EVA). The architectural drivers for the MALEO concept are, first, the need to provide an assured safe haven and comfortable working environment for the astronaut crew as safely and as quickly as possible, with the minimum initially risky EVA, and secondly, the maximum exploitation of the evolutionary benefits derived from the assembly and operation of space station Freedom (SSF‐1). Commonality and inheritability from the space station assembly experience is expected to have an advantageous impact on both the space station program as well as the MALEO lunar base.     

Effect of Iron Ore Pellet Size on its Properties and Microstructure

The properties of the pellets and their microstructure mainly depend on the raw material mix proportion, raw material chemical composition and the physicochemical conditions like the temperature and oxygen partial pressure within the induration machine. The pelletising plant products are in the size range of 8 to 16 mm. With increasing pellet size, the sintering intensity, thermo‐chemical conditions and formation of different phases vary across its cross section. The time required for varies reactions within the pellet is directly proportional to the pellet size. Because of differences in pellet size, the reduction and oxidation process takes place under different conditions resulting in different phases and microstructures. In this work, detailed studies were carried out on pellets of different size (8 to 16 mm) produced from a 4.2 Mtpa pellet plant for their physical, metallurgical and microstructural properties. It was observed that the pellets in the size range of +8 to ‐12 mm showed good strength and lower RDI. It was observed that the amount of hematite, magnetite, porosity, pore density, pore size and slag phase play a significant role on pellet strength and RDI.     

Stretchable and Tunable Microtectonic ZnO‐Based Sensors and Photonics

The concept of realizing electronic applications on elastically stretchable “skins” that conform to irregularly shaped surfaces is revolutionizing fundamental research into mechanics and materials that can enable high performance stretchable devices. The ability to operate electronic devices under various mechanically stressed states can provide a set of unique functionalities that are beyond the capabilities of conventional rigid electronics. Here, a distinctive microtectonic effect enabled oxygen‐deficient, nanopatterned zinc oxide (ZnO) thin films on an elastomeric substrate are introduced to realize large area, stretchable, transparent, and ultraportable sensors. The unique surface structures are exploited to create stretchable gas and ultraviolet light sensors, where the functional oxide itself is stretchable, both of which outperform their rigid counterparts under room temperature conditions. Nanoscale ZnO features are embedded in an elastomeric matrix function as tunable diffraction gratings, capable of sensing displacements with nanometre accuracy. These devices and the microtectonic oxide thin film approach show promise in enabling functional, transparent, and wearable electronics.     

Enhanced intestinal absorption and bioavailability of raloxifene hydrochloride via lyophilized solid lipid nanoparticles

The current oral therapy with raloxifene hydrochloride (RXH) is less effective due to its poor bioavailability (only 2%). Henceforth, an attempt was made to investigate the utility of triglyceride (trimyristin, tripalmitin and tristearin) based solid lipid nanoparticles (SLNs) for improved oral delivery of RXH. The SLN formulations prepared were evaluated for particle size, zeta potential and % entrapment and the optimized formulation was lyophilized. Solid state characterization studies unravel the transformation of RXH to amorphous or molecular state from the native crystalline form. Further the in situ perfusion studies carried out in rat intestine reveal the potential of SLN for enhanced permeation of raloxifene HCl across gastrointestinal barrier. To derive the conclusions, in vivo pharmacokinetic study was conducted in rats to assess the bioavailability of RXH from SLN formulation compared to drug suspension. Overall a twofold increase in bioavailability with SLN formulations confer their potential for improved oral delivery of RXH.     

Elemental Analogues of Graphene: Silicene,Germanene, Stanene,and Phosphorene

The fascinating electronic and optoelectronic properties of free‐standing graphene has led to the exploration of alternative two‐dimensional materials that can be easily integrated with current generation of electronic technologies. In contrast to 2D oxide and dichalcogenides, elemental 2D analogues of graphene, which include monolayer silicon (silicene), are fast emerging as promising alternatives, with predictions of high degree of integration with existing technologies. This article reviews this emerging class of 2D elemental materials – silicene, germanene, stanene, and phosphorene – with emphasis on fundamental properties and synthesis techniques. The need for further investigations to establish controlled synthesis techniques and the viability of such elemental 2D materials is highlighted. Future prospects harnessing the ability to manipulate the electronic structure of these materials for nano‐ and opto‐electronic applications are identified.