Tubular precipitation structures: materials synthesis under non-equilibrium conditions

Inorganic precipitation reactions are known to self-organize a variety of macroscopic structures, including hollow tubes. We discuss recent advances in this field with an emphasis on experiments similar to 'silica gardens'. These reactions involve metal salts and sodium silicate solution. Reactions triggered from reagent-loaded microbeads can produce tubes with inner radii of down to 3 μm. Distinct wall morphologies are reported. For pump-driven injection, three qualitatively different growth regimes exist. In one of these regimes, tubes assemble around a buoyant jet of reactant solution, which allows the quantitative prediction of the tube radius. Additional topics include relaxation oscillations and the templating of tube growth with pinned gas bubble and mechanical devices. The tube materials and their nano-to-micro architectures are discussed for the cases of silica/Cu(OH)(2) and silica/Zn(OH)(2)/ZnO tubes. The latter case shows photocatalytic activity and photoluminescence.     

Adsorption of silane onto cellulose fibers. II. The effect of pH on silane hydrolysis,condensation, and adsorption behavior

The hydrolysis of four alkoxysilane agents, γ‐methacryloxypropyl trimethoxysilane (MPS), γ‐mercaptopropyl trimetoxysilane (MRPS), octyl trimethoxysilane OS), and N‐phenyl‐γ‐aminopropyl trimethoxysilane (PAPS), was carried out in an ethanol/water (80/20) solution under both acid and basic conditions. ¹H, ¹³C, and ²⁹Si NMR spectroscopy were used to provide quantitative analyses of the structural components during hydrolysis and condensation reaction. The analysis revealed that the acid‐catalyzed hydrolysis of silane allows the formation of high amount of silanol groups, reduced the selfcondensation reaction among silanol groups and stabilized the proportion of intermediary hydrolyzed species for several days. However, under basic condition, condensation reactions proceed as soon as the hydrolysis reaction started leading to the rapid consumption of silanol groups through selfcondensation and to the growth of three‐dimensional high molecular structures. The interaction of MPS and MRPS with cellulose fibers and the evolution of their surface properties were then investigated using adsorption isotherms and contact angle measurement. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Seawater desalination using PVDF-HFP membrane in DCMD process: assessment of operating condition by response surface method

Central composite design (CCD) was applied in this work to analyze the performance of poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) flat sheet membrane in the seawater desalination using direct contact membrane distillation (DCMD) process. It is the most popular in response surface method (RSM). Development on Quadratic Regression model for membrane performance as a function of the operating conditions was studied. The ranges for each operating condition were selected as follows: feed temperature (T_f): 48–58?°C, feed flow rate (Q_f): 80–180?mL/min, permeate temperature (T_p):17–22?°C and permeate flow rate (Q_p): 80–180?mL/min. The model R-squared of 0.9759 (adjusted to degree-of-freedom), Lack-of-fit test (p?=?0.4764), predicted residual error sum of squared (PRESS) statistic of 10.3 suggest that the model is adequate to correlate the impact of operating conditions on permeates. ANOVA analysis showed that factors as feed flow rate, feed temperature, and permeate temperature have a valuable impact (p?≤?0.05) on the response variable. Additionally, the interaction among feed temperature-feed flow rate, feed flow rate-permeate flow rate, and the quadratic impact of feed temperature, permeate temperature, and permeate flow rate have shown an important impact (p?≤?0.05) on the permeate flux. Optimization of operating conditions to make the permeate flux and salt rejection high as possible was determined according to desirability function approach. A desirability of 0.969 was achieved at a feed temperature of 58?°C, feed flow rate of 180?mL/min, permeate temperature of 18.8?°C, and permeate flow rate of 145.3?mL/min in which a permeate flux of 12.56?kg/m²h and a salt rejection of 99.97% was obtained.     

A further introduction to finite element analysis ofelectromagnetic problems

Finite element analysis is applied to find solutions to problems involving Poisson's equation and wave equations. Typical examples are used for illustration. Problems of node numbering, bandwidth reduction, and mesh generation are discussed     

Detailed manufacturing process of a tubular carbon microfiltration membrane for industrial wastewater treatment

Journal of Porous Materials - This paper discusses the preparation of an asymmetric microfiltration carbon membrane made of mineral coal powder and phenolic resin. Tubular supports were obtained...     

