Self-assembly of iron oxide-poly(ethylene glycol) core-shell nanoparticles at liquid-liquid interfaces

Nanoparticles (NPs) play an increasingly important role in the fabrication of functional advanced materials. Two major steps need to be carried out in order to achieve control of the material properties. First of all, the properties of the single NPs have to be under control, especially in relation to colloidal stability; aggregation and corrosion negate all the benefits associated to the nanoscopic dimensions. Secondly, the assembly process has to be controlled to achieve a material with the desired properties. We propose here to use stabilized ceramic NPs consisting of a magnetite core, coated by a poly(ethylene glycol) (PEG) shell and study their assembly at polar/ non-polar liquid interfaces, en route to fabricating functional NP membranes. These NPs show extraordinary stability in aqueous solutions achieved by anchoring linear PEG chains through an end-terminating nitroDOPA group to their surface. Furthermore, the core and shell sizes of these NPs can be independently varied with ease. We first describe the details of the NP synthesis and stabilization in bulk solutions, discussing the PEG molecular weight needed to achieve bulk stability. Subsequently, we demonstrate self-assembly of these particles at liquid-liquid interfaces (SALI) into monolayers of stable properties. SALI has been chosen as path for the assembly given its suitability for fabricating two-dimensional materials. We report here results from pendant drop tensiometry which illustrate the kinetics of NP adsorption at the liquid-liquid interface and highlight the role played by the molecular weight of the PEG shell in the interfacial assembly. In particular we show that the requisites to ensure particle stability at a liquid interface are more stringent compared to the bulk case.     

The assembly line worker assignment and balancing problem with stochastic worker availability

Assembly lines can be employed successfully in sheltered work centres to better include persons with disabilities in the labour market as well as to improve production efficiency. The optimal assignment of a heterogeneous workforce is known as the assembly line worker assignment and balancing problem (ALWABP). These assembly lines are characterised not only by a heterogeneous workforce, but also by high levels of absenteeism, which makes it more difficult to obtain stable and efficient line balancing solutions. In this paper, an extension of the ALWABP to minimise the expected cycle time under uncertain worker availability is proposed. We model this problem as a two-stage mixed integer program, and propose local search heuristics for solving it. Computational experiments show that stochastic modelling can help to improve the line’s efficiency and that the proposed heuristics produce good results for instances of practical size.     

Dielectrophoretic manipulation and real-time electrical detection of single-nanowire bridges in aqueous saline solutions

Dielectrophoretic manipulation of nanoscale materials is typically performed in nonionic, highly insulating solvents. However, biomolecular recognition processes, such as DNA hybridization and protein binding, typically operate in highly conducting, aqueous saline solutions. Here, we report investigations of the manipulation and real-time detection of individual nanowires bridging microelectrode gaps in saline solutions. Measurements of the electrode impedance versus frequency show a crossover in behavior at a critical frequency that is dependent on the ionic strength. We demonstrate that by operating above this critical frequency, it is possible to use dielectrophoresis to manipulate nanowires across electrode gaps in saline solutions. By using electrical ground planes and nulling schemes to reduce the background currents, we further demonstrate the ability to electrically detect bridging and unbridging events of individual nanowires in saline solutions. The ability to both manipulate and detect bridging events with electrical signals provides a pathway toward automated assembly of nanoscale devices that incorporate biomolecular recognition elements.     

Investigation of the effects of a variation of fuel assembly position on the ex-core neutron flux detection in a PWR

This work shows the impact of potential displacements of the fuel assembly positions in the reactor core on the signal values of the ex-core instrumentation of a pressurized water reactor in order to understand in detail the impact on the calibration factor of ex-core detectors. This was done with a range of Monte Carlo calculations that simulated the detailed geometrical effect by stepwise changing of the positions of fuel assemblies for selected, conservative scenarios. First, criticality calculations were carried out for the chosen core configurations, and corresponding surface sources on the core barrel were determined. In these calculations, the distances were varied between the fuel assemblies which were in the line of sight of the ex-core instrumentation. A maximal change of the fluxes on the surface of the core barrel of 4%/mm could be calculated under conservative assumptions for the combination of displaced fuel assemblies. In addition, a dependence of this effect as a function of cycle burn-up was analyzed. In a second step, transport calculations for the ionization chambers were performed using the surface sources. An increase of the reaction rate at the chambers of up to 3%/mm has been calculated.     

Catalytic Materials for High-Temperature Combustion

Catalytic combustion, as an alternative to conventional thermal combustion, has received considerable attention during the past decade. Research efforts have been promoted by the need to meet governmental demands concerning pollution and the wish to use energy sources more efficiently. The two main advantages offered by catalytic combustors over flame combustors apply to these goals:

1. Catalytic combustion can be carried out over a wide range of fuel concentrations in air and at low temperatures.
2. These low temperatures result in attaining NO, emission levels substantially lower than possible with conventional combustors.