气动锚杆钻机常见故障浅析

通过对气动锚杆钻机原理图的分析,绘制出路线图,并利用路线图对锚杆钻机常见故障进行了分析     

浸锑对石墨材料摩擦磨损性能的影响

碳石墨制品具有良好的自润滑性能,但是作为高温耐磨密封材料,机械强度较低,耐磨和抗氧化性能较差,应用范围受到很大的限制。向石墨制品中浸入金属锑,可以有效地提高材料的耐磨性能,使之成为一种前景非常好的特种工程材料。     

广东某闪锌矿选矿过程中铟的行为走向探讨

分析了广东某闪锌矿除富含Zn、S外，还富含稀散金属铟（In）。通过对不同选矿工艺流程及药剂制度下铟的跟踪分析，发现在不同的选别条件下，铟随着锌精矿而富集的行为走向。     

基于复数域的自适应递推子空间辨识算法

针对工业系统广泛存在的特征值分布于复数域的特性,提出一种基于复数域的自适应递推子空间辨识算法。该算法首先设计了变遗忘因子机制下Hankel矩阵的无偏更新形式;其次利用正交化子空间跟踪算法实现广义能观测矩阵的递推更新;最后,针对工业系统参数矩阵特征值普遍分布于复数域的特点,利用特征值空间的欧氏距离信息实现变遗忘因子的自适应更新。数值仿真结果表明,该自适应算法对时变参数的跟踪速度快、跟踪精度高。     

Highly dispersed and confined Ni/MMO catalyst synthesized in a rotating packed bed for hydrogenation of maleic anhydride

Catalytic hydrogenation of maleic anhydride (MA) into succinic anhydride (SA) is one of the most important transformations in synthetic organic chemistry. Herein, we firstly synthesized well-dispersed nickel particles confined by mixed metal oxides (Ni/MMO) derived from in situ transformation of Ni-Al hydrotalcite in a rotating packed bed (RPB) to catalyze this process. A series of Ni/MMO catalysts (63 wt%–89 wt% Ni) were effectively fabricated and the structure–activity relationship was established. Results showed that a Ni/MMO catalyst (82 wt% Ni) with substantial surface defect sites and the highest Ni surface area among the prepared Ni/MMO catalysts, demonstrates the highest activity with ~100% MA conversion and ~100% selectivity to SA under 25°C within 77 min. This is, to our knowledge, the highest conversion and selectivity under room temperature to date. Moreover, the Ni/MMO catalyst prepared by RPB has higher specific surface area and Ni surface area, therefore possessing a higher hydrogenation rate compared to that by stirred tank reactor (1.69 vs. 1.36, 10⁻³·mol_MA/g_cat/min). These results will provide an attractive option of the catalysts for MA hydrogenation, and a novel strategy for synthesizing nickel catalyst derived from Ni-Al hydrotalcite.     

Pyrazine-interior-embodied MOF-74 for selective CO2 adsorption

A series of pyrazine-interior-embodied metal–organic framework-74 composites (py-MOF-74) were successfully synthesized by a post-synthetic vapor modification method. Here, pyrazine molecules occupy the cavity to block the wide pores of MOF-74, which accentuates the difference in adsorption of a pair of gases on MOFs and consequently reinforces the adsorption selectivity. Different from the “physical confinement” of occupants, the pyrazine molecule with dual “para-nitrogen” atoms donates one N atom to bond with the open metal ion of MOF-74 for stability and the other N atom for potential CO₂ trapping. Typically, py-MOF-74c with the highest pyrazine insertion ratio displays selectivity greatly superior to that of MOF-74 in equimolar CO₂/CH₄ (598 vs. 35) and in simulated CO₂/N₂ flue gas (471 vs. 49). Py-MOF-74 entities are long-lived adsorbents, and their CO₂ capacity can be maintained even after storage for 1 year in air. Py-MOF-74 also showed a sharp molecular sieve property in fixed-bed cycle adsorption tests, which implies its great potential in real applications.     

可生物降解PBAT/PLA/生物质垃圾袋的制备和表征

将聚己二酸/对苯二甲酸丁二酯（PBAT）和聚乳酸（PLA）进行共混,然后添加竹粉、木质素和秸秆粉,利用混合熔融造粒、挤出吹膜工艺制备了PBAT/PLA/生物质粉（BP）（质量比74.26/4.95/19.80）复合垃圾袋,并采用扫描电子显微（SEM）、红外光谱仪（FTIR）、X射线衍射测试（XRD）、热重分析仪（TG）及差示扫描量热仪（DSC）等对垃圾袋的微观形貌、组成、耐热性能、拉伸性能及抗漏性能进行了测试和表征,对其实用性进行了评估。结果表明,3种BP在PBAT/PLA基体中分散性较好,对薄膜结构和热性能几乎没有影响;添加竹粉和木质素材料的垃圾袋相比于添加秸秆粉的垃圾袋有明显的强度优势,强度提高了40 %以上。本研究对于降低PBAT/PLA垃圾袋的生产成本、促进生物降解材料的产业化应用具有重要借鉴意义。     

Fabrication of effective mesoporous silica materials for emergency hemostasis application

Silicon - Uncontrolled bleeding is an important cause of traumatic death in wartime and peacetime. Despite the significant advances in hemostatic research, it is still challenging to develop safer...     

稀土Y与喷射沉积技术对铝铁合金组织和性能的影响

普通凝固条件下得到的铸造Al-Fe合金中存在粗大的针状或片状初生富铁相,严重割裂基体,引起应力集中,恶化合金性能。利用稀土Y对Al-6Fe合金进行微合金化处理,结合快速凝固技术,并辅以热挤压技术,获得较常规凝固条件下更加细小均匀的显微组织,以解决铝铁合金中粗大的针片状富铁相割裂基体的问题。实验结果表明,稀土元素Y抑制了初生富铁相生长的趋势,将粗大针片状富铁相细化为菱形和短棒状,一定程度上减小了合金的第二相尺寸;稀土Y微合金化结合快速凝固技术,使得铝铁合金中形成了细小弥散的三元Al-Fe-Y金属间化合物,极大细化了第二相,在改善组织形貌的同时提升了合金的硬度和屈服强度。      

磁悬浮分子泵用Hartley涡流传感器

工业领域的磁悬浮分子泵用位移传感器除了要具有良好的静态特性外,还应具有高动态响应特性,同时其体积大小还影响着磁悬浮分子泵的抽速、真空度和压缩比。针对高真空磁悬浮分子泵,提出了一种基于Hartley原理的电涡流位移传感器设计方法,将传感器对称探头接入同一振荡电路作为工作电感。对传感器的动态特性进行了分析,并提出了对其动态响应特性在不影响灵敏度和线性度等静态性能的情况下进行补偿的方法。实验结果表明,在-0.4~0.4mm内,传感器的线性度为±1.17%,灵敏度为9.901mV/μm,分辨率为0.25%,动态响应带宽达到了10.2kHz,两径向四路位移信号测量集成电路板体积仅为π×4~2 cm~2,大大减小了传感器体积,满足了磁悬浮分子泵面向更高抽速和更高真空度的发展需求。