NO
2 sensing properties of SnO
2-based varistor-type sensors have been investigated in the temperature range of 400-650°C and in the NO
2 concentration range of 15–30 ppm. Pure SnO
2 exhibited a weak nonlinear
I–
V characteristic in air, but clear nonlinearity in NO
2 at 450°C. The breakdown voltage of SnO
2 shifted to a high electric field upon exposure to NO
2 and the magnitude of the shift was well correlated with NO
2 concentration. Thus, SnO
2 exhibited some sensitivity to NO
2 as a varistor-type sensor. When SnO
2 particles coated with a SiO
2 thin film were used as a raw material for fabricating a varistor, the breakdown voltage in air was approximately the double that of pure SnO
2 and the sensitivity to 15 ppm NO
2 was enhanced slightly. However, the sensitivity to 30 ppm NO
2 decreased. The Cr
2O
3-loading on SnO
2 also led to an increase in the breakdown voltage in air, but the Cr
2O
3 addition was not effective for promoting the NO
2 sensitivity under the present experimental conditions.
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