Response of a proton exchange membrane fuel cell to a sinusoidal current load

The load-following capability of a proton exchange membrane fuel cell was studied by measuring the cell voltage response to a sinusoidal current load with large amplitude and varying frequency. A mathematical model was developed, incorporating mass transport and capacitive effects as well as the membrane resistance. The model was capable of separating the faradaic and capacitive currents and predicting the observed hysteresis. At frequencies of the sinusoidal current load below 1 Hz, no appreciable hysteresis in the polarisation curve was observed. When increasing the frequency above 1 Hz, a hysteresis appeared at current densities below 0.2 A cm^?2. The model related this hysteresis to capacitive effects. When using air as the cathode feed, hysteresis in the current density range 0.5 A cm^?2 and higher appeared above 1 Hz compared to 100 Hz for pure oxygen. The model revealed that hysteresis observed in this current density range was caused by oxygen transport limitations.     

Electroconductive paper prepared by coating with blends of poly(3,4‐ethylenedioxythiophene)/poly(4‐styrenesulfonate) and organic solvents

Electroconductive papers were produced by coating commercial base papers with blends of poly(3,4‐ethylenedioxythiophene)/poly(4‐styrenesulfonate) (PEDOT:PSS) and organic solvents. The bulk conductivities of the coated papers were measured using a four‐probe technique. One‐sided and two‐sided coating gave comparable conductivity levels. The presence of sorbitol and isopropanol in the PEDOT:PSS blends did not enhance the bulk conductivity of the coated paper, and with increasing concentrations of these solvents, the conductivity decreased due to dilution of the conducting component. Samples coated with PEDOT:PSS blends containing N‐methylpyrrolidone (NMP) or dimethyl sulfoxide (DMSO) exhibited a higher conductivity than those coated with pure PEDOT:PSS because of their plasticizing effect and conformational changes of PEDOT molecules indicated by the red shift and disappearance of the shoulder peak at about 1442 cm^?1 in the Raman spectra of the coated samples. EDS imaging showed that PEDOT:PSS is distributed throughout the thickness direction of the paper. Contact angle measurements were made to monitor the hydrophilicity of the paper surface and total sulfur analysis was used to determine the amount of PEDOT:PSS deposited onto the paper. The tensile strength of all the paper samples increased slightly after treatment. Thus, it is demonstrated that enhanced bulk conductivity in the order of 10^?3 S/cm can be achieved by using organic conductive materials and surface treatment techniques. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Molecular electronics: insight from first-principles transport simulations

Conduction properties of nanoscale contacts can be studied using first-principles simulations. Such calculations give insight into details behind the conductance that is not readily available in experiments. For example, we may learn how the bonding conditions of a molecule to the electrodes affect the electronic transport. Here we describe key computational ingredients and discuss these in relation to simulations for scanning tunneling microscopy (STM) experiments with C60 molecules where the experimental geometry is well characterized. We then show how molecular dynamics simulations may be combined with transport calculations to study more irregular situations, such as the evolution of a nanoscale contact with the mechanically controllable break-junction technique. Finally we discuss calculations of inelastic electron tunnelling spectroscopy as a characterization technique that reveals information about the atomic arrangement and transport channels.     

Experimental investigation of an industrial scale black liquor gasifier. 1. The effect of reactor operation parameters on product gas composition

A novel technology to mitigate the climate changes and improve energy security is Pressurized Entrained flow High Temperature Black Liquor Gasification (PEHT-BLG) in combination with an efficient fuel synthesis using the resulting syngas. In order to optimise the technology for use in a pulp and paper mill based biorefinery, it is of great importance to understand how the operational parameters of the gasifier affect the product gas composition. The present paper is based on experiments where gas samples were withdrawn from the hot part of a 3 MW entrained flow pressurized black liquor gasifier of semi industrial scale using a high temperature gas sampling system. Specifically, the influence of process conditions on product gas composition (CO₂, CO, H₂, CH₄, H₂S, and COS) were examined by systematically varying the operational parameters: system pressure, oxygen to black liquor equivalence ratio, black liquor flow rate to pressure ratio and black liquor pre-heat temperature. Due to the harsh environment inside the gasification reactor, gas sampling is a challenging task. However, for the purpose of the current study, a specially designed high temperature gas sampling system was successfully developed and used. The results, obtained from two separate experimental campaigns, show that all of the investigated operational parameters have a significant influence on the product gas composition and present valuable information about to the process characteristics.     

Influence of glucosinolates and a tentative high-molecular detrimental factor on the nutritional value of rapeseed meal

Feeding experiments with mice suggest that high-molecular weight compounds in rapeseed meal without direct relationship to glucosinolates have a detrimental effect on the nutritional value of the meal. This effect is precluded by treatment with ethanol or upon heating. Ethanol extraction improves the nutritional value of the residue as a result of the removal of non-essential nitrogenous compounds. The nutritional value of the seed meal of the cultivar Bronowski was superior to that of the high-glucosinolate meal. A freeze-dried ethanol extract of the high-glucosinolate cultivar Sv Rigo was toxic to mice, especially when fed in combination with myrosinase, in contrast to ethanol extract from the low-glucosinolate cultivar Bronowski. A decrease of the glucosinolate content to a level below that of Bronowski did not effect the growth response of mice.     

