Oxidation Resistance Evaluation of Silicon Carbide Ceramics with Various Additives

Five silicon carbide ceramics with various additives were evaluated for oxidation resistance at 1300°C in flowing dry and wet air. In the dry atmosphere, the oxidation of the five samples was diffusion-controlled, and in wet atmosphere they exhibited a linear relation beween weight gain by oxidation and water vapor content. Water vapor in the atmosphere strongly accelerated oxidation. The influence of oxidation on room-temperature strength was complex, but the samples were not as affected by oxidation.     

Optical and electrical anisotropies of polydiacetylene derivative film aligned by shear stress

The molecular alignment of polydiacetylene (PDA) derivatives and their optical and electrical properties of thin films based on PDA derivatives have been studied. The PDA derivatives were aligned depending on the direction of applied shear stress in the film. From measurements of the polarized absorption and current–voltage characteristics, the optical and electrical anisotropies have been observed, that was discussed by taking the PDA main chain alignment into consideration.     

Control of microstructure and disintegration properties of silica granules from PVA slurries by spray drying

The microstructure of spray-dried model granules, comprising silica microspheres and poly (vinylalcohol), was observed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) with an ultramicrotome technique. Disintegration of granules was characterized by a shear method for granular beds, and by a compression test for single granules. The internal structure changed significantly with the pH of the slurry from which the granules were spray-dried. Granules from pH 7 slurry showed the smallest apparent density, and were disintegrated under the smallest applied load. By analysing the relationship between microstructure, apparent density and flow behaviour of the slurries, it was possible to obtain a guideline for preparation of appropriate granules with controlled microstructure and strength.     

Effects of the method of preparing iron orthophosphate catalyst on the structure and the catalytic activity

Catalytic activity of iron orthophosphate [FePO₄] was studied using oxidative dehydrogenation of lactic acid to pyruvic acid as a reaction probe. The structure and surface area are different depending on the differences in the source of starting materials as well as in the preparing methods. However, the specific activity, activity per unit surface area, is little affected with the variation in the structure. By the reduction and reoxidation, the catalytic activity clearly increases.     

A molecular orbital study on the chemical interaction across the indomethacin/silica interparticle boundary due to mechanical stressing

A discrete variational-Xα (DV-Xα) method was applied to elucidate the formation of C-O-Si bridging bonds, produced when a silanol group of SiO₂ comes close enough to react with a carboxyl group of indomethacin (IM). A decrease in the coordination number (CN) of oxygen atoms per silicon atom at the SiO₂ surface increased the net charge (NC) of the silanolic hydrogen atom and decreased the bond overlap population (BOP) between the silanolic oxygen and hydrogen atoms. These changes favored the formation and stabilization of C-O-Si bridging bonds with simultaneous dehydration. The computational results agreed well with our previous experimental study of a ground indomethacin-SiO₂ mixture to obtain a better solid dispersion of the drug.     

Nano-strip grating lines self-organized by a high speed scanning CW laser

After a laser annealing experiment on Si wafer, we found an asymmetric sheet resistance on the surface of the wafer. Periodic nano-strip grating lines (nano-SGLs) were self-organized along the trace of one-time scanning of the continuous wave (CW) laser. Depending on laser power, the nano-trench formed with a period ranging from 500 to 800 nm with a flat trough between trench structures. This simple method of combining the scanning laser with high scanning speed of 300 m min(-1) promises a large area of nanostructure fabrication with a high output. As a demonstration of the versatile method, concentric circles were drawn on silicon substrate rotated by a personal computer (PC) cooling fan. Even with such a simple system, the nano-SGL showed iridescence from the concentric circles.     

Bubble behavior in vertical tube banks installed in a fluidized bed

Fluidized bed combustion is one of the advantageous technologies for coal and/or incineration firing especially with respect to the environmental protection of emissions, such as NO_x/SO_x. Bed material movement in such a fluidized bed has a prime importance in the heat transfer process. Thus, quantitative measurement of the bed material movement and the void fraction are indispensable for better understanding of the fluidized bed. In this investigation, neutron radiography is applied to visualize the bed material movement in a simulated fluidized bed heat exchanger installed with vertical tubes. Bubble behavior and void fraction profile are obtained by the image processing technique. Bubble movement is highly restrained by these vertical tubes, so that the bubbles rise up along the tube. The bubble diameter is well correlated by the modified Mori and Wen's correlation taking into account the pitch of the tube arrangement. The bubble rise velocity and void fraction are well correlated by applying the drift‐flux model. © 2003 Wiley Periodicals, Inc. Heat Trans Asian Res, 32(8): 727–739, 2003; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.10127     

An integrated structure and scaling methodology for severe accident technical issue resolution: Development of methodology

Scaling has been identified as a particularly important element of the Severe Accident Research Program because of its relevance not only to experimentation, but also to analyses based on code calculations or special models. Recognizing the central importance of severe accident scaling issues, the United States Regulatory Commission implemented a Severe Accident Scaling Methodology (SASM) development program involving a lead laboratory contractor and a Technical Program Group to guide the development and to demonstrate its practicality via a challenging application. The Technical Program Group recognized that the Severe Accident Scaling Methodology was an integral part of a larger structure for technical issue resolution and, therefore, found the need to define and document this larger structure, the Integrated Structure for Technical Issue Resolution (ISTIR). The larger part of the efforts have been devoted to the development and demonstration of the Severe Accident Scaling Methodology, which is Component II of the ISTIR. The ISTIR and the SASM have been tested and demonstrated, by their application to a postulated direct containment heating scenario. The ISTIR objectives and process are summarized in this paper, as is its demonstration associated directly with the SASM. The objectives, processes and demonstration for the SASM are also summarized in the paper. The full body of work is referenced.     

Approach and structure of stabilizing control system preventing an extension of synchronism loss

Recently, large-capacity power stations have been built far from load centers with long-distance transmission lines. Therefore, if a fault occurs at the line, generators in the large-capacity power station may lose synchronism from the remaining generators [1, 3]. To prevent an extension of loss of synchronism to other generators, fast shedding of some generators is an effective measure. The following methods have been proposed so far: A method [3] based on energy function approach; and a method [2] which estimates and predicts the relative swing among generators using data measured on-line at each generator and proposes shedding some generators for stabilization. This method requires a large communication network for an exchange of data between power stations. This paper presents a new stabilizing method and a newly developed stabilizing control system which does not require a large communication network because it utilizes generator output, voltage and current measured on-line in the vicinity of the large-capacity power station. Using these measured data, the system estimates and predicts the relative swing between generators in the large-capacity power station and the remaining generators. Finally, the number of generators to be shed for stabilization is decided and shedding is performed. Configuration and characteristics of the developed stabilizing control system are shown. The validity of this method is confirmed by simulation and testing using an artificial power system.