KINETICS OF HYDROCARBON GAS GENERATION FROM MARINE KEROGEN AND OIL: IMPLICATIONS FOR THE ORIGIN OF NATURAL GASES IN THE HETIANHE GASFIELD, TARIM BASIN, NW CHINA

In this paper we derive kinetic parameters for the generation of gaseous hydrocarbons (C_1‐5) and methane (C₁) from closed‐system laboratory pyrolysis of selected samples of marine kerogen and oil from the SW Tarim Basin. The activation energy distributions for the generation of both C_1‐5 (Ea = 59‐72kcal, A = 1.0×10¹⁴ s^?1) and C₁ (Ea = 61‐78kcal, A = 6.06×10¹⁴ s^?1) hydrocarbons from the marine oil are narrower than those for the generation of these hydrocarbons from marine kerogen (Ea = 50‐74kcal, A = 1.0×10¹⁴ s^?1 for C_1‐5; and Ea = 48‐72kcal, A=3.9×10¹³ s^?1 for C₁, respectively). Using these kinetic parameters, both the yields and timings of C_1‐5 and C₁ hydrocarbons generated from Cambrian source rocks and from in‐reservoir cracking of oil in Ordovician strata were predicted for selected wells along a north‐south profile in the SW of the basin. Thermodynamic conditions for the cracking of oil and kerogen were modelled within the context of the geological framework. It is suggested that marine kerogen began to crack at temperatures of around 120°C (or 0.8 %Ro) and entered the gas window at 138°C (or 1.05 %Ro); whereas the marine oil began to crack at about 140 °C (or 1.1 %Ro) and entered the gas window at 158 °C (or 1.6%Ro). The main geological controls identified for gas accumulations in the Bachu Arch (Southwest Depression, SW Tarim Basin) include the remaining gas potential following Caledonian uplift; oil trapping and preservation in basal Ordovician strata; the extent of breaching of Ordovician reservoirs; and whether reservoir burial depths are sufficiently deep for oil cracking to have occurred. In the Maigaiti Slope and Southwest Depression, the timing of gas generation was later than that in the Bachu Arch, with much higher yields and generation rates, and hence better prospects for gas exploration. It appears from the gas generation kinetics that the primary source for the gases in the Hetianhe gasfield was the Southwest Depression.     

1422轧机滑块式万向接轴的故障及处理

以热轧板厂粗轧主传动滑块式万向接轴为例，分析了该接轴及接轴平衡机构的常见故障及其排除方法，提出了日常维护措施。     

落实职教战略地位走创新发展之路

大力发展职业教育是我国教育发展的战略重点。落实职教的战略地位必须走创新发展的道路，树立服务的意识和经营的观念；根据经济社会发展需求形成培养的特色和优势；加强合作，实现国际化和规模化，创新学校管理，深化教育教学改革。     

西安地铁区间隧道通过地裂缝带的施工方案

通过对西安地铁区间隧道通过地裂缝的特点分析,提出了几种地铁区间隧道通过地裂缝的方法,指出地铁结构采用这些方法能够适应地裂缝的变形发展,并在地裂缝活动的情况下维持地面交通和地铁的正常运营。     

Direct evaluation of singular integrals in elastoplastic analysis by the boundary element method

This paper presents a new method for the direct and accurate evaluation of strongly singular integrals in the sense of Cauchy principal values and weakly singular integrals over quadratic boundary elements in three-dimensional stress analysis and quadratic internal cells in two-dimensional elastoplastic analysis by the boundary element method. A quadratic triangle polar co-ordinate transformation technique is applied to reduce the order of singularity of the singular integrals. Next, a form of Stokes' theorem is introduced in order to remove the singularity in the Cauchy principal value integrals; therefore, the evaluation of these integrals can be carried out by standard Gaussian quadrature. Numerical examples of 2-D elastoplastic problems and a 3-D elastic problem show the effectiveness and efficiency of the method.     

石家庄市室内氡及其子体浓度

本文报道了用双滤膜法对石家庄市室内空气中氡及其子体浓度的调查结果。47个房间室内氡年平均浓度为17.0Bq·m~(-3),氡子体平均浓度是7.14Bq·m~(-3)。氡及其子体浓度的日变化是清晨4—8时出现峰值。季节变化是夏秋季低,冬季高,全年的最低值出现在8月,最高值出现在11月。     

Localized audio watermarking technique robust against time-scale modification

Synchronization attacks like random cropping and time-scale modification are very challenging problems to audio watermarking techniques. To combat these attacks, a novel content-dependent localized robust audio watermarking scheme is proposed. The basic idea is to first select steady high-energy local regions that represent music edges like note attacks, transitions or drum sounds by using different methods, then embed the watermark in these regions. Such regions are of great importance to the understanding of music and will not be changed much for maintaining high auditory quality. In this way, the embedded watermark has the potential to escape all kinds of distortions. Experimental results show strong robustness against common audio signal processing, time-domain synchronization attacks, and most distortions introduced in Stirmark for Audio.     

A wavelet-based procedure for process fault detection

To detect faults in a time-dependent process, we apply a discrete wavelet transform (DWT) to several independently replicated data sets generated by that process. The DWT can capture irregular data patterns such as sharp "jumps" better than the Fourier transform and standard statistical procedures without adding much computational complexity. Our wavelet coefficient selection method effectively balances model parsimony against data reconstruction error. The few selected wavelet coefficients serve as the "reduced-size" data set to facilitate an efficient decision-making method in situations with potentially large-volume data sets. We develop a general procedure to detect process faults based on differences between the reduced-size data sets obtained from the nominal (in-control) process and from a new instance of the target process that must be tested for an out-of-control condition. The distribution of the test statistic is constructed first using normal distribution theory and then with a new resampling procedure called "reversed jackknifing" that does not require any restrictive distributional assumptions. A Monte Carlo study demonstrates the effectiveness of these procedures. Our methods successfully detect process faults for quadrupole mass spectrometry samples collected from a rapid thermal chemical vapor deposition process     

热带城市垃圾典型组分的热解特性研究

对热带城市垃圾的几种典型组分进行了热解实验，得到了它们的失重曲线，通过对失重曲线进行分析，得到了这几种典型组分的热解规律，并通过建立热解动力学模型，求出了其中两种组分的活化能E和频率因子A。     

超高相对分子质量聚乙烯纤维研究进展

介绍了超高分子质量聚乙烯纤维的制备、表面改性及应用的研究进展 ,指出了今后超高分子质量聚乙烯纤维的研究及应用的发展方向