Fe2O3 core-NaCo[Fe(CN)6] shell nanoparticles—Synthesis and characterization

A facile precipitation route was developed for the synthesis of cobalt hexacyanoferrate (CoHCF) as a thin shell around cores of nanoparticles of iron(III) oxide, forming nanoparticles of iron(III) oxide@CoHCF (n-Fe₂O₃@NaCo[Fe(CN)₆]). The morphology and structure of the as-prepared n-Fe₂O₃@NaCo[Fe(CN)₆] were characterized by the techniques of electron microscopies, X-ray diffraction measurements, X-ray photoelectron spectroscopy, infrared spectroscopy and thermogravimetry. Carbon composite electrodes of n-Fe₂O₃@NaCo[Fe(CN)₆] were prepared and the electrochemical behavior of the nanoparticles was evaluated using cyclic voltammetry. The redox couples of n-Fe₂O₃@NaCo[Fe(CN)₆] were investigated and the diffusion coefficients of counter cation in the shell of CoHCF were obtained. The effect of size of particles and the structure of CoHCF was also evaluated. n-Fe₂O₃@NaCo[Fe(CN)₆] represented prominent electrocatalytic activity toward the oxidation of some biologically active compounds.     

Performance evaluation of a modified step-feed anaerobic/anoxic/oxic process for organic and nutrient removal

A pilot scale modified step-feed process was improved to increase nutrient(N and P)and organic removal operations from municipal wastewater.It combined the step-feed process and a method named "University of Cape Town(UCT)".The effect of nutrient ratios and inflow distribution ratios were studied.The highest uptake efficiency of 95% for chemical oxygen demand(COD)has been achieved at the inflow distribution ratio of 40/35/25.However,maximum removal efficiency obtained for total nitrogen(TN)and phosphorus at 93% and 78%,respectively.The average mixed liquor suspended solids(MLSS)was 5500 mg·L~(-1).In addition,convenient values for dissolved oxygen(DO)concentration,and p H were obtained throughout different stages.The proposed system was identified to be an appropriate enhanced biological nutrient removal process for wastewater treatment plants owing to relatively high nutrient removal,sturdy sludge settle ability and COD removal.     

Mechanical,thermal, and rheological properties of graphene‐based polypropylene nanocomposites prepared by melt mixing

In this article, we describe the fabrication by melt mixing of graphene‐polypropylene nanocomposites and present the effect of graphene addition on some selected properties of polypropylene (PP). The graphene nanosheets (GNs) used as nano‐reinforcing agents were obtained through chemical reduction of graphene oxide by hydrazine hydrate. GNs were characterized and successfully dispersed into PP matrix to produce PP/GNs nanocomposites. The effects of GNs content on thermal, mechanical, and rheological properties were reported, and the obtained results were discussed in terms of morphology and state of dispersion and distribution of the GNs within the polymer matrix. Characterization by scanning electron microscopy and X‐ray diffraction of the nanocomposites has shown a relatively good dispersion of GNs in the polymer matrix, with the presence of only few aggregates. Increasing GNs content resulted in a significant increase in both mechanical and thermal properties with only few percent of GNs loading. Rheological behavior of the PP/GNs nanocomposites showed a Maxwellian‐like behavior for low GNs concentrations and a viscoelastic solid‐like behavior for GNs content exceeding the concentration of the percolation threshold. POLYM. COMPOS., 2012. © 2012 Society of Plastics Engineers     

一种改进的Ribbon snake遥感图像道路网自动生成算法

针对树木或高大建筑物遮挡以及噪声等因素造成道路提取结果不完整的现象,根据道路的几何特征,在Snake模型中加入道路宽度信息,构造Ribbon Snake模型。为了克服模型对内部参数依赖性较大、容易受到复杂背景干扰影响的不足,采用B样条曲线对道路的平滑性进行约束,与Ribbon Snake相结合建立道路提取算法,通过调节控制点的数目增强曲线的灵活性。从改进的B样条Ribbon Snake的道路网分割结果可以看出,分割的结果更加平滑,精度更高,对噪声具有更好的鲁棒性。     

Preliminary results of composite liner field performance study

This paper presents preliminary results of a study of the field performance of composite liners. The purpose of the study is to evaluate the ability of composite liners to contain municipal solid waste (MSW) leachate. The paper presents data for double-lined MSW landfills having composite top liners consisting of a geomembrane (GMB) upper component and a compacted clay liner (CCL) lower component. Data on flow volumes and flow constituents for the leachate collection and removal system (LCRS) and the leakage detection system (LDS) components of the double liner system are analyzed to assess whether leakage has occurred through the composite top liner. Data for nine MSW landfill cells with monitoring periods of up to eight years are presented. Preliminary results indicate that the nine composite liners are performing well and are effective in containing MSW leachate.     

Actinides oxalate precipitation in emulsion modeling: From the drop scale to the industrial process

An original process of actinides coprecipitation based on pulsed flow column is studied. The novelty of this process lies in the confinement of the aqueous reagents in separated droplets, dispersed in an inert organic phase (W/O emulsion). Precipitation occurs inside drops when they coalesce. Besides the implementation of well-known technologies of the nuclear industry, this precipitation in emulsion process is particularly convenient for the control of supersaturation, and ensures the sticky precipitates’ confinement within drops, thereby limiting the fouling risk and its adverse consequences on productivity and safety.