Studies on synthesis,characterization, and metal adsorption of mimosa and valonia tannin resins

A few thermosetting wood adhesive tannin resin system from formaldehyde reaction with both condensed and hydrolysable tannin has been developed. Polymerization of formaldehyde with mimosa tannin and valonia tannin was carried out at optimal conditions obtained from literature to establish the adhesive resin formulation. Formed reaction products were characterized by FTIR spectroscopy. The possible adsorption mechanisms for the adsorption of various metal ions onto tannin‐formaldehyde resins were proposed. Also, thermal analysis were studied and discussed by differential scanning calorimetry and thermogravimetry. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 786–797, 2006     

Substrate Analysis on the Design of Wide-Band Antenna for Sub-6 GHz 5G Communication

Wireless Personal Communications - A compact triple band antenna with stacked T-shaped strips inside a rectangular ring monopole has been proposed. This novel structure with a slot in the defected...     

Post-fire behavior of CFRP retrofitted thin-walled steel tanks

Thin-walled shell structures are characterized by a lightweight structural form with high strength. This structure has many applications in various engineering fields and is considered to be a basic tool in the modern industry. This study investigates the effect of CFRP on tanks after post-fire in order to examine the buckling and post-buckling of the cylindrical tanks. Herein, post-fire was introduced at different temperatures (150°C-600°C). Ten laboratory specimens in two groups with verified temperatures, under external pressure, are examined. The models were designed to demonstrate how repairing steel tanks, which are damaged by fire, by using carbon-fiber-reinforced polymer can recover lost capacity. The results of testing under different theories and codes were compared. This study shows that the initial buckling load of the temperature group increased by 30.82% to 57.09% compared to the temperature without-CFRP group. The overall buckling load of the temperature group increased by 37.01% to 67.74% compared to the temperature without-CFRP group. The collapse load of the temperature group increased by 27.04% to 52.64% compared to the temperature without-CFRP group. And using carbon-fiber-reinforced polymer on models, which are damaged by fire, can be an improvement behavior for the buckling and post-buckling specimen tests.     

Magnetically Driven Silver‐Coated Nanocoils for Efficient Bacterial Contact Killing

The increasing threat of multidrug‐resistant bacterial strains against conventional antibiotic therapies represents a significant worldwide health risk and intensifies the need for novel antibacterial treatments. In this work, an effective strategy to target and kill bacteria using silver‐coated magnetic nanocoils is reported. The coil palladium (Pd) nanostructures are obtained by electrodeposition and selective dealloying, and subsequently coated with nickel (Ni) and silver (Ag) for magnetic manipulation and antibacterial properties, respectively. The efficiency of the nanocoils is tested in the treatment of Gram‐negative Escherichia coli (E. coli) and Gram‐positive methicillin‐resistant Staphylococcus aureus (S. aureus), both of which represent the leading multidrug‐resistant bacterial pathogens. The nanocoils show highly effective bacterial killing activity at low concentrations and in relatively short durations of treatment time. Three different investigation techniques, LIVE/DEAD assay, colony‐forming unit counting, and scanning electron microscope, reveal that the antibacterial activity is a result of bacterial membrane damage caused by direct contact with the nanocoil. The low cytotoxicity toward fibroblast cells along with the capability of precise magnetic locomotion makes the proposed nanocoil an ideal candidate to combat multidrug‐resistant bacteria in the field of biomedical and environmental applications.     

Temperature dependent electrical conductivity of p-doped poly(3,4-ethylenedioxythiophene) and poly(3-alkylthiophene)s

Summary Temperature dependent electrical conductivity of substituted polythiophenes (poly(3,4-ethylenedioxythiophene) PEDOTh and head-to-tail type poly(3-alkylthiophene) HT-P3RTh) has been measured. The electrical conductivity (σ) of p-doped PEDOTh and HT-P3RTh obeys equations of a type, ln σ= ln σ_o− (T_o/T)^0.25, with the T_o value of about 10⁵–10⁷ K. Received: 21 December 1998/Revised version: 8 February 1999/Accepted: 15 February 1999     

The effect of aggregation on the nonlinear optical absorption performance of indium and gallium phthalocyanines in a solution and co-polymer host

The nonlinear optical properties (NLO) of Pcs can be modified by substituting different metal atoms into the ring or altering peripheral and axial functionalities. In this study, nonlinear optical absorption properties of tetra-substituted gallium and indium phthalocyanine complexes both in solution and polymeric film have been investigated by open aperture Z-scan measurements with nanosecond pulses at 532 nm. All investigated compounds exhibited reverse saturable absorption for both solution and film experiments. The investigated compounds in the solution showed better nonlinear optical absorption properties than polymeric films. The observed nonlinear optical absorption differences depending on the aggregation are discussed using the ultrafast dynamics and decay processes of excited states found from femtosecond pump-probe spectroscopy with white light continuum experiments.     

Ball-Mill Grinding Kinetics of Cement Clinker Comminuted in the High-Pressure Roll Mill

The use of high-pressure grinding rolls (HPGR) prior to ball mills has become a common practice in cement clinker grinding due to significant energy savings in comparison to ball milling alone. The energy savings has been attributed to higher energy efficiency of HPGR at low reduction ratios, smaller particle top sizes in the ball mill feed, and the weakening of particles resulting from compression of particle bed by HPGR. This study attempts to show how the weakening effect changes the kinetic breakage parameters of the HPGR-treated clinker. For this purpose, batch ball mill experiments were conducted with three narrow-size fractions (?3.35 + 2.36, ?1.70 + 1.18, and ?0.85 + 0.60 mm) of the feed and product samples of an industrial HPGR, and the breakage rate and breakage distribution parameters of the samples were compared. The results show that the weakening effect leads to nonlinear breakage rates for all sizes, coupled with abnormal breakage at the two coarsest sizes. The weakening effect leads to increased breakage rates of the HPGR product relative to particles of the HPGR feed. The increased breakage rates are accompanied by coarser progeny distributions for the two coarsest size ranges relative to that of the HPGR feed. The progeny distribution of the finest size of the HPGR product, however, is finer than that of the HPGR feed. Ball milling of size-distributed feeds prepared from the HPGR product and feed samples for the same grinding time produces self-similar size distributions when the size is normalized with respect to the median size.