Efficient solutions to multicast routing in communication networks

An important problem in both wireless and wired communication networks is to be able to efficiently multicst information to a group of network sites. Multicasting reduces the transmission overhead of both wireless and wired networks and the time it takes for all the nodes in the subset to receive the information. Since transmission bandwidth is a scarce commodity especially in wireless networks, efficient and near minimum-cost multicast algorithms are particularly useful in the wireless context. In this paper, we discuss methods of establishing efficient and near minimum-cost multicast routing in communication networks. In particular, we discuss an efficient implementation of a widely used multicast routing method which can construct a multicast tree with a cost no greater than twice the cost of an optimal tree. We also present two efficient multicast tree constructions for a general version of the multicast routing problem in which a network consists of different classes of nodes, where each class can have one or more nodes of the same characteristic which is different from the characteristics of nodes from other classes. Because of their efficient running times, these multicast routing methods are particularly useful in the mobile communication environments where topology changes will imply recomputation of the multicast trees. Furthermore, the proposed efficient and near minimum-cost multicast routing methods are particularly suited to the wireless communication environments, where transmission bandwidth is more scarce than wired communication environments.Partially supported by NSF/LaSER under grant number EHR-9108765, by LEQSF grant number 94-RD-A-39, by NASA under grant number NAG 5-2842.     

Non-contact structural health monitoring of a cable-stayed bridge: case study

In this article, the condition assessment of a cable-stayed bridge using remote sensing is presented. The displacement influence line (DIL) of the bridge under the live load tests is measured for a discrete number of target points. Three different remote sensing techniques including, laser scanning, terrestrial robotic total station and digital levelling are adopted for this purpose. It is demonstrated that DIL obtained by non-contact system is capable of identifying an emulated damage in an actual operating system. The contribution of the work is fourfold. First, a damage index based on the displacement profile of the bridge under the weigh-in-motion is extracted from the non-contact sensing system. Second, our study compares three different remote sensing techniques, namely, digital levelling, robotic total station and laser scanning and uses the measurements to validate the finite element model. Third, the effectiveness of the proposed method for structural damage identification is validated in a real-world large-scale operating structure. Finally, it is validated that strain-based influence line is highly likely to misidentify damage especially when the location of damage is not in the close proximity of the sensor; however, DIL is a better damage indicator even if damage occurs far from the measurement point.     

Toward the understanding of the metabolism of levodopa I. DFT investigation of the equilibrium geometries, Acid-base properties and levodopa-water complexes

Levodopa (LD) is used to increase dopamine level for treating Parkinson's disease. The major metabolism of LD to produce dopamine is decarboxylation. In order to understand the metabolism of LD; the electronic structure of levodopa was investigated at the Density Functional DFT/B3LYP level of theory using the 6-311+G** basis set, in the gas phase and in solution. LD is not planar, with the amino acid side chain acting as a free rotator around several single bonds. The potential energy surface is broad and flat. Full geometry optimization enabled locating and identifying the global minimum on this Potential energy surface (PES). All possible protonation/deprotonation forms of LD were examined and analyzed. Protonation/deprotonation is local in nature, i.e., is not transmitted through the molecular framework. The isogyric protonation/deprotonation reactions seem to involve two subsequent steps: First, deprotonation, then rearrangement to form H-bonded structures, which is the origin of the extra stability of the deprotonated forms. Natural bond orbital (NBO) analysis of LD and its deprotonated forms reveals detailed information of bonding characteristics and interactions across the molecular framework. The effect of deprotonation on the donor-acceptor interaction across the molecular framework and within the two subsystems has also been examined. Attempts to mimic the complex formation of LD with water have been performed.     

Sensor network security: a survey

Wireless sensor networks (WSNs) use small nodes with constrained capabilities to sense, collect, and disseminate information in many types of applications. As sensor networks become wide-spread, security issues become a central concern, especially in mission-critical tasks. In this paper, we identify the threats and vulnerabilities to WSNs and summarize the defense methods based on the networking protocol layer analysis first. Then we give a holistic overview of security issues. These issues are divided into seven categories: cryptography, key management, attack detections and preventions, secure routing, secure location security, secure data fusion, and other security issues. Along the way we analyze the advantages and disadvantages of current secure schemes in each category. In addition, we also summarize the techniques and methods used in these categories, and point out the open research issues and directions in each area.