Modeling of bubble coalescence and disintegration in confined upward two-phase flow

This paper presents the modeling of bubble interaction mechanisms in the two-group interfacial area transport equation (IATE) for confined gas–liquid two-phase flow. The transport equation is applicable to bubbly, cap-turbulent, and churn-turbulent flow regimes. In the two-group IATE, bubbles are categorized into two groups: spherical/distorted bubbles as Group 1 and cap/slug/churn-turbulent bubbles as Group 2. Thus, two sets of equations are used to describe the generation and destruction rates of bubble number density, void fraction, and interfacial area concentration for the two groups of bubbles due to bubble expansion and compression, coalescence and disintegration, and phase change. Five major bubble interaction mechanisms are identified for the gas–liquid two-phase flow of interest, and are analytically modeled as the source/sink terms for the transport equation in the confined flow. These models include both intra-group and inter-group bubble interactions.     

Model evaluation of two-group interfacial area transport equation for confined upward flow

The bubble interaction mechanisms have been analytically modeled in the first paper of this series to provide mechanistic constitutive relations for the two-group interfacial area transport equation (IATE), which was proposed to dynamically solve the interfacial area concentration in the two-fluid model. This paper presents the evaluation approach and results of the two-group IATE based on available experimental data obtained in confined upward flow, namely, 11 data sets in or near bubbly flow and 13 sets in cap-turbulent and churn-turbulent flows. The two-group IATE is evaluated in steady-state, one-dimensional (1D) form. To account for the inter-group bubble transport, the void fraction transport equation for Group-2 bubbles is also used to predict the void fraction for Group-2 bubbles. Agreement between the data and the model predictions is reasonably good and the average relative difference for the total interfacial area concentration between the 24 data sets and predictions is within 7%. The model evaluation demonstrates the capability of the two-group IATE focused on the current confined flow to predict the interfacial area concentration over a wide range of flow regimes.     

Surface treatment of titanium dioxide nanopowder using rotary electrode dielectric barrier discharge reactor

Titanium dioxide (TiO2) nanopowder (P-25;Degussa AG) was treated using dielectric barrier discharge (DBD) in a rotary electrode DBD (RE-DBD) reactor.Its electrical and optical characteristics were investigated during RE-DBD generation.The treated TiO2 nanopowder properties and structures were analyzed using x-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR).After RE-DBD treatment,XRD measurements indicated that the anatase peak theta positions shifted from 25.3° to 25.1°,which can be attributed to the substitution of new functional groups in the TiO2 lattice.The FTIR results show that hydroxyl groups (OH) at 3400 cm-1 increased considerably.The mechanism used to modify the TiO2 nanopowder surface by air DBD treatment was confirmed from optical emission spectrum measurements.Reactive species,such as OH radical,ozone and atomic oxygen can play key roles in hydroxyl formation on the TiO2 nanopowder surface.     

Crystal, electronic and luminescence properties of Eu-doped Sr2Al2−xSi1+xO7−xNx

The crystal and electronic structures, as well as the luminescence properties of Sr₂Al_2−xSi_1+xO_7−xN_x:Eu²⁺ are reported. First-principles calculations energetically confirm that the Al and Si atoms are in partial ordering in the 2a and 4e sites in Sr₂Al₂SiO₇. In addition, the band structure calculation shows that Sr₂Al₂SiO₇ has an indirect band gap with an energy gap of about 4.07 eV, which is in good agreement with the experimental data (5.3 eV) obtained from the diffuse reflection spectrum. The crystal structure of Sr₂Al₂SiO₇ can be modified by Si–N substitution for Al–O in the lattice with a maximum solubility of about x=0.6. The average bond length of Eu_Sr^-(O,N) slightly increases although the lattice parameters decrease with the incorporation of Si–N in Sr₂Al₂SiO₇:Eu²⁺. Under excitation in the visible spectral region, Sr₂Al_2−xSi_1+xO_7−xN_x:Eu²⁺ emits blue to yellow light with a broad emission band in the range of 480–570 nm, varying with both the Eu concentration and the x value. The red shift of the emission band of Eu²⁺ is associated with an increase in the crystal-field splitting and the covalency, which arise from the incorporation of nitrogen as well as the energy transfer between the Eu ions at high Eu concentrations. Moreover, the Eu ions have a strong effect on both the concentration quenching and the thermal quenching in Sr₂Al_2−xSi_1+xO_7−xN_x. The temperature dependence of photoluminescence indicates that Sr₂Al_2−xSi_1+xO_7−xN_x:Eu²⁺ shows strong thermal quenching due to the dominant nonradiative process at room temperature.     

