Partition-based workload scheduling in living data warehouse environments

The demand for so-called living or real-time data warehouses is increasing in many application areas such as manufacturing, event monitoring and telecommunications. In these fields, users normally expect short response times for their queries and high freshness for the requested data. However, meeting these fundamental requirements is challenging due to the high loads and the continuous flow of write-only updates and read-only queries that might be in conflict with each other. Therefore, we present the concept of workload balancing by election (WINE), which allows users to express their individual demands on the quality of service and the quality of data, respectively. WINE exploits these information to balance and prioritize both types of transactions—queries and updates—according to the varying user needs. A simulation study shows that our proposed algorithm outperforms competing baseline algorithms over the entire spectrum of workloads and user requirements.     

Thermal-hydraulic and aerosol containment phenomena modelling in ASTEC severe accident computer code

Transients in containment systems of different scales (Phebus.FP containment, KAEVER vessel, Battelle Model Containment, LACE vessel and VVER-1000 nuclear power plant containment) involving thermal-hydraulic phenomena and aerosol behaviour, were simulated with the computer integral code ASTEC. The results of the simulations in the first four facilities were compared with experimental results, whereas the results of the simulated accident in the VVER-1000 containment were compared to results obtained with the MELCOR code. The main purpose of the simulations was the validation of the CPA module of the ASTEC code. The calculated results support the applicability of the code for predicting in-containment thermal-hydraulic and aerosol phenomena during a severe accident in a nuclear power plant.     

Sulfate determines the glucosinolate concentration of horseradish in vitro plants (Armoracia rusticana Gaertn., Mey. & Scherb.)

BACKGROUND: Horseradish plants (Armoracia rusticana) contain high concentrations of glucosinolates. Former studies have revealed that Armoracia plants cultivated in vitro have markedly lower glucosinolate concentrations than those grown in soils. Yet, these studies neglected that the sulfate concentration in the growth medium may have had a strong impact on glucosinolate metabolism. Accordingly, in this study horseradish in vitro plants were cultivated with differing sulfate concentrations and the glucosinolate concentrations were quantified by ion pair HPLC. RESULTS: Cultivation in 1.7 mmol L^?1 sulfate (as used in the prior studies) resulted in the accumulation of 16.2 µmol g^?1 DW glucosinolates, while the glucosinolate concentration increased to more than 23 µmol g^?1 DW when 23.5 mmol L^?1 sulfate was used in the medium. Correspondingly, the glucosinolate concentration decreased to 1.6 µmol g^?1 DW when sulfate concentration was lowered to 0.2 mmol L^?1. CONCLUSION: Since the glucosinolate accumulation in relation to the sulfate concentration follows a typical saturation curve, we deduce that the availability of sulfate determines the glucosinolate concentration in horseradish in vitro plants. © 2012 Society of Chemical Industry     

Waste cement dusts as fillers for rubber compounds

The possibility of substitution of expensive active fillers, e.g. carbon black, for the waste products which can play the role of these fillers, e.g. the waste cement dusts or the waste post-HF silica, were investigated. The physico-chemical properties of the investigated waste cement dusts and the waste post-HF silica, as well as the strength properties of the rubber compounds containing these as fillers, were determined. To increase the activity and chemical affinity with the rubber, the waste cement dusts and the waste post-HF silica were modified by the use of adhesion promoters, that is alkoxysilanes. It was found that it would be possible to partly substitute carbon black for the waste cement dusts and the waste post-HF silica. The mixture ratio of a compound which had these wastes and showed the optimum strength properties was proposed.     

Caffeine in your drink: natural or synthetic?

Owing to possible adulteration and health concerns, it is important to discriminate between natural and synthetic food ingredients. A new method for compound-specific isotope analysis (CSIA) by coupling high-temperature reversed-phase liquid chromatography to isotope ratio mass spectrometry (HT-RPLC/IRMS) was developed for discrimination of natural and synthetic caffeine contained in all types of drinks. The analytical parameters such as stationary phase, column inner diameter, and column temperature were optimized for the separation of caffeine directly from drinks (without extraction). On the basis of the carbon isotope analysis of 42 natural caffeine samples including coffee beans, tea leaves, guaraná powder, and maté leaves, and 20 synthetic caffeine samples from different sources by high-temperature reversed-phase liquid chromatography coupled to isotope ratio mass spectrometry, it is concluded that there are two distinguishable groups of caffeine δ(13)C-values: one between -25 and -32‰ for natural caffeine, and the other between -33 and -38‰ for synthetic caffeine. Isotope analysis by HT-RPLC/IRMS has been applied to identify the caffeine source in 38 drinks. Four mislabeled products were detected due to added but nonlabeled synthetic caffeine with δ(13)C-values lower than -33‰. This work is the first application of HT-RPLC/IRMS to real-world food samples, which showed several advantages: simple sample preparation (only dilution), high throughput, long-term column stability, and high precision of δ(13)C-value. Thus, HT-RPLC/IRMS can be a very promising tool in stable isotope analysis of nonvolatile compounds.     

