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31.
Aranzazu García M Victoria Ruiz-Méndez Concepción Romero Manuel Brenes 《Journal of the American Oil Chemists' Society》2006,83(2):159-164
By definition, virgin olive oil is consumed unrefined, although a great proportion of the olive oil produced has to be refined
to render it edible. Phenolic compounds are among the substances eliminated during the refining process; in the present work
these were characterized by HPLC, and their evolution during the different refining steps was studied. The complete refining
process removed most polyphenols from oils, but the behavior of individual compounds at each step also was observed. o-Diphenols
(hydroxytyrosol, catechol, and hydroxytyrosol acetate) and flavonoids (luteolin and apigenin) were eliminated first during
the alkaline treatment. Tyrosol and 4-ethylphenol remained in the oil until the deodorization step. A large amount of phenolic
compounds was discovered in the refining by-products such as soapstocks and deodorization distillates. In the latter streams,
the concentrations of tyrosol and 4-ethylphenol reached up to 149 and 3720 mg/kg by-product, respectively. This high level
of 4-ethylphenol and its well-known strong off-odor can interfere during further processing of the deodorization distillates,
and this must be taken into account when deciding what is to become of them. Similarly, the results of this work open the
possibility of recovering phenolic compounds from the “second centrifugation olive oils” by adding a new washing step prior
to the refining process. By including this new step, the most polar polyphenols, hydroxytyrosol and tyrosol, will diffuse
from oil to water and a concentration of up to 1400 mg/L of hydroxytyrosol may be achieved. 相似文献
32.
Jose Ygnacio Pastor Jaime Planas Manuel Elices 《Journal of the American Ceramic Society》1993,76(11):2927-2929
A new technique that provides stable fracture tests in brittle ceramic materials at room and at high temperature is presented. This technique uses the crack mouth opening displacement signal from a laser extensometer to feed the servo control of a hydraulic testing machine. In this way it is possible to obtain—in addition to the fracture toughness—the fracture energy and the R -curve, in a single test. 相似文献
33.
Pablo Giménez Benjamín Molina Jaime Calvo-Gallego Manuel Esteve Carlos E. Palau 《Computers in Industry》2014
Sensor Web Enablement (SWE) technologies have been successfully applied to a great variety of outdoor scenarios but, in practical terms, little effort has been applied for indoor environments, and even less in the field of industrial applications. This article presents an intelligent SWE application for an indoor and industrial scenario, with the aim of improving and increasing the levels of human safety. The base low-level architecture is built on top of wireless sensor networks (WSN) connected to a Sensor Observation Service (SOS). Higher layers in the architecture include services that make real time decisions based on the collected data. Both simulation and experimental results are presented. The paper shows the viability of our approach in terms of performance, scalability, modularity and safety. 相似文献
34.
Towards an Environmentally Acceptable Heterogeneous Catalytic Method of Producing Adipic Acid by the Oxidation of Hydrocarbons in Air 总被引:1,自引:0,他引:1
Raja Robert Lee Sang-Ok Sanchez-Sanchez Manuel Sankar Gopinathan Harris Kenneth D.M. Johnson Brian F.G. Thomas John Meurig 《Topics in Catalysis》2002,20(1-4):85-88
A survey is given of the catalytic methods potentially available for the production of adipic acid by the oxidation of readily available hydrocarbon precursors under environmentally benign conditions. Encouraging results are reported using H2O2 as oxidant and microporous FeAlPO-5 as catalyst at moderate temperatures. 相似文献
35.
Ana Paula Vieira Soares Manuel Farinha Portela Alain Kiennemann 《Catalysis Reviews》2005,47(1):125-174
This review deals with the important industrial reaction of formaldehyde manufacture by methanol oxidation over iron molybdate catalysts. Detailed reference is made to the used catalyst, preparation techniques (coprecipitation, sol-gel like, mechanical mixing, etc.) including unsupported and supported catalysts, promoters and characterization methods. The controversial active phase assignment (stoichiometric versus Mo rich iron molybdate) is discussed. The proposed reaction mechanisms and kinetic laws for the main and side reactions are examined. The catalyst deactivation processes are reviewed and the role of Mo excess on these processes is underlined. Finally conclusions and perspectives are presented. 相似文献
36.
Emilio Soto Candela Mario Ortega Pérez Clemente Marín Romero David C. Pérez López Gustavo Salvador Herranz Manuel Contero Mariano Alcañiz Raya 《Multimedia Tools and Applications》2014,70(3):1837-1868
In this paper, a computer vision based interactive multi-touch tabletop system called HumanTop is introduced. HumanTop implements a stereo camera vision subsystem which allows not only an accurate fingertip tracking algorithm but also a precise touch-over-the-working surface detection method. Based on a pair of visible spectra cameras, a novel synchronization circuit makes the camera caption and the image projection independent from each other, providing the minimum basis for the development of computer vision analysis based on visible spectrum cameras without any interference coming from the projector. The assembly of both cameras and the synchronization circuit is not only capable of performing an ad-hoc version of a depth camera, but it also introduces the recognition and tracking of textured planar objects, even when contents are projected over them. On the other hand HumanTop supports the tracking of sheets of paper and ID-code markers. This set of features makes the HumanTop a comprehensive, intuitive and versatile augmented tabletop that provides multitouch interaction with projective augmented reality on any flat surface. As an example to exploit all the capabilities of HumanTop, an educational application has been developed using an augmented book as a launcher to different didactic contents. A pilot study in which 28 fifth graders participated is presented. Results about efficiency, usability/satisfaction and motivation are provided. These results suggest that HumanTop is an interesting platform for the development of educational contents. 相似文献
37.