Extended studies of degradation mechanisms in the refractory lining of a rotary kiln for iron ore pellet production

Changes, over a period of 8 years, in the chemical composition and morphology of deposit and lining materials in a production rotary kiln for iron ore pellet manufacture are described. The following have been studied: two types of refractory brick used as lining material; deposited chunk materials from the lining; the interaction zones between deposits and linings. Morphological changes at the deposit/lining interface, and the active chemical reactions, are established. Larger hematite grains in the deposit material (5–50 μm) primarily remain at the original deposit/lining interface. The remainder penetrates fissures, voids and brick joints, forms a laminar structure with corundum from the bricks, and migrates in grains in the lining material. Potassium penetrates more deeply into the bricks than hematite, resulting in the formation of kalsilite, leucite and potassium β-alumina, which contribute to degradation of the lining.     

Effect of Silver Loading on the Lean NOx Reduction with Methanol Over Ag–Al2O3

The influence of silver loading on the lean NO_x reduction activity using methanol as reductant has been studied for alumina supported silver catalysts. In general, increasing the silver loading (0–3 wt%), in Ag–Al₂O₃, shifts or extends the activity window, for lean NO_x reduction towards lower temperatures. In particular Ag–Al₂O₃ with 3 wt% silver is active for NO_x reduction under methanol-SCR conditions in a broad temperature interval (200–500 °C), with high activity in the low temperature range (maximum around 300 °C) typical for exhaust gases from diesel and other lean burn engines. Furthermore, increasing the C/N molar ratio enhances the reduction of NO_x. However, too high C/N ratios results in poor selectivity to N₂.     

STEAM DRYLNG OF WOOD FUELS

ABSTRACT

The objective of this work is to investigate some of the important aspects in the design of a steam band dryer for wood fuels. For this purpose the drying of the material in a bench-scale fixed bed dryer has been studied.

Drying times and thermal efficiencies for experiments conducted under different conditions are compared. The investigated materials are soft-and hardwood chips and softwood bark.

The thermal efficiency, the part of the sensible heat which is used during one passage of the steam through the bed, increases with increasing mass load (mass of dry matter per unit area) and with decreasing steam mass flux. At a mass load of 30 kg/m the thermal efficiency is about 0.85 even at steam mass fluxes as high as 0.6 kg/m² s (1.2 m/s). The thermal efficiency proves to be almost independent of pressure and temperature of the steam.

Due to the very inhomogeneous materials the steam mass flow distribution was uneven. This causes a decreased thermal efficiency. When bark     

Multivariable data analysis of a cold rolling control system to minimise defects

This paper focuses on the application of principal component analysis (PCA) to thoroughly analyse and interpret multidimensional data from a cold rolling process. The analysis includes the effects of variables on the final properties of strips in a cold rolling mill. Unscrambler software was used to analyse and identify hidden variables. Variable correlations were also used to derive correlations between the control parameters. The results of this research will be used to improve the selection of material in order to reduce the occurrence of defects in the cold rolling process and to improve the adjustment of the set points that are performed in every pass or section of the cold rolling process. The hot rolled strips that enter the cold rolling mill are made of different materials and are produced by different strip manufacturers. Some strips break during the thickness reduction process in the cold rolling mill. This paper focuses on two possible causes of breakage: non-uniform strip material properties and failures in the rolling mill process. Two types of rolled strips (those that break and those that do not break) were compared to identify causes of breakage. The results indicate that breakages are caused by material or process failures. PCA was applied to the dataset in order to identify and analyse the relationships between the variables in the process. This information was used to interpret and diagnose the process behaviour. Swarm analysis and relating observations to process behaviour were able to distinguish between different start-up conditions, and between desirable and undesirable process conditions.     

Ambient oxygen ingress rate method—an alternative method to Ox‐Tran for measuring oxygen transmission rate of whole packages

The ambient oxygen ingress rate method (AOIR) is an alternative method to Ox‐Tran for measuring the oxygen transmission rates (OTR) of whole packages. The objective of the present work was (a) to compare OTR values obtained by the two methods, and (b) to evaluate the use of the AOIR method for measuring OTR at realistic food storage temperatures and humidity levels. The AOIR method gave equal OTR values compared to the Ox‐Tran method for the five different types of whole packages used in the experiment, with OTR values in the range 0.06–1.48 ml O₂/day. The repeatability of the AOIR method measured on an HDPE bottle was ±2.6% of the measured value in this experiment. This is slightly higher than the general specifications of the Ox‐Tran method (1% of reading for packages). However, the AOIR method can be considered to be a reliable, precise and cheap alternative method to the Ox‐Tran method for measuring OTR of whole packages. The capacity of the method is also high. The AOIR method showed satisfactory results when comparing OTR for packages tested under realistic food storage conditions covering 23°C/50% relative humidity (RH) and at 4°C/60% RH on the outside, combined with water (100% RH) or dry air inside the packages. Copyright © 2000 John Wiley & Sons, Ltd.