On the importance of equilibrium in studies on the transport of hydrogen in metals

In this paper, specific properties of the metal-hydrogen systems, M-H's, and bulk metal-hydrogen solids, MH_n's, are reviewed, with an emphasis of problems related to reaching the equilibrium and its confinements. In MH_n's the chemical potential of interstitial H species is determined both by its concentration and the self-stress of the metal matrix, these being in a feedback relation. Consequently, the transport of hydrogen in metals is non-Fickian. This imposes special requirements on the studies of this transport. For determining its kinetic parameters, not only should the experiments be initiated at equilibrium in the system under study, as in the case of studies of Fickian transport, but the experiments themselves must also be performed close to equilibrium. Accordingly, the recently proposed transfer function spectroscopy at quasi-equilibrium has to be considered as the only technique making possible a reliable estimation of the kinetic parameters of this transport: not only the diffusion coefficient of hydrogen, but also the bulk elastic modulus of MH_n. The properties of various transfer functions are compared and the usefulness of specimens of different shapes are discussed.     

Decision system for a team of autonomous underwater vehicles—Preliminary report

The paper presents preliminary research whose main goal is to build a ship protection system. One of the elements of the system will be a sub-system responsible for capturing and destroying/neutralizing all dangerous objects occurring inside a guarded area. This task will be performed by a team of autonomous underwater vehicles. To construct a decision system for the vehicles, i.e. the system whose task is to provide high-level decisions regarding direction and velocity of move, many different methods can be applied. Examples are evolutionary neural networks and expert systems with fuzzy decision rules. To test usefulness of the above methods in a role of the decision system, experiments in a predator-prey problem were carried out. In the experiments, the task of vehicles-predators was to capture a vehicle-prey behaving by a simple deterministic strategy. The current paper is a report on all the experiments mentioned.     

Salt Concentration Effects in Planar Light‐Emitting Electrochemical Cells

Incorporation of ions in the active layer of organic semiconductor devices may lead to attractive device properties like enhanced injection and improved carrier transport. In this paper, we investigate the effect of the salt concentration on the operation of light‐emitting electrochemical cells, using experiments and numerical calculations. The current density and light emission are shown to increase linearly with increasing ion concentration over a wide range of concentrations. The increasing current is accompanied by an ion redistribution, leading to a narrowing of the recombination zone. Hence, in absence of detrimental side reactions and doping‐related luminescence quenching, the ion concentration should be as high as possible.     

Cold Model Investigations of Melting of Ice in a Gas-Stirred Vessel

The melting of steel scrap in high temperature liquid iron melt is investigated by conducting cold model experiments of the melting of ice sample of different geometries and sizes in an argon-stirred vessel containing water. The melting process of ice samples is observed using a high-speed camera. Design of experiments is based on similarity criteria. The relationships between non-dimensional groups related to heat transfer (Nu, Re, Pr, and Gr) are derived for different experimental conditions. The results are compared with those reported in the literature. The heat transfer coefficient is estimated as a function of mixing power and is found to be in good agreement with the calculated values obtained by using reported relationships in literature.     

On Stochastic Modeling of Interface Defects in Composite Materials

The article presents mathematical and computational research dealing with the problem of stochastic interface defects occurring in composite materials between their constituents. A mathematical model of the periodic composite with such defects is presented in detail, as well as probabilistic numerical methods enabling computational experiments which are shown in a further part of the text. The fiber-reinforced and laminated composite has been tested in numerical tests as well as the superconducting coil cable-four-component composite to verify how the structural defects considered, according to the model introduced, influence the static behavior of the composites analyzed. All the results obtained and discussed in the article are summarized in concluding remarks which show the directions of further model development, while numerous references enable the reader to study the problem further.     

Antimicrobial Activity of a Pullulan–Caraway Essential Oil Coating on Reduction of Food Microorganisms and Quality in Fresh Baby Carrot

This research evaluated the antimicrobial efficacy of pullulan films containing caraway essential oil (CEO). The films were prepared from a 10% of pullulan, containing from 0.12% to 10.0% of CEO. The composition of the CEO was analyzed with the use of gas chromatography. The antimicrobial activity of the CEO was evaluated with the method of serial microdilutions, and the films containing CEO—with the agar diffusion method against selected Gram‐negative, Gram‐positive bacteria, and fungi. The structure of the film surface and its cross‐section were analyzed using a scanning electron microscope (SEM). Analyses were also carried out to determine the efficacy of a pullulan coating with 10% CEO on baby carrots experimentally inoculated with Salmonella enteritidis, Staphylococcus aureus, Saccharomyces cerevisiae, or Aspergillus niger and stored at a room temperature for 7 d. At a concentration of 0.12%, CEO inhibited the growth of all the tested microorganisms. Pullulan films containing 8% to 10% of CEO were active against all tested microorganisms. Populations of S. aureus on carrot samples were reduced by approximately 3 log CFU/g, while those of A. niger and S. cerevisiae by, respectively, 5 and 4 log CFU/g, after 7 d of storage. S. enteritidis was the most resistant among the tested species, since it was not significantly reduced after 7 d of storage. At the end of storage, samples treated with pullulan–caraway oil coating maintained better visual acceptability than control samples. Results of this study suggest the feasibility of applying a pullulan film with incorporated CEO to extend the microbiological stability of minimally processed foods.     

New Hormaphididae(Hemiptera,Aphidomorpha)from the Baltic Amber and its Palaeogeographic Significance

The present study describes a new genus and species Unicohormaphis sorini, which belongs to the subfamily Cerataphidinae. The contemporary distribution of aphids belonging to the Hormaphididae family is summarized and analyzed. According to the obtained data, the climate warming in Eocene was conducive to the expansion of the family over the areas of Europe. Subsequent climate changes, resulting from epeirogenic and orogenic movements towards the end of Eocene, led to a considerable cooling and drying of climate in the northern hemisphere. These processes contributed to the shrinking down of areas covered by subtropical forests, which constituted the habitat of Hormaphididae (Cerataphidinae). Retaining their way of life, the Cerataphidinae were forced to limit their distribution, and the representatives of the family in Europe became completely extinct.     

Three-dimensional FE model for calculation of temperature of a thermosensitive disc

An effect of variations of the temperature-dependent thermophysical properties of materials of a pad and a disc on the temperature generated due to friction was studied. A three-dimensional boundary-value problem of heat conduction of the disc heated locally within the contact area by the moving with the constant deceleration heat flux and the intensity proportional to the specific capacity of friction was formulated. An issue was solved numerically using the finite element method (FEM). The experimental dependences curves of the thermal conductivity and the thermal diffusivity on the temperature ranging from 20 to 500 °C indispensable for the calculations were approximated using Chichinadze's methodology. The comparative analysis of temperature values on the contact surface of the disc obtained with and without influence of temperature dependence of the four different pad and the same quantity of the disc materials was carried out. It was demonstrated that apparent temperature differences arose for each friction couple combining temperature-dependent and constant properties of materials, however, the largest observed discrepancy (13.7%) occurred for the disc made of aluminium alloy series Al MMC. Other disc materials i.e. iron alloy series FCD50, cast iron ChNMKh and steel EI-696 revealed relatively equal temperature differences of order of 6.4%. Furthermore incorporated in the formula for the heat partition temperature variability of the thermophysical properties of materials affected the resulting contact temperature of the disc for friction couple combined exclusively with the titanium pad VT-14 (3.1%).