Surface modifications of aligned carbon nanotube thin films by Argon‐ion sputtering

To use carbon nanotubes (CNTs) as anode material for the solid‐state thin‐film Li‐ion rechargeable battery, the tubes are preferred to be aligned perpendicular to a substrate and the CNT thin film to have a smooth surface. Using an Ar‐ion sputtering technique, we carried out the surface modifications of the CNT thin film prepared by the SiC surface decomposition method. In order to evaluate the surface modification, the surface and cross section of the modified CNT film were investigated by field‐emission scanning electron microscopy and atomic force microscopy. © 2012 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc.     

Effect of Maillard Reaction on Some Physical Properties of Ovalbumin

Ovalbumin freeze-dried with or without the addition of glucose was stored at 50°C and 65% relative humidity to study the effect of the Maillard reaction on some physical properties of ovalbumin. In the early stage of the reaction in which ovalbumin-glucose complexes were formed, there were soluble types of monomer and aggregates of which α-helix and available lysine contents were gradually decreased with length of storage and degree of aggregation. These compounds were characterized by properties possessing a marked resistance towards destruction of conformation and coagulation. With progress of the reaction, ovalbumin-glucose complexes changed to insoluble forms having higher particle weight and breakdown products.     

Rate of emulsion polymerization of styrene

In emulsion polymerization, the Smith and Ewart theory gives about two or three times the number of polymer particles obtained by experiment. In this paper, a reaction model is proposed which, from the standpoint of reactor design, can give an adequate explanation of the whole course of an emulsion polymerization of monomer highly insoluble in water. Among other things, the generating process of polymer particles is examined in detail. It is demonstrated experimentally that a new parameter proposed here, which represents the degree of difficulty of monomer initiation in micelles, is indispensable in explaining that process. Also confirmed is that monomer initiation takes place more easily in polymer particles than in micelles. According to the new model, the progress of polymerization, i.e., monomer conversion, the number of the polymer particles, and properties of polymer thus produced can be estimated with satisfactory accuracy. Furthermore, approximate equations are derived for easier estimation.     

基于目标模型的遗传算法在走廊辨识中的应用

为了保证移动机器人能够沿着走廊自动行走并具有一定的智能水平，工作环境的辨识就显得至关重要．同时考虑到控制的实时性，提出了一种基于目标模型的模型匹配的走廊辨识方法．利用遗传算法对未处理的灰度图像中的走廊影像进行匹配，从而使移动机器人自动地适应复杂环境，实现了模型对灯光条件变化以及包括干扰物等环境噪声的鲁棒性，并经实际走廊图像试验验证了辨识效果．     

Microstructure and press formability of a cross-rolled magnesium alloy sheet

Cross-rolling, in which the roll axis is tilted by 7.5° towards the TD-direction, was carried out on a commercial magnesium alloy. The (0002) texture intensity of the cross-rolled specimen was lower than that of the unidirectionally rolled specimen, and the (0002) texture of the cross-rolled specimen was inclined about 10° towards the TD-direction. Also, the grain size of the cross-rolled specimen was smaller than that of the unidirectionally rolled specimen. As a result of the Erichsen tests at 433-493 K, the press formability of the cross-rolled specimen was higher than that of the unidirectionally rolled specimen. The high formability of the cross-rolled specimen is attributed to both the modification of (0002) texture and the enhancement of grain refinement by the cross-rolling.     

SST estimation within Syowa's station mask using MOS-1's visible and thermal infrared radiometers

Since February 1989 measurements from MOS-1 could be received at Syowa Station in Antarctica. The first set of MOS-1 visible and thermal infrared (VTIR) recordings from Syowa Station is analysed in this study. A method developed by Schüssel and Grassl is applied for ice and cloud filtering. For clear ocean pixels the sea surface temperatures are estimated by applying Muneyama's split window algorithm. A sea surface temperature composite of ten VTIR passes is presented.