Guadalupe Del C. Pizarro Oscar G. Marambio Manuel Jeria O Margarita Huerta Bernab L. Rivas 《应用聚合物科学杂志》2006,100(1):178-185
The free‐radical copolymerization of water‐soluble poly(1‐vinyl‐2‐pyrrolidone‐co‐hydroxyethylmethacrylate) was carried out with a feed monomer ratio of 75:25 mol %, and the total monomer concentration was 2.67M. The synthesis of the copolymer was carried out in dioxane at 70°C with benzoyl peroxide as the initiator. The copolymer composition was obtained with elemental analysis and 1H‐NMR spectroscopy. The water‐soluble polymer was characterized with elemental analysis, Fourier transform infrared, 1H‐ and 13C‐NMR spectroscopy, and thermal analysis. Additionally, viscosimetric measurements of the copolymer were performed. The thermal behavior of the copolymer and its complexes were investigated with differential scanning calorimetry (DSC) and thermogravimetry techniques under a nitrogen atmosphere. The copolymer showed high thermal stability and a glass transition in the DSC curves. The separation of various metal ions by the water‐soluble poly(1‐vinyl‐2‐pyrrolidone‐co‐hydroxyethylmethacrylate) reagent in the aqueous phase with liquid‐phase polymer‐based retention was investigated. The method was based on the retention of inorganic ions by this polymer in a membrane filtration cell and subsequent separation of low‐molar‐mass species from the polymer/metal‐ion complex formed. Poly(1‐vinyl‐2‐pyrrolidone‐co‐hydroxyethylmethacrylate) could bind metal ions such as Cr(III), Co(II), Zn(II), Ni(II), Cu(II), Cd(II), and Fe(III) in aqueous solutions at pHs 3, 5, and 7. The retention percentage for all the metal ions in the polymer was increased at pH 7, at which the maximum retention capacity could be observed. The interaction of inorganic ions with the hydrophilic polymer was determined as a function of the pH and filtration factor. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 178–185, 2006 相似文献
38.
39.
Natália F. C. Vargas Mahmoud S. Alkathy José A. Eiras Valmor Roberto Mastelaro Manuel H. Lente 《Journal of the American Ceramic Society》2021,104(6):2600-2609
In this work, the influence of the sintering temperature on the physical properties of (Pb0.8La0.2)(Ti0.9Ni0.1)O3 (PLT-Ni) ceramics is reported. The experimental data revealed that the energy band gap of PLT-Ni ceramics could be tailored from approximately 2.7 to 2.0 eV by changing the sintering temperature from 1100°C to 1250°C. It is demonstrated that the simple substitution of Ti4+ by Ni2+ cations is effective to decrease the intrinsic band gap while increasing the tetragonality factor and the spontaneous polarization. However, the additional red-shift observed in the absorption edge of the PLT-Ni with increasing the sintering temperature was associated with a continuous increase in the oxygen vacancies () amount. It is believed that the impact of the creation of these thermally induced is manifold. The presence of and Ni2+ ions generate the Ni2+- defect-pairs that promoted both a decrease in the intrinsic band gap and an additional increase of the tetragonality factor, consequently, increasing the spontaneous polarization. The creation of Ni2+- defects also changed the local symmetry of Ni2+ ions from octahedral to a square pyramid, thus lifting the degeneracy of the Ni2+ 3d orbitals. With the increase in the sintering temperature, lower-energy absorbing intraband states were also formed due to an excess of , being responsible for an add-on shoulder in the absorption edge, extending the light absorption curve to longer wavelengths and leading to an additional absorption in “all investigated” spectrum as well. 相似文献
40.
CO2‐assisted polymer processing is proposed as an alternative route for intractable and high molecular weight polymers based on the plasticization effects of CO2 and its direct effect on the melting behavior of semicrystalline polymers. A modified processing system was used to process a variety of polymers in the presence of high‐pressure CO2. The system includes an extruder that was modified to allow for high pressures created by the injection of CO2. The new design includes a modified feed section that allows a given mass of polymer to interact with CO2 before and during the extrusion process. The inherent shear mixing and the presence of CO2 allow for a specific control over the extrudate morphology. Results suggest that this alternative design provides a new and easy route to melt process high melt viscosity polymers of commercial importance, such as polytetrafluoroethylene (PTFE), fluorinated ethylene propylene copolymer (FEP), and syndiotactic polystyrene (s‐PS). The increased processability of these systems in CO2 is related to the plasticization effect of CO2 that was quantified through a depression in the glass‐transition temperature according to the Chow model. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1501–1511, 2004 相似文献