High temperature properties of B6O-materials

B₆O is a potential superhard material with a hardness of 45 GPa measured on single crystals. Recently it was found that different oxides can be utilized as an effective sintering additive which allows densification under low pressures. In this work the effect of addition of Y₂O₃/Al₂O₃ on high temperature properties was investigated using impulse excitation technique (IET), hardness measurements and dilatometric measurements. The IET technique reveals the softening of the residual B₂O₃ in the materials without additives at 450 °C; in the materials with Y₂O₃/Al₂O₃ the softening is observed at only about 800 °C. This data agrees with the values found for different borate glasses.The materials showed no pronounced reduction of hardness at these temperatures. This is additional evidence, supporting previous observations that the material consists of pure grain boundaries between B₆O grains. Hardness values (HV5) of up to 17 GPa at 1000 °C were observed.     

Microstructural Analysis of Reballed Tin-Lead,Lead-Free,and Mixed Ball Grid Array Assemblies Under Temperature Cycling Test

In this study, ball grid array (BGA) packages with Sn-3.0Ag-0.5Cu (SAC305) solder balls were reballed with Sn-37Pb solder balls. Three different reballing methods were used. The non-reballed lead-free BGAs were assembled with SAC305 and Sn-37Pb solder pastes to form the lead-free and mixed assemblies. The reballed Sn-Pb BGAs were assembled with Sn-37Pb solder paste to form the reballed Sn-Pb assemblies. All assemblies were subjected to a temperature cycling test with a temperature range of −55°C to 125°C. For the same component type, the reballed BGA assemblies showed similar temperature cycling reliability regardless of the reballing methods. However, the temperature cycling reliability of the reballed assemblies was worse than that of the mixed and the lead-free assemblies. The mean cycles-to-failure of the mixed assemblies was larger than or equal to that of the lead-free assemblies. Failure analysis revealed that the failure site in reballed Sn-Pb assemblies was located in the bulk solder at the component side regardless of the component type and the reballing method, indicating that the reballing method did not influence the crack propagation in reballed assemblies. The mixed assemblies had the same failure site as the lead-free assemblies, i.e., in the bulk solder at the component side. The microstructure differences between the tin-lead, lead-free, and mixed assemblies are also discussed in detail.     

Discrete Terahertz Beam Steering with an Electrically Controlled Liquid Crystal Device

We present an electronic beam switching/steering device for operation at THz frequencies. The propagation direction of the THz beam is switched via electronic manipulation of the refractive index of a liquid crystal. The design of the steering device and the parameters of the liquid crystal are described and angle-dependent THz-TDS measurements of the beam steering are reported. This device is able to deflect the propagation direction of the THz beam by 6.3?°. This particular device approach offers a viable option for beam steering/switching in various THz applications including fiber switches, scanning imagers, and free-space communication systems in which the detector or emitter is in motion.     

Terahertz quasi-time-domain spectroscopy imaging

We demonstrate terahertz (THz) imaging with a quasi-time-domain spectrometer. This type of THz system is inexpensive, compact, and relatively easy to set up. Beating the simultaneously emitted equidistant modes of a compact diode laser allows for analysis of samples at multiple frequencies with a single measurement. Thus, this technique merges the potential of terahertz time-domain spectrometers with the simplicity of continuous wave lasers. Multiple imaging applications and stability issues are discussed.     

Amber Light Control of Peptide Secondary Structure by a Perfluoroaromatic Azobenzene Photoswitch

The incorporation of photoswitches into the molecular structure of peptides and proteins enables their dynamic photocontrol in complex biological systems. Here, a perfluorinated azobenzene derivative triggered by amber light was site-specifically conjugated to cysteines in a helical peptide by perfluoroarylation chemistry. In response to the photoisomerization (trans→cis) of the conjugated azobenzene with amber light, the secondary structure of the peptide was modulated from a disorganized into an amphiphilic helical structure.